한국진공학회:학술대회논문집 (Proceedings of the Korean Vacuum Society Conference)
- 한국진공학회 2011년도 제40회 동계학술대회 초록집
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- Pages.319-319
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- 2011
Heterogeneous Catalysts for Hydrogen Generation Based on Ru-Incorporated Hydroxyapatite
- Jaworski, Justyn Wayne (Department of Chemistry, Gyeongsang National University) ;
- Kim, Dae-Hyun (Department of Chemistry, Gyeongsang National University) ;
- Jung, Kyeong-Mun (Department of Chemistry, Gyeongsang National University) ;
- Kim, So-Hue (Department of Chemistry, Gyeongsang National University) ;
- Jeong, Jong-Ok (Central Instrument Facility, Gyeongsang National University) ;
- Jeon, Hyo-Sang (Clean Energy Center, (KIST) Kore) ;
- Min, Byoung-Koun (Clean Energy Center, (KIST) Kore) ;
- Kwon, Ki-Young (Department of Chemistry, Gyeongsang National University)
- 발행 : 2011.02.09
초록
Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol