• Title/Summary/Keyword: hydrogen explosion

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Comparative Analysis of IEC Standard and Simulation Results for Hydrogen Hazardous Distance (수소 폭발위험범위에 대한 IEC기준과 시뮬레이션 결과의 비교분석)

  • Seung-Hyo An;Eun-Hee Kim;Seon-Hee Lee;Byung-Chol Ma
    • Journal of the Korean Institute of Gas
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    • v.28 no.1
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    • pp.19-26
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    • 2024
  • In workplaces handling flammable gas such as hydrogen, hazardous area is determined through KS C IEC 60079-10-1 standard. Because this standard determines the hazardous distance based on the release characteristic regardless of the type of gas, indoor/outdoor conditions, and atmospheric conditions, concerns are being raised about the effectiveness. In this study, simulations (PHAST, HyRAM) were performed to calculate the hazardous distance for hydrogen under various release characteristics and atmospheric conditions, and compared these results to IEC standard log-log graph. Also, we performed regression analysis according to each result. we found that the simulation results were 0.6 to 3.8 times less than the IEC standard, presented convenient linear regression equations. In addition, We confirmed that the results of hazardous distance varied based on wind velocity and atmospheric stability at the same release characteristic. In addition, we derived linear regression equations for release characteristics and hazardous distance that can be conveniently utilized. So, when classifying hazardous area in workplaces where they handle the hydrogen, the integrated graph and linear regression equation are helpful for confirming the hazardous area. Moreover, it is expected that the economic burden will be minimized by being able to classify reasonable hazardous area and to greatly reduce the risk of hydrogen explosion.

A Study on Quantitative Risk Analysis & Model Application for Hydrogen Filling Center (수소충전시설에 대한 정량적 위험성 평가 및 모델적용에 관한 연구)

  • Shin, Jung-Soo;Byun, Hun-Soo
    • Journal of the Korean Institute of Gas
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    • v.16 no.6
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    • pp.87-101
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    • 2012
  • In gas industries, the potential risks of serious accidents have been increased due to high technology application and process complexities. Especially, in case of gas-related accidents, the extent of demage is out of control since gas plants handle and produce combustible, flammable, explosive and toxic materials in large amounts. The characteristics of this kind of disaster is that accident frequency is low, while the impact of damage is high, extending to the neighboring residents, environment and related industries as well as employees involved. The hydrogen gases treated important things and it used the basic material of chemical plants and industries. Since 2000, this gas stood in the spotlight the substitution energy for reduction of the global warming in particular however it need to compress high pressure(more than 150 bar.g) and store by using the special cylinders due to their low molecular weight. And this gas led to many times the fire and explosion due to leak of it. To reduce these kinds of risks and accidents, it is necessary to improve the new safety management system through a risk management after technically evaluating potential hazards in this process. This study is to carry out the quantitative risk assesment for hydrogen filling plant which are very dangerous(fire and explosive) and using a basic materials of general industries. As a results of this risk assessment, identified the elements important for safety(EIS) and suggested the practical management tools and verified the reliability of this risk assessment model through case study of accident.

Analysis on the Legal Control Levels and GHS Classification Information Status for Strongly Acidic Hazardous Materials (강산성 유해화학물질의 법적관리 수준 및 GHS 분류정보 제공 실태분석 연구)

  • Lee, Kwon Seob;Jo, Ji Hoon;Park, Jin Woo;Song, Se Wook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.4
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    • pp.384-392
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    • 2013
  • Objective: This study inspected incident cases, legal control levels, and GHS(Globally Harmonized System of Classification and Labeling of Chemicals) classification results of strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid, which have been responsible for many recent chemical accidents. As a result, it is deemed necessary for legal control levels of these strong acids to be revised and GHS classification be managed nation-wide. Methods: This study inspected incident cases and legal control levels for strong acids such as hydrogen fluoride, hydrogen chloride, nitric acid, and sulfuric acid. The study analyzed and compared chemical information status and GHS classification results. Results: There were 76 domestic incidents involving strongly acidic hazardous materials over the five years between 2007 and 2011. They include 37 leakage incidents(46.7%) within a workplace, 30 leakage incidents(39.5%) during transportation, and nine leakage incidents(13.8%) following an explosion. The strongly acidic materials in question are defined and controlled as toxic chemicals according to the classes of Substances Requiring Preparation for Accidents, Managed Hazardous Substance, Hazardous Chemical(corrosive) as set forth under the Enforcement Decree of the Toxic Chemicals Control Act and Rules on Occupational Safety and Health Standards of Occupational Safety and Health Act. Among them, nitric acid is solely controlled as a class 6 hazardous material, oxidizing liquid, under the Hazardous Chemicals Control Act. The classification results of the EU ECHA(European Chemicals Agency) CLP(Commission Regulation(EC) No. 790/2009 of 10 August 2009, for the purposes of its adaptation to technical and scientific progress, Regulation(EC) No 1272/2008 of the European Parliament and of the Council on classification, labeling and packaging of substances and mixtures) and NIER (National Institute of Environmental Research) are almost identical for the three chemicals, with the exception of sulfuric acid. Much of the classification information of NITE (National Institute of Technology and Evaluation) and KOSHA(Korea Occupational Safety and Health Agency, KOSHA) is the same. NIER provides 12(41.4%) out of 29 classifications, as does KOSHA.

Evaluation of Numerical Model of a Ball Valve used for a Gas Pipeline (가스 파이프라인용 볼 밸브의 수치해석 모델 평가)

  • KIM, CHUL-KYU;LEE, KYOUNG-KEUN;LIM, TAE-GYUN;JANG, CHOON-MAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.764-772
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    • 2016
  • This paper presents on the evaluation of numerical analysis model of a ball valve used for a gas pipeline. The ball valve has important role to control the gas flow of the pipeline as well as safety operation to prevent gas explosion at the emergency. For the validation of numerical simulation, the computational domains are introduced three different types: a hexahedron chamber connected to a pipeline outlet without considering the geometry of pressure tubes, a pipeline only considered the geometry of pressure tubes, and a pipeline connected both of the a hexahedron chamber and pressure tubes. The commercial code, SC/Tetra, is introduced to solve the three-dimensional steady-state Reynolds-averaged Navier-Stokes analysis in the present study. The valve flow coefficient and valve loss coefficient with respect to the valve opening rate of 30%, 50%, and 70% are compared with experimental results. Throughout the numerical analysis for the three analysis domains, pressure computed along the pipeline is affected by computational domains. It is noted pressure obtained by the computational model considering both of the a hexahedron chamber and pressure tubes has a relatively good agreement to the experimental data.

Performance Analysis of Emergency Communication System of Nuclear Power Plant using Markov Model (마코프 모델을 이용한 원전 비상 통신 시스템 성능 분석)

  • Son, Kwang Seop
    • Journal of the Institute of Electronics and Information Engineers
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    • v.51 no.3
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    • pp.10-21
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    • 2014
  • In Fukushima accident, when the severe accident such as a natural disaster happens, it is impossible to monitor the plant status due to a extreme environment and station blackout and most I&C systems break downs. Finally, these cause the loss of emergency cooling function and thus results in a hydrogen explosion and radiation leak. In this paper, the emergency response system is introduced that monitors and controls properly when the sever accidents like Fukushima accident happen, And the performance requirements of a wireless communication system used in the emergency respons system is described and the performance of emergency communication system is analyzed using the markov model.

Protective Effect of Oak Extracts on Oxidative Stress Induced by Hydrogen Peroxide

  • Nam, Jeong Bin;Park, Hyung Bin;Jung, Ji Young;Yang, Jae-Kyung
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.5
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    • pp.523-532
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    • 2014
  • This study was done to evaluate the antioxidant effect of oak hot water extracts on the oxidative stress induced by reactive oxygen species (ROS). The cytotoxicity of $H_2O_2$-induced oxidative stress was performed by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide (MTT) assay for the cell viability according to the dose-dependent treatment. Oak extracts demonstrated a dose-dependent ability to inhibit $H_2O_2$-induced apoptosis in cultured tenofibroblasts, as assessed by MTT assay and FACS analysis. $H_2O_2$ increased the phosphorylation of extracellular regulated kinase1/2 (ERK1/2) and of c-Jun N-terminal kinase (JNK) and the production of reactive oxygen species (ROS). In contrast, treatment with oak extracts was decreased this activation of ERK1/2 and JNK, as confirmed by western blot analysis, and reduced the production of ROS, as verified by fluorescent microscopic and flow cytometry (FACS) analyses. These findings suggest that oak extracts, by suppressing JNK, ERK1/2, and intracellular ROS production, have a concentration-dependent antiapoptotic effect on achilles tenofibroblasts exposed to an oxidative stressor, and may have therapeutic potential.

Dynamic Response of Drill Floor to Fire Subsequent to Blowout

  • Kim, Teak-Keon;Kim, Seul-Kee;Lee, Jae-Myung
    • Journal of Ocean Engineering and Technology
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    • v.34 no.2
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    • pp.110-119
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    • 2020
  • Explosions and fires on offshore drilling units and process plants, which cause loss of life and environmental damage, have been studied extensively. However, research on drilling units increased only after the 2010 Deepwater Horizon accident in the Gulf of Mexico. A major reason for explosions and fires on a drilling unit is blowout, which is caused by a failure to control the high temperatures and pressures upstream of the offshore underwater well. The area susceptible to explosion and fire due to blowout is the drill floor, which supports the main drilling system. Structural instability and collapse of the drill floor can threaten the structural integrity of the entire unit. This study simulates the behavior of fire subsequent to blowout and assesses the thermal load. A heat transfer structure analysis of the drill floor was carried out using the assessed thermal load, and the risk was noted. In order to maintain the structural integrity of the drill floor, passive fire protection of certain areas was recommended.

Performance Analysis of Detecting buried pipelines in GPR images using Faster R-CNN (Faster R-CNN을 활용한 GPR 영상에서의 지하배관 위치추적 성능분석)

  • Ko, Hyoung-Yong;Kim, Nam-gi
    • Journal of Convergence for Information Technology
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    • v.9 no.5
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    • pp.21-26
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    • 2019
  • Various pipes are buried in the city as needed, such as water pipes, gas pipes and hydrogen pipes. As the time passes, buried pipes becomes aged due to crack, etc. these pipes has the risk of accidents such as explosion and leakage. To prevent the risks, many pipes are repaired or replaced, but the location of the pipes can also be changed. Failure to identify the location of the altered pipe may cause an accident by touching the pipe. In this paper, we propose a method to detect buried pipes by gathering the GPR images by using GPR and Learning with Faster R-CNN. Then experiments was carried out by raw data sets and data sets augmentation applied to increase the amount of images.

Improvement Plan for Prevention Regulations to Improve Hazardous Material Safety Management

  • Seongju Oh;Jaewook Lee;Hasung Kong
    • International Journal of Advanced Culture Technology
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    • v.11 no.3
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    • pp.346-357
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    • 2023
  • The purpose of this study is to suggest improvement plans for prevention regulations by reflecting the toxicity, fire and explosion effects of hazardous materials factories and surrounding areas using an off-site consequence assessment program. Regarding the effects of the hydrogen cyanide leak accident, which is the 1st petroleum of the 4th class flammable liquid, Areal Locations of Hazardous Atmospheres (ALOHA) program was used to compare and analyze the extent of damage effects for toxicity, overpressure, and radiation. As a result, the toxicity was analyzed to exceed 5km in the area with Acute exposure guideline level (AEGL)-2 concentration or higher, the overpressure was 103m in the range of 1 psi or more, and the radiant heat was analyzed to be 724m in the range of 2kw/m2 or more. Toxicity and radiation affected the area outside the hazardous material storage area, but the overpressure was limited to the inside of the hazardous material storage area. Therefore, we propose to improve the safety management of hazardous materials by conducting a risk assessment for hazardous materials and reflecting the results in internal and external emergency response plans to prepare prevention regulations.

A Study on the Safety Improvement of Carbon Black Manufacturing Process (카본블랙 제조공정의 안전성 향상에 관한 연구)

  • Joo, Jong-Yul;Jeong Phil-Hoon;Sung-Eun, Lee
    • Journal of the Korea Safety Management & Science
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    • v.25 no.4
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    • pp.153-161
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    • 2023
  • Carbon black is a material in the form of fine black powder obtained by incomplete combustion or pyrolysis of hydrocarbons, and is composed of 90-99% carbon, and the rest is composed of hydrogen and oxygen. In the event of an emergency during the manufacture of carbon black, the generated tail gas should be safely discharged through an emergency line to prevent fire, explosion, and environmental pollution accidents caused by the tail gas. If the pressure continues to rise, the pressure control valve shall operate and the rupture plate shall be ruptured sequentially and the tail gas shall be discharged to the vent stack through the emergency line. As an emergency emission system, even if some untreated substances in the tail gas are released into the atmosphere, they are lighter than air, so it is safe to discharge them to a safe place through the Vent Stack. If the gas pressure is rising or worse, it is discharged from the Vent Stackine, and discharging fuel.