• Journal of the Korea Concrete Institute
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• v.18 no.1 s.91
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• pp.125-132
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• 2006

Recently, surface finishing and protection materials were developed to restore performance of the deteriorated concrete and inhibiting corrosion of the reinforcing-bar. For this purpose, surface protection agent as well as coatings are used. Coatings have the advantage of low Permeability of $CO_2,\;SO_2$ and water. However, for coatings such as epoxy, urethane and acryl, long-term adhesive strength is reduced and the formed membrane of those is blistered by various causes. Also when organic coatings are applied to the wet surface of concrete, those have a problem with adhesion. On the other hand, surface protection agent penetrates into pore structure in concrete through capillary and cm make a dense micro structure in concrete as a result of filling effect. Furthermore, the chemical reaction between silicate from surface protection agent and cement hydrates can also make a additional hydration product which is ideally compatible with concrete body. The aim of this study is to examine the effect of penetrative surface protection agent(SPA) by evaluating several concrete durability characteristics. The results show that the concrete penetrated surface protection agent exhibited higher durability characteristics for instance, carbonation velocity coefficient, resistance to chemical attack and chloride ion penetration than the plain concrete. These results due to formation of a discontinuous macro-pore system which inhibits deterioration factors of concrete by changed the pore structure(porosity and pore size distributions) of the concrete penetrated surface protection agent.

• Journal of the Korea Institute of Building Construction
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• v.13 no.6
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• pp.602-608
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• 2013

The aim of this study is to investigate experimentally the effect of the combination of fine particle cement with high Blaine fineness (FC) and recycled aggregates on the engineering properties and micro structure of high volume blast furnace slag (BS) concrete with 75% BS and 21 MPa. FC manufactured by particle classification at the plant with Blaine fineness of more than $7000cm^2/g$ was used as additional alkali activator for high volume blast furnace slag concrete made with recycled fine and coarse aggregates. FC was replaced by 15, 20 and 25% OPC. Test results showed that the incorporation of FC resulted in an increase in the compressive strength compared to BS concrete without FC by as much as 30% due to accelerated hydration and associated latent hydraulic reaction. It was found that the use of FC and recycled aggregates played an important role in activating BS for high volume BS concrete by offering sufficient alkali.

• Journal of the Korean Recycled Construction Resources Institute
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• v.8 no.2
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• pp.235-244
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• 2020

This study conducted a series of studies to offer a novel method of using CBS-dust that produced as by-product in the manufacture of cement. Four different contents of BS and CBS-dust were adopted for test parameters of this study. Mortar with 50% of W/B was fabricated. First, in the case of the fresh mortar, the flow decreased as the CBS-dust replacement rate increased, but the binder composition ratio BS 45% and 65% showed higher fl ow than Pl ain when repl acing CBS-dust 5%. In the case of air content, overall, the tendency was proportional to the CBS-dust replacement rate, and chloride tended to exceed the reference value at all replacement rates except for the CBS-dust 0% replacement. The compressive strength of the hardened mortar shows the resul t that the strength is improved when the CBS-dust is repl aced by 5% to 10%, and the CSH gel and structure formation is confirmed by microstructure analysis through the hydration reaction when the CBS-dust is replaced. Therefore, for a given condition CBS-dust is used as a early-strength admixture in a concrete secondary product that uses a large amount of admixture without reinforcing bars it can be an effective method for enhancing the strength of concrete as an alkali activator.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.3
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• pp.252-260
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• 2022

In Korea, low-quality kaolin has significantly greater reserves and superior economic efficiency than high-purity kaolin. However, the utilization is low because it does not match the demand conditions of the market, and it is difficult to find a suitable source of demand. The purpose of this study is to derive the possibility and optimal calcination temperature of domestic low-quality kaolin that can be used as a raw material for limestone plastic clay cement (LC³). Isothermal calorimetry, X-ray diffraction analysis, Thermogravimetric Analysis, and compressive strength tests were conducted to evaluate hydrate generation and mechanical properties of LC³ paste according to calcination temperatures (600 ℃, 700 ℃, 800 ℃, 900 ℃). As a result, although 50 % of the clinker was replaced, the domestic low-quality kaolin clay produced calboaluminate hydrate and C(A)SH from the 3rd day of hydration, showing almost equal or higher strength to OPC, and there was a big difference in strength depending on the firing temperature.

• Resources Recycling
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• v.11 no.4
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• pp.27-36
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• 2002

The clinker of which main component was calcium-chloroaluminate ($l1CaOㆍ7Al_2$$O_3$ㆍ$CaCl_2$), was synthesized with the bottom ash of municipal solid waste incinerator ash. The hydration mechanism and synthesis temperature of calcium-chloro-aluminate were investigated. The synthesized clinker was blended with a cement. It was substituted with 3～13 wt.% for clinker and $CaSO_4$ of ordinary portland cement. The compressive strength and the content of leached heavy metals of its mortar were measured. Calcium-chloroaluminate was synthesized above $800^{\circ}C$ and its main hydrate was ettringite ($3CaOㆍAl_2$$O_3$ㆍ$3CaSO_4$ㆍ$32H_2$O). The calcium-chloroaluminate was also synthesized above $800^{\circ}C$ with the bottom ash of which size fraction was below 30 mesh mainly. The compressive strength of the blended cement mortar was increased as the additive content of the clinker synthesized from the bottom ash was increased by 11 wt.%. The concentration of heavy metals leached from each mortar was satisfied with the value of the environmental standards and regulations.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.6C
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• pp.303-311
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• 2009

In this study, weakly cemented sand was cured at air dry condition with different periods (3, 7, 14, 21, 28 days) and its unconfined compressive strength was evaluated. As a result, the strength of specimens with low cement ratios such as 4 and 8% increases until 7 days curing but, after 7 days, their strength continuously decreases. The strength of specimens with relatively high cement ratios such as 12 and 16% increases up to 7 days curing and then stays almost constant until 21 days. After 21 days curing, their strength suddenly dropped down, which is much lower than the strength of 3 days curing specimen. A cemented sand and gravel called CSG, which is highly permeable, could be exposed to repetitive drying and wetting conditions due to rainfall or groundwater table change during curing. In this study, the weakly cemented sand is exposed to repetitive drying and wetting and then its unconfined compressive strength was evaluated. As a result, the strength of a specimen with 27 days drying condition following 1 day wetting was at maximum 35% lower than the one cured under 28 days drying. The strength degradation due to wetting decreases as a cement ratio increases. However, the strength of a specimen with repetitive drying and wetting increases as the number of wetting increases until 3 cycles. After 3 cycles of drying and wetting, the rate of strength increase decreases due to an insufficient water for hydration or stays constant. If the sufficient water supply is provided to cemented sand during curing, the target or design strength increase can be achieved. Otherwise, the strength degradation due to wetting should be considered at the design stage.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.14 no.9
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• pp.4602-4609
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• 2013

In summer and winter, the difference between the temperature during the day and that during the night is high, which leads to various problems during concrete placement, such as cracks and defects in the concrete as well as low durability and strength. Although nuclear power plant concrete is widely used for placement in all seasons, particular attention must be paid to its quality during the summer. Therefore, we evaluated the effects of a cooling method for mixing water, which is a commonly used hot weather precooling method, and the use of a retarder, on the characteristics of Nuclear Power Plant concrete. In the cooling method for mixing water, cold water at 5 was used, with 50% of the water content consisting of ice flakes. The effects of using a retarder were evaluated by reviewing the characteristics of the cement at the unset stage and after hardening. To evaluate the characteristics of the unset cement, we measured the slump, air volumes, setting times, and pressure strengths after hardening. Furthermore, we measured the heat of hydration at different temperatures; the loss of heat was minimized using insulation. Both the slump time and the complete ageing time of the air volume were found to be 120 min at $20^{\circ}C$ and 40 min at $40^{\circ}C$. In the case when the cooling method for mixing water was used and in the case when a retarder was used, the initial and final sets by penetration resistance were delayed, and the delay decreased with increasing air temperature. For the heat of hydration, the cooling method for mixing water not only lowered the maximum temperature but also delayed its attainment. However, the use of a retarder had no effect on the maximum temperature. Moreover, in the early ages (e.g., 3 and 7 days), the pressure strength of the concrete was lower than that of plain cement. However, the strength of 28-day concrete met the standard construction specifications.

• Journal of the Korea Concrete Institute
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• v.27 no.2
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• pp.95-102
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• 2015

In this paper, the effects of sodium hydroxide (NaOH) and aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) dosage on strength properties were investigated. For evaluating the property related to the dosage of alkali activator, sodium hydroxide (NaOH) of 4% (N1 series) and 8% (N2 series) was added to 1~5% (K1~K5) dosage of aluminum potassium sulfate ($AlK(SO_4)_2{\cdot}12H_2O$) and 1% (C1) and 2% (C2) dosage of calcium oxide (CaO). W/B ratio was 0.5 and binder/ fine aggregate ratio was 0.5, respectively. Test result clearly showed that the compressive strength development of alkali-activated slag cement (AASC) mortars were significantly dependent on the dosage of NaOH and $AlK(SO_4)_2{\cdot}12H_2O$. The result of XRD analysis indicated that the main hydration product of $NaOH+AlK (SO_4)_2{\cdot}12H_2O$ activated slag was ettringite and CSH. But at early ages, ettringite and sulfate coated the surface of unhydrated slag grains and inhibited the hydration reaction of slag in high dosage of $NaOH+AlK(SO_4)_2{\cdot}12H_2O$. The $SO_4{^{-2}}$ ions from $AlK(SO_4)_2{\cdot}12H_2O$ reacts with CaO in blast furnace slag or added CaO to form gypsum ($CaSO_4{\cdot}2H_2O$), which reacts with CaO and $Al_2O_3$ to from ettringite in $NaOH+AlK(SO_4)_2{\cdot}12H_2O$ activated slag cement system. Therefore, blast furnace slag can be activated by $NaOH+AlK(SO_4)_2{\cdot}12H_2O$.

• Economic and Environmental Geology
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• v.54 no.2
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• pp.285-297
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• 2021

Globally, nuclear-decommissioning facilities have been increased in number, and thereby hundreds of thousands of wastes, such as concrete, soil, and metal, have been generated. For this reason, there have been numerous efforts and researches on the development of technology for volume reduction and recycling of solid radioactive wastes, and this study reviewed and examined thoroughly such previous studies. The waste concrete powder is rehydrated by other processes such as grinding and sintering, and the processes rendered aluminate (C3A), C4AF, C3S, and ��-C2S, which are the significant compounds controlling the hydration reaction of concrete and the compressive strength of the solidified matrix. The review of the previous studies confirmed that waste concretes could be used as recycling cement, but there remain problems with the decreasing strength of solidified matrix due to mingling with aggregates. There have been further efforts to improve the performance of recycling concrete via mixing with reactive agents using industrial by-products, such as blast furnace slag and fly ash. As a result, the compressive strength of the solidified matrix was proved to be enhanced. On the contrary, there have been few kinds of researches on manufacturing recycled concretes using soil wastes. Illite and zeolite in soil waste show the high adsorption capacity on radioactive nuclides, and they can be recycled as solidification agents. If the soil wastes are recycled as much as possible, the volume of wastes generated from the decommissioning of nuclear power plants (NPPs) is not only significantly reduced, but collateral benefits also are received because radioactive wastes are safely disposed of by solidification agents made from such soil wastes. Thus, it is required to study the production of non-sintered cement using clay minerals in soil wastes. This paper reviewed related domestic and foreign researches to consider the sustainable recycling of concrete waste from NPPs as recycling cement and utilizing clay minerals in soil waste to produce unsintered cement.

• Journal of the Korea Concrete Institute
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• v.15 no.1
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• pp.25-34
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• 2003

The degradation of reinforced concrete (RC) structures due to physical and chemical attacks has been a major issue in construction engineering. Deterioration of RC structures by chloride attack followed by reinforcement corrosion is one of the serious problems. An objective of this study is to develop a form of mathematical model of chloride ingress into concrete. In order to overcome some limits of the previous approaches, a chloride ingress model, consisting of chloride solution intrusion through the capillary pore and chloride ion diffusion through the pore water, was proposed. Moreover, the variability of chloride ion diffusivity due to the degree of hydration of cement, relative humidity in pore, exposure condition, and variation of chloride binding, was considered in the model. In order to verify the proposed model, the results predicted by the proposed model were compared with analysis results of Life-365, a computer program for predicting the service life of reinforced concrete structures exposed to chlorides. In conclusion, the proposed model would be promising to predict the chloride ion profile and to estimate the service life of RC structures.