• Journal of the Korean Institute of Gas
• /
• v.21 no.1
• /
• pp.72-79
• /
• 2017

The operating temperature range of the natural gas pipeline in Arctic environment would be controlled primarily to optimize gas throughput and to minimize the environmental impact resulting from operation of such pipelines. The temperature of the gas as it flows through the pipeline is a function of both the Joule-Thomson effect and the pipe to soil heat transfer. Therefore, the heat transfer and Joule-Thomson effect of the buried natural gas pipeline in this study were carefully considered. Soil temperatures and overall heat transfer coefficients were assumed to be $0{\sim}-20^{\circ}C$ and $0{\sim}5.5W/m^2K$, respectively. The gas temperature and pressure calculations along a pipeline were performed simultaneously at different soil temperatures and overall heat transfer coefficients. Also, this study predicted the phase change and hydrate formation for different soil temperatures and overall heat transfer coefficients using HYSYS simulation package.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.10 no.1
• /
• pp.74-79
• /
• 2022

In this study, the effect of a sudden decrease in internal humidity and a decrease in hydration level due to the tight internal structure of high-strength concrete and cement composites was investigated. To verify the change in the internal Si hydration, waste glass foam beads were used as a lightweight aggregate, and the internal unreacted hydrate reduction and hydrate formation tendency were identified over the mid- to long-term. Waste glass foam beads were mixed with 5, 10, and 20 %, and were used by pre-wetting. As the mixing rate of the waste glass foamed beads increased, the strength showed a tendency to decrease. In addition, when the mixing amount of pre-wetted waste glass foam beads increases inside through XRD analysis, TGA analysis, and Si NMR analysis, it is judged that the hydration degree of internal Si is different because moisture is supplied to the paste.

• Bulletin of the Korean Chemical Society
• /
• v.30 no.9
• /
• pp.2017-2020
• /
• 2009

Three complexes, [bis(L-, D- and DL-alaninato)(diaqua)]nickel(II) di-hydrate, were prepared and characterized by X-ray crystallography, gas chromatography, UV-Visible spectroscopy and isothermal calorimetry. Small deviations from the 50:50 distribution of the enantiomers assigned to chiral preferences of the ligands in the complexes were observed. The surprising and unexpected results indicate that complexing alanine with nickel(II) ion alters the racemization rates of D and L isomers of the amino acid. The precipitated complex due to change in pH resulted in preferential precipitation of one isomer with respect to the other. It has been observed that this alternation is ogmented by the long time span which would result in preferential protein forming from the L-isomer. Although the results are bizarre and perplexing, they are fascinating and sound scientifically.

• Proceedings of the KSME Conference
• /
• 2003.04a
• /
• pp.1663-1666
• /
• 2003

TMA clathrate that is used by PCM of ice storage system in this research creates hydrate crystallization at higher temperature than pure water, and application is expected as PCM because having comparative big dormant temperature without phase separation phenomenon. In case this research uses TMA clathrate by PCM, choose admixture by purpose to control or remove subcooling of TMA clathrate and evaluated experimentally. Subcooling is improved and can expect contraction of freezing machine running time and increase of coefficient of performance as that add admixture to TMA clathrate conclusively. Also, may supply thermal storage system that apply low temperature potential heat thermal storage material that subcooling is improved more extensively laying stress on medium size building and small size building, can expect allowance through localization of ice storage system.

• Proceedings of the KSME Conference
• /
• 2003.11a
• /
• pp.250-255
• /
• 2003

TMA clathrate that is used as PCM of low temperature thermal storage system in this research creates hydrate crystallization at higher temperature then pure water, and its application is expected as PCM because of comparatively big latent heat without phase separation phenomenon. Acetone, Ethylen Glycol, and Ethanol is used as additive and evaluated experimentally for the purpose of the improvement in subcooling of TMA clathrate. In view of the results so far achieved subcooling is improved, the running time of the refrigerator is reduced. Thus the results are expected to use for the increase of coefficient of performance of low temperature thermal storage system in the building.

• Journal of Pharmaceutical Investigation
• /
• v.28 no.2
• /
• pp.81-85
• /
• 1998

Three polymorphic modifications and two pseudopolymorphic modifications of cefotaxime sodium were obtained by crystallization from different organic solvents. The isolated crystal forms were characterized by UV spectrophotometry, DSC, TGA and X-ray crystallography. Crystal forms of cefotaxime sodium were also compared by dissolution rate. The dissolution rate of form 1 was the highest, followed by form 2, form 4, form 6, form 5 and form 3. Among these polymorphic modifications the dissolution rate of form 3 and form 5 was much slower than that of cefotaxime sodium on the market. All forms showed no change after 2-month storage test in the silica gel desiccator. But after the storage of 2-month at 95% relative humidity condition, all forms were deliquesced by hygroscopic property except form 1 that showed the highest dissolution rate. At 52% relative humidity condition, form 1, form 2 and form 6 had no evidence of phase transformation, but form 3, form 4 and form 5 were also deliquesced.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.11a
• /
• pp.497-500
• /
• 2004

Recently, the use of structure compound waterproof agent (hereinafter referred to as 'SCWA') that is used when manufacturing concrete for concrete structures, increases in quantity. However, while it is expected that the SCWA that is mixed in the concrete inside can significantly affect the change of physical properties that lift the internal force of a structure. This study has been conducted through an experiment for the effects of cement hardener on the formation of microscopic texture, and newly generated hydrates from that result were not confirmed in the present experiment. It was found that at the hydrate reaction it has the property that can be hardened within the limit of pore diameterar a specific size rather than there is the internal gap filling capacity due to generating other hydrates.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2004.11a
• /
• pp.777-780
• /
• 2004

Recently, the use of structure compound waterproof agent (hereinafter referred to as 'SCWA') that is used when manufacturing concrete for concrete structures, increases in quantity. However, while it is expected that the SCWA that is mixed in the concrete inside can significantly affect the change of physical properties that lift the internal force of a structure. This study has been conducted through an experiment for the effects of cement hardener on the formation of microscopic texture, and newly generated hydrates from that result were not confirmed in the. present experiment. It was found that at the hydrate reaction it has the property that can be hardened within the limit of pore diameterar a specific size rather than there is the internal gap filling capacity due to generating other hydrates.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.11a
• /
• pp.243-247
• /
• 2003

The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

• Journal of the Korean Geotechnical Society
• /
• v.34 no.2
• /
• pp.19-32
• /
• 2018

During the process of gas hydrate extraction in the deep seabed, fine diatom particle migration occurs, which causes the seabed slope failure and the productivity deterioration of the gas hydrate. Therefore, a study related with the changes of the ground characteristics due to the fine particle migration is required. The objective of this study is to investigate the change of hydraulic properties of sand due to the migration of fine diatom particle in sandy soils. In order to simulate the sediments of the Ulleung basin gas hydrate in the East Sea, fifteen sand-diatom mixtures that have different diatom volume fractions (DVF) are prepared. During the falling head permeability tests, the coefficients of permeability are measured according to the DVF. In addition, for the simulation of the fine diatom particle migration, constant head permeability tests are conducted by applying the hydraulic pressures of 3 kPa, 6kPa, and 9 kPa on a specimen composed of two layers: a specimen with 50% DVF in upper layer and a specimen with 0% DVF in lower layer. Furthermore, the coefficient of permeability and the electrical resistivity of the migration zone are measured during the constant head permeability test. The falling head permeability tests show that the coefficient of permeability decreases as the DVF of the specimen increases. In addition, the gradient of the coefficient of permeability curve decreases in the DVF range of 10%~50% compared with that of 0%~10%, and increases above 50% in DVF. The result of constant head permeability tests shows that the coefficient of permeability decreases and electrical resistivity increases in the migration zone due to the fine diatom particle migration. This study demonstrates that fine diatom particle migration reduces the permeability of the soils and the behavior of the migration zone due to the fine diatom particle migration may be estimated based on the reversal relationship between the coefficient of permeability and the electrical resistivity.