• Title/Summary/Keyword: hybrid cure

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Effect of Various Cross-linking Types on the Physical Properties in Carbon Black-Filled Natural Rubber Compound (천연고무 배합물에서 가교형태 변화가 물성에 미치는 영향)

  • Park, Byung-Ho;Jung, Il-Gouen;Park, Sung-Soo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.63-70
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    • 2001
  • The objective of this study was to investigate the effect of cure type on the processing and physical properties under conditions of similar stress-strain properties. On the carbon black filled natural rubber(NR) based compound, the induction time decreased, but the cure rate became fast with increasing loading of sulfur donor agent. Tensile strength was little affected on the curing type. However, elongation generally decreased with increasing accelerator. Effect of cure type on the blow-out properties was followings: CV

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Investigation of cure cycle for co-cured metal/composite hybrid structures without fabricating thermal residual stress (동시경화 하이브리드 금속/복합재료 구조물의 제조 잔류 열응력 제거를 위한 경화사이클에 관한 연구)

  • Kim Hak Sung;Park Sang Wook;Lee Dai Gil
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.10a
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    • pp.83-87
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    • 2004
  • In this work, the cure cycle of co-cured metal/composite structure was investigated to decrease fabricating thermal residual stresses between the metal and the composite material. DSC (Differential scanning calorimetry) experiment and static lap shear test of co-cured aluminum/composite double lap joint as well as the curvature experiment of co-cured steel/composite strip were performed to investigate the effect of curing cycle on the thermal residual stress of co-cured hybrid structures. From the experiments, it was found that post curing method after abrupt cooling of co-cured aluminum/composite hybrid structure at certain point of degree of cure during curing process could eliminate fabricating the thermal residual stresses.

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Generation of SAC using a ASMOD and a Hybrid curve approximation (ASMOD와 혼합 곡선 근사법을 이용한 SAC의 생성)

  • 김현철;이경선;김수영
    • Proceedings of the Korean Institute of Intelligent Systems Conference
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    • 1997.10a
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    • pp.435-438
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    • 1997
  • This paper presents the process generating a SAC(Sectional Area Cure) by using ASMOD(Adaptive Spline Modeling of Observation Data). That is, we define SACs of real ships as B-spline curves by a hybrid cure approximation(which is the combination method of a B-spline fitting method and a genetic algorithm) and accumulate a database of control points. Then we let ASMOD learn from the correlation principal dimensions with control points.

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Cure Characteristics of Ethoxysilyl Bisphenol A Type Epoxy Resin Systems for Next Generation Semiconductor Packaging Materials (새로운 반도체 Packaging용 Ethoxysilyl Bisphenol A Type Epoxy Resin System의 경화특성 연구)

  • Kim, Whan Gun
    • Journal of the Semiconductor & Display Technology
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    • v.16 no.2
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    • pp.19-26
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    • 2017
  • The cure properties of ethoxysilyl bisphenol A type epoxy resin (Ethoxysilyl-DGEBA) systems with different hardeners were investigated, comparing with DGEBA and Diallyl-DGEBA epoxy resin systems. The cure kinetics of these systems were analyzed by differential scanning calorimetry with an isothermal approach, and the kinetic parameters of all systems were reported in generalized kinetic equations with diffusion effects. The Ethoxysilyl-DGEBA epoxy resin system showed lower cure conversion rates than DGEBA and Diallyl-DGEBA epoxy resin systems. The conversion rates of these epoxy resin systems with DDM hardener are lower than those with HF-1M hardener. It can be considered that the optimum hardener for Ethoxysilyl-DGEBA epoxy resin system is Phenol Novolac type. These lower cure conversion rates in the Ethoxysilyl-DGEBA epoxy resin systems could be explained by the retardation of reaction molecule movements according to the formation of organic-inorganic hybrid network structure by epoxy and ethoxysilyl group in Ethoxysilyl- DGEBA epoxy resin system.

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Cure Monitoring of Composite Laminates Using Fiber Optic Sensors (광섬유 센서를 이용한 복합재료 적층판의 성형 모니터링)

  • Gang, Hyeon-Gyu;Gang, Dong-Hun;Park, Hyeong-Jun;Hong, Chang-Seon;Kim, Cheon-Gon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.2
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    • pp.59-66
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    • 2002
  • In this paper, we present the simulataneous monitoring of the strain and temperature during cures f various composite laminates using fiber Bragg grating/extrinsic Fabry-Perot interferometric (FBG/EFPI) hybrid sensors. Three types of graphite/epoxy composite were used : a undirectional laminate, a symmetric cross-ply laminate, and a fabric laminate. Two FBG/EFPI hybrid sensors were embedded in each laminate at different directions and different locations. We performed the real time monitoring of fabrication strains and temperatures at two points within the composite laminates during cure process in an autoclave. Throuhg these experiments, FBG/EFPI sensors proved to be an efficient choice for smart cure monitoring of composite structures.

Effect of surface treatment and luting agent type on shear bond strength of titanium to ceramic materials

  • Karaokutan, Isil;Ozel, Gulsum Sayin
    • The Journal of Advanced Prosthodontics
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    • v.14 no.2
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    • pp.78-87
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    • 2022
  • PURPOSE. This study aimed to compare the effect of different surface treatments and luting agent types on the shear bond strength of two ceramics to commercially pure titanium (Cp Ti). MATERIALS AND METHODS. A total of 160 Cp Ti specimens were divided into 4 subgroups (n = 40) according to surface treatments received (control, 50 ㎛ airborne-particle abrasion, 110 ㎛ airborne-particle abrasion, and tribochemical coating). The cementation surfaces of titanium and all-ceramic specimens were treated with a universal primer. Two cubic all-ceramic discs (lithium disilicate ceramic (LDC) and zirconia-reinforced lithium silicate ceramic (ZLC)) were cemented to titanium using two types of resin-based luting agents: self-cure and dual-cure (n = 10). After cementation, all specimens were subjected to 5000 cycles of thermal aging. A shear bond strength (SBS) test was conducted, and the failure mode was determined using a scanning electron microscope. Data were analyzed using three-way ANOVA, and the Tukey-HSD test was used for post hoc comparisons (P < .05). RESULTS. Significant differences were found among the groups based on surface treatment, resin-based luting agent, and ceramic type (P < .05). Among the surface treatments, 50 ㎛ air-abrasion showed the highest SBS, while the control group showed the lowest. SBS was higher for dual-cure resin-based luting agent than self-cure luting agent. ZLC showed better SBS values than LDC. CONCLUSION. The cementation of ZLC with dual-cure resin-based luting agent showed better bonding effectiveness to commercially pure titanium treated with 50 ㎛ airborne-particle abrasion.

Time Dependent Extension and Failure Analysis of Structural Adhesive Assemblies Under Static Load Conditions

  • Young, Patrick H.;Miller, Zachary K.;Gwasdacus, Jeffrey M.
    • Journal of Adhesion and Interface
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    • v.21 no.1
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    • pp.6-13
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    • 2020
  • The objective of the current study is to characterize the long-term stability and efficacy of a structural adhesive assembly under static load. An apparatus was designed to be used in the Instron tensile test machine that would allow for real time modeling of the failure characteristics of an assembly utilizing a moisture- cure adhesive which was bonded to concrete. A regression model was developed that followed a linear - natural log function which was used to predict the expected life of the assembly. Evaluations at different curing times confirmed the structure was more robust with longer cure durations prior to loading. Finally, the results show that under the conditions the assembly was tested, there was only a small amount of inelastic creep and the regression models demonstrated the potential for a stable structure lasting several decades.

Simultaneous Measurement of Strain and Temperature During and After Cure of Unsymmetric Composite Laminate Using Fiber Optic Sensors (비대칭 복합적층판의 성형시 및 성형후 광섬유 센서를 이용한 변형률 및 온도의 동시 측정)

  • 강동훈;강현규;김대현;방형준;홍창선;김천곤
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2001.05a
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    • pp.244-249
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    • 2001
  • In this paper, we present the simultaneous measurement of the fabricaition strain and temperature during and after cure of unsymmetric composite laminate uising fiber optic sensors. Fiber Bragg grating/extrinsic Fabry-Perot interferometric (FBG/EFPl) hybrid sensors are used to measure those measurands. The characteristic matrix of sensor is analytically derived and measurements can be done without sensor calibration. A wavelength-swept fiber laser is utilized as a light source. FBG/EFPI sensors are embedded in a graphite/epoxy unsymmetric cross-ply composite laminate at different direction and different location. We perform the real time measurement of fabrication strains and temperatures at two points of the composite laminate during cure process in an autoclave. Also, the thermal strains and temperatures of the fabricated laminate are measured in thermal chamber. Through these experiments, we can provide a basis for the efficient smart processing of composite and know the thermal behavior of unsymmetric cross-ply composite laminate.

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Comparative study on carboxylated styrene butadiene rubber composites reinforced by hybrid fillers of rice bran carbon and graphite carbon

  • Fan, Yuan;Li, Qingyuan;Li, Xiangxu;Lee, Dam hee;Cho, Ur Ryong
    • Carbon letters
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    • v.27
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    • pp.72-80
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    • 2018
  • In the present work, a comparative study of the mechanical behavior of two series of elastomeric composites, based on carboxylated styrene butadiene rubber (X-SBR) and reinforced with rice bran carbon (RBC) and graphite, is reported. Hybrid composites of X-SBR filled with RBC-graphite were also investigated in terms of the cure characteristics, hardness, tensile properties, abrasion resistance, and swelling. It was observed that the cure times decreased with the incorporation of a carbon filler whereas the torque difference, tensile strength, tensile modulus, hardness, and swelling resistance increased compared to the neat X-SBR revealing a favorable characteristic of crosslinking. Dynamic rheological analysis showed that the G' values of the composites, upon the addition of RBC-graphite, were changed to some extent. This demonstrates that the presence of a strongly developed network of fillers will ensure a reinforcing characteristic in a polymer matrix.

A Study on Mechanical Strength in AI7075/CFRP Hybrid Composite (AI7075/CFRP 하이브리드 복합재료의 기계적강도 평가에 관한 연구)

  • 유재환
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.57-62
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    • 1997
  • The combined structure of hybrid composite made through the bonding process of materials of different properties greatly defines its mechanical characteristics, as the results of the experiments on materials of different properties show much dissimilarity. When carbon/epoxy materials are applied to hybrid composite, the carbon materials helps to improve the mechanical properties of the hybrid composite, and the epoxy reduces its fracture strain and impact resistance. Carbon fiber which is now in general commercialization is classified as high modulus or high strength system, and its manufacturing methods are various. The study of the materials having combined structure is focused on the numerical analysis of the layers of bonding surface in materials with difference modulus. The hybrid composite made through the multilayered bonding of reinforced aluminium sheets with aramid fiber now faces the marketing phase, and especially its excellent fatigue resistance and mechanical properties promote active researches on the similar products of hybrid composite. This study aims to investigate the effects of CFRP volume ratio and fiber's orientation over the properties of mechanical strength and fatigue life of the hybrid composite, AI7075/CFRP. To carry out this study, static tensile and fatigue tests were given to some of the panels which, made through the co-cure processing in an autoclave, have different CFRP volume ratio and carbon fiber orientations.

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