• Title/Summary/Keyword: hot pressing condition

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Effect of various MEA fabrication methods on the PEMFC durability testing at high and low humidity conditions (MEA 제조 방법에 따른 상대습도 변화가 PEMFC 내구성에 미치는 영향)

  • Kim, Kun-Ho
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.86.2-86.2
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    • 2010
  • In order to improve polymer electrolyte membrane fuel cell (PEMFC) durability, the durability of membrane electrode assemblies (MEA), in which the electrochemical reactions actually occur, is one of the vital issues. Many articles have dealt with catalyst layer degradation of the durability-related factors on MEAs in relation to loss of catalyst surface area caused by agglomeration, dissolution, migration, formation of metal complexes and oxides, and/or instability of the carbon support. Degradation of catalyst layer during long-term operation includes cracking or delamination of the layer which result either from change in the catalyst microstructure or loss of electronic or ionic contact with the active surface, can result in apparent activity loss in the catalyst layer. Membrane degradation of the durability-related factors on MEAs can be caused by mechanical or thermal stress resulting in formation of pinholes and tears and/or by chemical attack of hydrogen peroxide radicals formed during the electrochemical reactions. All of these effects, the mechanical damage of membrane and degradation of catalyst layers are more facilitated by uneven stress or improper MEA fabrication process. In order to improve the PEMFC durability, therefore, it is most important to minimize the uneven stress or improper MEA fabrication process in the course of the fabrication of MEA. We analyzed the effects of the MEA fabrication condition on the PEMFC durability with MEA produced using CCM (catalyst coated membrane) method. This paper also investigated the effects of MEA fabrication condition on the PEMFC durability by adding additional treatment process, hot pressing and pressing, on the MEA produced using CCM method.

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The study on the recycle for machined chips and scraps of AZ91 magnesium alloy (AZ91 마그네슘합금 절분 및 스크랩의 재활용에 관한 연구)

  • 이두면;이준서;이치환
    • Resources Recycling
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    • v.3 no.1
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    • pp.25-31
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    • 1994
  • This paper was focused to optimize hot extrusion condition of Mg machined chips and scraps as fundamental basic research for the recycle of Mg alloy. We have been performed to extrude at $300~380^{\circ}C$ temperature range under the extrusion ratio of 25:1 after cold-pressing AZ91 Mg machined chips and scraps. AZ91 Mg ingots was used as reference materials. Microstructure observation showed that the extruded machined chips were perfectly bonded and extruded materials became fine grain size($20\mu\textrm{m}$) by recrystallization during hot extrusion. The specimens extruded from the machined chips, scraps and Mg ingot indicated tensile strength of 330MPa and the elongation of 10% at room temperature.

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A Study on Synthesis and Mechanical Properties of (Ti.W)C Complex Carbide by SHS Chemical Furnace (SHS 화학로에 의한 (Ti.W)C 복탄화물의 합성 및 기계적 특성에 관한 연구)

  • 이형복;오유근;이풍헌;장동환
    • Journal of the Korean Ceramic Society
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    • v.33 no.4
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    • pp.418-424
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    • 1996
  • (Ti.W)C complex carbide was synthesized by self-propagating high temperature synthesis (SHS) chemical furnace. Attempt to find the optimal condition for synthesis of (Ti.W)C the effects of molar ratio of Ti:W:C on the synthesized powders and mechanical properties were investigated, Optimum molar ratio of these synthe-sized powder was Ti:W:C=0.7:0.2:1.0 The bulk density M,O.R Hardness Fracture toughness of (Ti.W)C complex carbide sintered at 200$0^{\circ}C$ for 60 min by hot-pressing under the pressure of 20 MPa were 7.6g/cm3, 475 MPa, 17,.7 GPa respectively.

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Consolidation Behavior of Ti-6Al-4V Powder by Spark Plasma Sintering (Spark plasma sintering에 의한 Ti-6Al-4V 합금분말의 성형성)

  • Kim, J.H.;Lee, J.K.;Kim, T.S.
    • Journal of Powder Materials
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    • v.14 no.1 s.60
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    • pp.32-37
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    • 2007
  • Using spark plasma sintering process (SPS), Ti-6Al-4V alloy powders were successfully consolidated without any contamination happened due to reaction between the alloy powders and graphite mold. Variation of microstructure and mechanical properties were investigated as a function of SPS temperature and time. Compared with hot isostatic pressing (HIP), the sintering time and temperature could be lowered to be 10 min. and $900^{\circ}C$, respectively. At the SPS condition, UTS and elongation were about 890 MPa and 24%, respectively. Considering the density of 98.5% and elongation of 24%, further improving the tensile strength would obtain by increasing the SPS pressure.

Development of Graphite Bushing for Bearing (베어링용 흑연재 Bushing 개발)

  • 김경자;조광연;정윤중;임연수
    • Journal of the Korean Ceramic Society
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    • v.34 no.8
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    • pp.797-802
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    • 1997
  • The use of carbon materials in mechanical components such as bearings, seals, and bushings that do not require lubricants is increasing rapidly. This paper reports on establishing the optimal condition for resin-bonded carbon materials. We fixed the content ratio of materials, which include graphite powder and diatomite as a lubricant modifier and a friction modifier, respectably, with resin used as a bonding material. We then produced bushings using hot-pressing within the temperature range of resin curing. The properties of bushing, the friction coefficient, wear rate and the mechanical strengths are discussed in relation to the content of respective materials, with correlation of friction coefficient and sliding distance. Finally, we examined the friction coefficient changes according to the applied load on bushing and the friction coefficient changes according to contact speed of bushing.

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Studies on the Properties of the Fiberboard - I. Hardboard (S-1-S) from Juvenile Wood of Sycamore (Platanus orientalis L.) (섬유판(纖維板)의 재질(材質)에 관한 연구(硏究) - I. 유령(幼齡)버즘나무를 원료(原料)로 한 경질섬유판(硬質纖維板))

  • Min, Du-Sik;Shin, Dong So
    • Journal of Korean Society of Forest Science
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    • v.26 no.1
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    • pp.57-65
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    • 1975
  • This study was carried out to examine the effect of manufacturing factors on physical properties of hardboard (S.I.S) made from the juvenile wood of sycamore (Platanus orientalis L.) The results obtained may be summarized as follows: 1. The difference among the yields of pulp treated with preheat time (defibrate condition) was significant in those of treatments. There was no difference in the yield of pulp treated with defibrate time. The yields of pulp on the tree age classes were shown the difference by 2<4<6<8 years. 2. The specific gravities of hardboard that were treated with hot pressing conditions showed us significantly in those of treatments. There was no difference on the specific gravities among hardboards, treated with resin and wax contents. But in all cases of the specific gravities satisfied the standard which specified the KS F 3203 (Hardboard) 3. The moisture contents of hardboard satisfied the standard which calls for 13-percent below. There were difference in moisture contents between hardboard, treated with preheating time, resin and wax contents and hot pressing conditions. And the moisture contents of hardboard on the tree age classes showed the difference by 2<4<6<8 years. 4. The water absorption and thickness swelling of hardboard treated with defibrations, resin and wax contents, and hot pressing conditions were significant in those of treatments. And the water absorption and thickness swelling of hardboard on the tree age classes showed us the significant difference by 8<6<4<2 years. 5. The difference among the flexural strength in using tested three conditions showed us the difference by defibration$200kg/cm^2$) of hardboard, it is likely to be recommened that the juvenile wood of sycamore is valuable for the raw materials of hardboards.

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Comparison of Fatigue Strength Criteria for TiNi/Al6061-T6 and TiNi/Al2024-T4 Shape Memory Alloy Composite (TiNi/Al6061-T6과 TiNi/Al2024-T4 형상기억복합재료에 대한 피로강도기준의 비교)

  • Jo, Young-Jik;Park, Young-Chul
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.2
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    • pp.99-107
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    • 2009
  • This study produced a design curve and fatigue limit for a variation in volume ratio and reduction ratio of TiNi/Al composites. In many cases, stress-life curve does not indicate fatigue limit, so it was presented by probabilistic-stress-life curve. Goodman diagram was used to analyze the fatigue strength of materials with a finite life determined by repeated load and the fatigue strength of endurance limit with an infinite life. The fatigue experiment was conducted using the scenk-type plane bending specimen in same shape. The result of the fatigue test, which had been conducted under consistent stress amplitude, was examined. (i) The optimal condition for TiNi/Al in accordance with hot pressing (ii) Impacts of fatigue limit caused by a variation in reduction ratio and volume ratio of TiNi/Al composites (iii) Probability distribution for fatigue limit of TiNi/Al2024 and TiNi/Al6061.

Effects of $SiO_2$ Particle-size on Fabrication Properties of LPS-SiC Ceramics (LPS-SiC 세라믹스의 제조특성에 미치는 $SiQ_2$ 입자크기의 영향)

  • Kim, Seong-Hoon;Yoon, Han-Ki;Kim, Bu-An
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2006.11a
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    • pp.162-165
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    • 2006
  • In this study, Liquid Phase Sintered SiC (LPS-SiC) was fabricated by hot pressing method with $\beta$-SiC powder whose a particle size is 30nm and less on the average in argon condition at 1780 and $1800^{\circ}C$ under 20MPa. Alumina ($Al_2O_3$), yttria ($Y_2O_3$) and silica ($SiO_2$) were used for sintering additives. To investigate effects of particle-size and temperature on $SiO_2$, LPS-SiC was fixed $Al_2O_3$, $Y_2O_3$ and then particle-size of $SiO_2$ were changed as two kinds. The system of particle-size and temperature on sintering additives which affects a property of sintering os well os the influence depending on particle-size and temperature of sintering additives were investigated by measurement of sintering properties. Such as measurement of sintering density, vikers hardness and observing of microstructure were investigated to make sure of the optimum condition which is about matrix of $SiC_f/SiC$ composites. Base on the composition of sintering additives, microstructure and sintering property correlation, the effect of particle-size of sintering additives are discussed. An experimental method to investigate the dynamic characteristics of bums in extreme environmental condition is established.

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Studies on Manufacture of Thin Composite Panel for Substitute Use of Plywood (I) - On the Optimum Manufacturing Condition of Composites - (합판대용(合板代用) 박판상(薄板狀) 복합재(複合材) 제조(製造)에 관(關)한 연구(硏究) (I) - 복합재(複合材) 제조(製造)의 최적조건(最適條件)에 관(關)하여 -)

  • Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.23 no.2
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    • pp.55-69
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    • 1995
  • The primary objective of this research was to investigate optimum manufacturing condition of thin composite panels composed of sawdust, polyethylene film and polypropylene net. At the study the experiment was designed to make thin board in which sawdust offers effectiveness as core composing material, polyethylene as adhesive with added urea resin, and polypropylene as stiffness and flexibility in the composition panel. 100 types of thin composite panels were manufactured according to press-lam and mat-forming process of various hot pressing conditions(pressure, temperature and time). They were tested and compared with control boards on bending properties(MOR, MOE, SPL, WML), internal bond strength, thickness swelling, linear expansion and water absorption. At the same time the visual inspections of each types of panels were accomplished. The physical and mechanical properties of composite types passed by visual inspection were analyzed by Tukey's studentized range test. From the statistical analysis, the optimum manufacturing condition of thin composite panels were selected. Compared with two manufacturing processes, mat-forming process performed better than press-lam process in all tested properties. The optimum manufacturing conditions resulted from the experiment and statistical analysis were able to determine as following: the press temperature was shown the most good result at 130$^{\circ}C$ in mat forming process and 140$^{\circ}C$ press lam process, the press time 4 min in both processes, but the press pressure was 25-10kg/$cm^2$ in mat forming and 15k/$cm^2$ press lam process.

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Design and Fabrication of Full-Scale Regenerative Cooling Combustion Chamber (${\varepsilon}$=12) of Liquid Rocket Engine for Ground Hot Firing Tests (지상연소시험용 실물형 재생냉각 연소기(확대비 12)의 설계 및 제작)

  • Kim, Jong-Gyu;Han, Yeoung-Min;Seo, Seong-Hyeon;Lee, Kwang-Jin;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.114-118
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    • 2007
  • Design and fabrication of a 30-tonf-class full-scale regenerative cooling combustion chamber of a liquid rocket engine for a ground hot firing test are described. It has chamber pressure of 60 bar and nozzle expansion ration of 12 and manufactured to have a single welded structure of· the mixing head and the chamber. The material of the mixing head is STS316L which has excellent mechanical property in cryogenic condition. The chamber comprise of the cylinder, nozzle throat, and 1st/2nd nozzle parts. The material of the inner jacket is copper alloy/STS329J1/STS316L and that of the outer jacket is STS329J1. The components of· the combustor were manufactured by mechanical processing including lathing, milling, MCT, rolling and pressing. The machined components were integrated to a single body by means of general welding, electron beam welding(EBW), and brazing.

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