• 제목/요약/키워드: highly efficient

검색결과 2,182건 처리시간 0.024초

Mild Isomerative Opening of Tetrahydrofuranyl Subunits in Steroids Using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to Synthesis of C17-OH Rockogenin Acetate

  • Lee, Jong-Seok;Kim, Byung-Sook;Shin, Jun-Ho;Lee, Yeon-Ju;Shin, Hee-Jae;Lee, Hyi-Seung
    • Bulletin of the Korean Chemical Society
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    • 제33권1호
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    • pp.76-82
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    • 2012
  • A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condition, making it generally applicable to many tetrahydrofuranyl steroids. Moreover, it is a synthetic equivalent of 'Marker degradation' affording an efficient synthesis of C17-OH rockogenin acetate.

One-Pot Fischer Indole 화합물의 효율적인 합성 (Highly Efficient and Facile Green Approach for One-Pot Fischer Indole Synthesis)

  • Chaskar, Atul;Deokar, Hrushikesh;Padalkar, Vikas;Phatangare, Kiran;Patil, S.K.
    • 대한화학회지
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    • 제54권4호
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    • pp.411-413
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    • 2010
  • HPA-phosphomolybdic acid 촉매 하에서, 아릴히드라진과 알데히드/케톤을 반응시켜서 치환기를 가지고 있는 indole 화합물을 효율적으로 합성할 수 있는 친환경적인 합성 방법을 개발하였으며, 이때 촉매는 독성이 없으며, 회수하여 재 사용할 수 있다.

Efficient Synthesis of Cylindol A and the Proposed Structure of Cylindol B: The Structure of Cylindol B Still in Question

  • Chang, Jay-Hyok;Nam, Do-Hyun;Shin, Hyun-Ik
    • Bulletin of the Korean Chemical Society
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    • 제29권5호
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    • pp.1003-1006
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    • 2008
  • Highly efficient syntheses of cylindol A (1) and the proposed structure of cylindol B (2) have been accomplished using common synthetic transformations from symmetrical starting materials 7 and 11, respectively. The latter synthesis revealed that the proposed structure of the natural cylindol B was assigned incorrectly. Isomers of 2 such as 15 and 16 were synthesized as a possible candidate of the natural cylindol B. However, their spectral data also did not match that of the natural cylindol B. Therefore, the structure of the natural cylindol B is yet to be resolved.

Hierarchical Multiplexing Interconnection Structure for Fault-Tolerant Reconfigurable Chip Multiprocessor

  • Kim, Yoon-Jin
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제11권4호
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    • pp.318-328
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    • 2011
  • Stage-level reconfigurable chip multiprocessor (CMP) aims to achieve highly reliable and fault tolerant computing by using interwoven pipeline stages and on-chip interconnect for communicating with each other. The existing crossbar-switch based stage-level reconfigurable CMPs offer high reliability at the cost of significant area/power overheads. These overheads make realizing large CMPs prohibitive due to the area and power consumed by heavy interconnection networks. On other hand, area/power-efficient architectures offer less reliability and inefficient stage-level resource utilization. In this paper, I propose a hierarchical multiplexing interconnection structure in lieu of crossbar interconnect to design area/power-efficient stage-level reconfigurable CMP. The proposed approach is able to keep the reliability offered by the crossbar-switch while reducing the area and power overheads. Experimental results show that the proposed approach reduces area by up to 21% and power by up to 32% when compared with the crossbar-switch based interconnection network.

Sole and Combined Usage of Ultra-sonication and Hydrogen Peroxide as Mitigation Techniques of Bio-fouling

  • Haque, Md. Niamul;Kwon, Sung-hyun
    • 한국환경과학회지
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    • 제25권10호
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    • pp.1397-1405
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    • 2016
  • Mussels are stubborn organism attached to solid substrate by byssus threads and caused operational problems in utility of power generating stations. Sole and combined usage of ultrasonic (28 kHz- and 42 kHz- frequencies) and hydrogen peroxide ($H_2O_2$) has studied for control of blue mussel larvae and adult stage in seawater condition. A theoretical wo rking model using disinfection (Chick and Watson type) approaches is presented based on helpful results of experiments. This study also demonstrate that the combined treatment (ultra-sonication with $H_2O_2$) is overall highly efficient than individual treatment would, but on the basis of exposure time, the ultra-sonication was the most efficient among them. Therefore the development of sole and combined technique might be effective practical mitigation strategy against mussel attachment for water handling facilities.

박판형 고효율 터보홴의 공력학적 설계 (Aerodynamic Design of Slim and High-efficient Turbo-Fan)

  • 이명재;김남욱;박덕준;조인수;이승배
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2600-2605
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    • 2008
  • Turbo-fans for a FFU unit should be aerodynamically designed to provide the FFU system with the given flow-rate at the lowest rotational-speed by considering the interaction effect with the FFU casing. In this study, slim and highly efficient turbo-fans are designed to satisfy the given performance at the specific speed by using the hybrid-stacking method of an inducer and a 2D-bladed turbo fan. The mean-line analysis, cascade theory, and CFD technique are all together applied to control the passage areas on the meridional plane from the inlet to the exit of the blade. Furthermore, the torque control algorithm is adopted to improve the performances within the constraints by the motor rpm-torque characteristics, and the resulting measured performances of mock-up fans are discussed.

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WiBro 시스템을 위한 효율적인 구조의 채널 복호화기 구현 (Implementation of Efficient Channel Decoder for WiBro System)

  • 김장훈;한철희
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2007년도 하계종합학술대회 논문집
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    • pp.177-178
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    • 2007
  • WiBro system provides reliable broadband communication services for mobile and portable subcribers. It allows interference-free reception under the conditions of multipath propagation and transmission errors. Thus, powerful channel-error correction ability Is required. CC/CTC Decoder which Is mandatory for WiBro system needs lots of computations for real-time operation. So, it is desired to design a CC/CTC Decoder having highly optimized hardware scheme for low latency operation under high data rates. This paper proposes an efficient CC/CTC Decoder structure for high data rate WiBro system. Particularly, the proposed CTC Decoder architecture reduces decoding delay by applying pipelining and multiple decoding blocks. Simulation results show that reduction of about 80% of processing time is enabled with the proposed CC/CTC Decoder despite of increase in are.

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An Efficient Method for N-Formylation of Amines Using Natural HEU Zeolite at Room Temperature Under Solvent-Free Conditions

  • Bahari, Siavash;Mohammadi-Aghdam, Babak;Mohammad Sajadi, S.;Zeidali, Fereshteh
    • Bulletin of the Korean Chemical Society
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    • 제33권7호
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    • pp.2251-2254
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    • 2012
  • A rapid and practical green route for N-formylation of primary and secondary amines with formic acid at room temperature under the solvent-free conditions using HEU zeolite as a heterogeneous, reusable and highly efficient catalyst is described. The process is remarkably simple and environmentally benign. Excellent chemoselectivity was observed for the conversion of primary amines in the presence of secondary amines.

Silica Gel을 이용한 효율적인 3,4-dihydropyrano[c]chromenes의 합성 (Silica Gel Promoted Mild, Efficient and Inexpensive Protocol for the Preparation of 3,4-dihydropyrano[c]chromenes)

  • Prasanna, T.S.R.;Raju, K. Mohana
    • 대한화학회지
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    • 제55권4호
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    • pp.662-665
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    • 2011
  • 실온에서 방향족 알데히드, 말론니트릴과4-히드록시쿠마린을neat 실리카젤 속에서 one-pot반응시켜서 3,4-dihydropyrano[c]chromenes을 좋은 수율로 합성하였다.

A Fast, Highly Efficient and Green Protocol for One-Pot Synthesis of 2,4,5-Trisubstituted Imidazoles Catalyzed by [TBA]2[W6O19] as a Reusable Heterogeneous Catalyst

  • Ashrafi, Mozhgan;Davoodnia, Abolghasem;Tavakoli-Hoseini, Niloofar
    • Bulletin of the Korean Chemical Society
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    • 제34권5호
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    • pp.1508-1512
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    • 2013
  • A simple and efficient synthesis of 2,4,5-trisubstituted imidazoles was achieved via a one-pot three-component cyclocondensation of benzil, aromatic aldehydes, and ammonium acetate in the presence of a catalytic amount of tetrabutylammonium hexatungstate $[TBA]_2[W_6O_{19}]$ as a heterogeneous catalyst under thermal solvent-free conditions. The key features of this methodology are operational simplicity, high yields, short reaction times, and a recyclable catalyst with a very easy work up.