• Title/Summary/Keyword: higher order solution

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Precise Estimation of Nonlinear Parameter in Pulse-Like Ultrasonic Signal (펄스형 초음파 신호에서 비선형 파라미터의 정밀 추정)

  • Ha, Job;Jhang, Kyung-Young;Sasaki, Kimio;Tanaka, Hiroaki
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.2
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    • pp.77-83
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    • 2006
  • Ultrasonic nonlinearity has been considered as a solution for the detection of microcracks or interfacial delamination in a layered structure. The distinguished phenomenon in nonlinear ultrasonics is the generation of higher-order harmonic waves during the propagation. Therefore, in order to quantify the nonlinearity, the conventional method measures a parameter defined as the amplitude ratio of a second-order harmonic component and a fundamental frequency component included in the propagated ultrasonic wave signal. However, its application In field inspection is not easy at the present stage because no standard methodology has yet been made to accurately estimate this parameter. Thus, the aim of this paper is to propose an advanced signal processing technique for the precise estimation of a nonlinear ultrasonic parameter, which is based on power spectral and bispectral analysis. The method of estimating power spectrum and bispectrum of the pulse-like ultrasonic wave signal used in the commercial SAM (scanning acoustic microscopy) equipment is especially considered in this study The usefulness of the proposed method Is confirmed by experiments for a Newton ring with a continuous air gap between two glasses and a real semiconductor sample with local delaminations. The results show that the nonlinear parameter obtained tv the proposed method had a good correlation with the delamination.

Production of L-DOPA by Thermostable Tyrosine Phenol-lyase of a Thermophilic Symbiobacterium Species Overexpressed in Recombinant Escherichia coli

  • Lee, Seung-Goo;Ro, Hyeon-Su;Hong, Seung-Pyo;Kim, Eun-Hwa;Sung, Moon-Hee
    • Journal of Microbiology and Biotechnology
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    • v.6 no.2
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    • pp.98-102
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    • 1996
  • A thermostable tyrosine phenol-lyase gene of a thermophilic Symbiobacterium species was cloned and overexpressed in Escherichia coli in order to produce the biocatalyst for the synthesis of 3, 4-dihy-droxyphenyl-L-alanine (L-DOPA). The substrates used for the synthetic reaction were pyrocatechol, so-dium pyruvate, and ammonium chloride. The enzyme was stable up to $60^{\circ}C$, and the optimal temperature for the synthesis of L-DOPA was $37^{\circ}C$ . The optimal pH of the reaction was about 8.3. Enzyme activity was highly dependent on the amount of ammonium chloride and the optimal concentration was estimated to be 0.6 M. In the case of pyrocatechol, an inactivation of enzyme activity was observed at con-centrations higher than 0.1 M. Enzyme activity was increased by the presence of ethanol. Under op-timized conditions, L-DOPA production was carried out adding pyrocatechol and sodium pyruvate to the reaction solution intermittently to avoid substrate depletion during the reaction. The concentration of L-DOPA reached 29.8 g/l after 6 h, but the concentration didn t increase further because of the formation of byproducts by a non-enzymatic reaction between L-DOPA and pyruvate.

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Effects of Tempering Treatment on Microstructure and Mechanical Properties of Cu-Bearing High-Strength Steels (템퍼링에 따른 Cu 첨가 고강도강의 미세조직과 기계적 특성)

  • Lee, Sang-In;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.550-555
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    • 2014
  • The present study deals with the effects of tempering treatment on the microstructure and mechanical properties of Cu-bearing high-strength steels. Three kinds of steel specimens with different levels of Cu content were fabricated by controlled rolling and accelerated cooling, ; some of these steel specimen were tempered at temperatures ranging from $350^{\circ}C$ to $650^{\circ}C$ for 30 min. Hardness, tensile, and Charpy impact tests were conducted in order to investigate the relationship of microstructure and mechanical properties. The hardness of the Cu-added specimens is much higher than that of Cu-free specimen, presumably due to the enhanced solid solution hardening and precipitation hardening, result from the formation of very-fine Cu precipitates. Tensile test results indicated that the yield strength increased and then slightly decreased, while the tensile strength gradually decreased with increasing tempering temperature. On the other hand, the energy absorbed at room and lower temperatures remarkably increased after tempering at $350^{\circ}C$; and after this, the energy absorbed then did not change much. Suitable tempering treatment remarkably improved both the strength and the impact toughness. In the 1.5 Cu steel specimen tempered at $550^{\circ}C$, the yield strength reached 1.2 GPa and the absorbed energy at $-20^{\circ}C$ showed a level above 200 J, which was the best combination of high strength and good toughness.

Synthesis of N-p-Nitrophenyl Poly(m-Phenylene Isophthalamide (N-p-Nitrophenyl Poly(m-Phenylene Isophthalamide)의 합성)

  • Hongbum Kim;Donghyun Kim;Jaewung Lee;Sangyeop Song;Nakjoong Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.2
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    • pp.249-254
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    • 1993
  • N-p-nitrophenyl poly(m-phenylene isophthalamide) was obtained from treatment of poly(m-phenylene isophthalamide) with sodium hydride in dimethyl sulfoxide followed by the addition of 1-fluoro-4-nitrobenzene in 43 wt% yield. Its inherent viscosity was 0.606 g/cm${\cdot}$sec determined from a solution of 0.125 g of the above polymer dissolved in 25 ml of 98% sulfuric acid at $30^{\circ}C.$ In order to synthesize poly(m-phenylene isophthalamide), 1,3-phenylenediamine is allowed to react with isophthaloyl chloride in chloroform in the presence of triethylamine and added triethylamine hydrochloride. The value of inherent viscosity is 0.560 g/cm${\cdot}$sec measured at the same condition. The substitution ratio of N-p-nitrophenyl poly(m-phenylene isophthalamide) was to be 16.7∼47.0% by using the $^1H-NMR$ integration. When the higher inherent viscosity of poly(m-phenylene isophthalamide) was used, lower substitution ratio would be calculated.

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Synthesis of Mesoporous Titanium Dioxide Nanoparticles and Their Application into Dye Sensitized Solar Cells (다공성 산화타이타늄 나노입자 합성과 염료감응형 태양전지 응용)

  • Kim, Whidong;Ahn, Jiyoung;Kim, Soohyung
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.64.2-64.2
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    • 2010
  • In order to improve the overall power conversion efficiency in dye-sensitized solar cells (DSSCs), it is very important to secure the sufficient surface area of photocatalytic nanoparticles layer for absorbing dye molecules. It is because increasing the amount of dye absorbed generally results in increasing the amount of light harvesting. In this work, we proposed a new method for increasing the specific surface area of photocatalytic titanium oxide ($TiO_2$) nanoparticles by using an inorganic templating method. Salt-$TiO_2$ composite nanoparticles were synthesized in this approach by spray pyrolyzing both the titanium butoxide and sodium chloride solution. After aqueous removal of salt from salt-$TiO_2$ composite nanoparticles, mesoporous $TiO_2$ nanoparticles with pore size of 2~50 nm were formed and then the specific surface area of resulting porous $TiO_2$ nanoparticle was measured by Brunauer-Emmett-Teller (BET) method. Generally, commercially available P-25 with the average primary size of ~25 nm $TiO_2$ nanoparticles was used as an active layer for dye-sensitized solarcells, and the specific surface area of P-25 was found to be ~50 $m^2/g$. On the other hand, the specific surface area of mesoporous $TiO_2$ nanoparticles prepared in this approach was found to be ~286 $m^2/g$, which is 5 times higher than that of P-25. The increased specific surface area of $TiO_2$ nanoparticles will absorb relatively more dye molecules, which can increase the short curcuit current (Jsc) in DSSCs. The influence of nanoporous structures of $TiO_2$ on the performance of DSSCs will be discussed in terms of the amount of dye molecules absorbed, the fill factor, the short circuit current, and the power conversion efficiency.

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A Study on the Multi-Stage Inventory System - Especially with the Inventory Management of Fisheries Processing Industries- (다단계 재고시스템에 관한 연구 -수산물가공업의 재고관리를 중심으로-)

  • 이강우
    • The Journal of Fisheries Business Administration
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    • v.21 no.2
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    • pp.55-84
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    • 1990
  • The objective of this study is to develop an inventory model for the inventory management of a stocking point which sells processed fisheries products. The study, first of all, sets up fisheries processing companies, food companies, apparel companies, pharmaceutical companies and electronic and electrical companies as a population. Then, a comparative study is empirically applied to obtain the inventory characteristics of final products by industry through a survey of a sample selected by a random sampling procedure. The major inventory characteristics of processed fisheries products obtained from the above analysis can be summarized as follows : 1) The major demand characteristics of processed fisheries products is to have wide seasonal fluctuations because the supply of raw materials (i.e., fisheries products) heavily depends on the productive capacity of nature. 2) It has found that fisheries processing companies are the worst in inventory management among the various industries selected in the sample. However, the self-rating of inventory management system by inventory managers of companies shows that the fisheries processing companies are relatively higher than the other companies. 3) The portion of inventory holding cost out of inventory relevant cost is very high for processed fisheries products compared with final products of the other industries. 4) Processed fisheries products are distributed to final consumers through roughly two distribution echelons and take a parallel type inventory system for their distribution structure. In order to develop an inventory model which reflects the inventory characteristics of processed fisheries products mentioned in the above, an inventory model with partial backorders is developed under the situation of stochastic lead time under the consideration of the inventory characteristics of processed fisheries products and then an iterative solution method is provided for the model. Then this study analyzes sensitivity for the standard deviation of lead time in the model by numerical examples.

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Adsorption Characteristics of Cr6+ and As3+ Using Seaweed Biochar (해초 Biochar를 이용한 Cr6+과 As3+ 흡착 특성)

  • Kim, Bo-Ra;Shin, Woo-Seok;Kim, Young-Kee
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.483-488
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    • 2015
  • This study examined the adsorption characteristics of $Cr^{6+}$ and $As^{3+}$ in the aqueous solution by Hizikia susiformis biochar which was collected from Jeju Island. The optimal pH for $Cr^{6+}$ and $As^{3+}$ adsorption were 2 and pH 6, respectively. Kinetic data showed that the adsorption occurred during the first 100 min, and the most of heavy metals were bound to biochars within 300 min. Moreover, the kinetic data presented that the course of adsorption follows the Pseudo first and second order models. The equilibrium data were well fitted by the Langmuir model and the $Cr^{6+}$ adsorption capacity (25.91 mg/g) was higher than that of $As^{3+}$ (16.54 mg/g). From these results, the seaweed biochar was shown to be a efficient adsorbent for $Cr^{6+}$ and $As^{3+}$ metals in a contaminated environment.

A Study on Relationships Between Residential Environments and the Social Maturity of Middle School Students (중학생의 주거 환경과 사회적 성숙도와의 관계 연구)

  • Kim, See-Hee;Kwark, Kyung-Sook
    • Korean Journal of Human Ecology
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    • v.19 no.1
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    • pp.215-225
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    • 2010
  • This study had the purpose of presenting a residential environment solution as a desirable educational environment for middle school students to grow soundly and to achieve proper self-realization while providing basic materials to build up a suitable residential environment by comparing and analyzing what relationships exist between different home backgrounds, residential environments and middle school students' social maturity. This research was conducted from Feb. 11, 2008 to Feb. 13, 2008. The subject of this research was 601 students in 3 middle schools located in Gyunggi-do. The data analyzed used the SPSS 11.5 version. The summary of this study's results is as follows. First, in terms of home background, the higher the parents' educational background and social and economic position, the greater the students' social maturity. Second, in terms of home environment, the more spacious the living space, the better the water and sewage system and rest room, the more convenient the air conditioner and kitchen system, the better the lighting, ventilation, soundproofness, insulation, the less the danger in relation to fire, crime, traffic accidents, disaster, the greater the students' social maturity. Third, in terms of the home environment related to the correlation between the residential environment and social maturity, all areas such as housing facilities, housing structural environment and housing safety showed static correlations and proved that the residential environment has an important influence on social maturity. Accordingly, in order to build up an ideal residential environment, we should make efforts to expand and improve better facilities at home considering privacy, lighting, ventilation, soundproofness, heating etc. and remove unsound factors that obstruct students social maturity and build up clean and safe residential environment with good relations with their neighbors.

A Study on the Method of revitalization for Fire Services' Organization - The Solution for Conflict Between Desk Officials and Outside Duty Ones - (소방공무원의 조직 활성화 방안에 관한 연구 - 내외근 간의 갈등을 중심으로 -)

  • Chae, Jin;Woo, Seong-Cheon
    • Fire Science and Engineering
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    • v.23 no.2
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    • pp.85-95
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    • 2009
  • The fire organization of civil servant is a specified public official job which traditionally is characterized by conservative attributes, highly emphasized with a hierarchical culture and the order from higher position. Such a special condition of the fire organization is seemingly regarded as a prerequisite of the occurrence especially prevalent of the systematic discord rather than the other system of a civil servant such as a common administrative job. The conflict among fire officials which is caused by the variety of effort that has been input in pursuit of making a desirable structure does not in progress or even though it dose, weakened by a counterbalance. Therefore, the goal of this research is inducing a plan to revitalize the fire organization through the corroborative analysis of the conflict between indoor duty and outdoor service ones. That is the reason of the disagreement, the device of getting rid of discord and so on.

The Instructional Effect of a Four-stage Problem Solving Approach Visually Emphasizing the Molecular Level of Matter upon Students' Conceptions and Problem Solving Ability (물질의 분자 수준을 시각적으로 강조하는 4단계 문제 해결식 수업이 학생의 개념과 문제 해결 능력에 미치는 효과)

  • Noh, Tae-Hee;Moon, Kyung-Moon
    • Journal of The Korean Association For Science Education
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    • v.17 no.3
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    • pp.313-321
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    • 1997
  • The purpose of this study was to investigate the instructional effect of a four-stage problem solving approach visually emphasizing the molecular level of matter upon students' conceptions and problem solving ability. On the basis of the research results regarding molecular representation in learning chemistry, problem-solving instruction, and the effect of visual materials, the instructional strategy was developed while considering Korean educational situations. The treatment and control groups (2 classes) were selected from a girls' high school in Seoul and taught about stoichiometry, gas, liquid, solid, and solution for 13 weeks. For the treatment group, 52 charts were supplied in order to emphasize the molecular level of matter and/or 4 stage problem solving strategy-understanding, planning, solving, and reviewing. For the control group, traditional instruction was used. Before the instructions, the Group Assessment of Logical Thinking and the Spatial Ability Test were administered, and their scores were used as covariate and blocking variable, respectively. After the instructions, students' conceptions and problem solving ability were measured by the Chemistry Conceptions Test (CCT) and the Chemistry Problem Solving Ability Test (CPSAT), respectively. The results indicated that the CCT scores of the treatment group were significantly higher than those of the control group. The students in the treatment group also exhibited less misconceptions than those in the control group. However, there was not significant difference for the CPSAT scores. No interaction with students' spatial ability was found for both students' conceptions and problem solving ability. Educational implications are discussed.

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