• Advances in environmental research
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• v.6 no.2
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• pp.113-125
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• 2017

Santa Barbara Amorphous-15(SBA-15) nanoparticles were utilized as the inexpensive and effective adsorbents to remove methylene blue dye from the aqueous solution.SBA-15 was created by Zhao et al method. Infrared spectroscopy, X-ray diffraction and scanning electron microscopy (SEM) were used for the evaluated physical properties of SBA-15. The results of diffraction X-ray indicated that was the crystalline structure for it. Also IR spectroscopy indicated was a silica the whole structure of the groups and SEM image verify the structure of relatively identical particles size of SBA-15. Factors affecting adsorption including the amounts of adsorbent, pH and contact time were investigated by a SBA-15 nanomaterial design. The extent of dye removal enhanced with increasing initial dye concentration and pH from 4 to 10. The higher percentage adsorption were obtained under optimum conditions of variables (sorbent dose of 200 mg/liter, initial MB concentration 10 mg/liter, initial pH of 10 and temperature of $25^{\circ}C$). Maximum adsorption happened after the 2 hour and the kinetic processes of the dyes adsorption were described by applying the pseudo-first-order and the pseudo-second-order and the relatively High correlation with the kinetic Ellovich models. It was found that the pseudo-second-order models kinetic equation described the data of dye adsorption with a good correlation (R2>0.999) which indicated chemisorption mechanism. Freundlich and Langmuir adsorption models were investigated in conditions of variables (adsorbent dose 0.01 gr/liter, MB concentration 10, 20, 30 mg/liter, pH of 4, 7, 10, contact time 90 min and temperature of $27^{\circ}C$). The adsorption data were represented by Langmuir isotherm model. These values are higher than the adsorption capacities of some other adsorbents that have recently been published in the literature.

• Journal of the Society of Naval Architects of Korea
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• v.39 no.1
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• pp.8-15
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• 2002

A two-dimensional higher order panel method using B-splines has been developed to overcome the disadvantages of the low order panel method and to obtain more accurate solution. The sources and the normal dipoles are distributed on both the body and the free surface. Instead of applying the upwind finite difference schemes to satisfy the linearized free surface and the radiation condition, the derivatives of the basis functions of the B-splines are directly applied to the linearized free surface condition. Numerical damping in the Dawson's method are avoided in the Present computations. In order to validate the present method, numerical computations are carried out for a submerged cylinder and a two-dimensional hydrofoil steadily moving beneath a free surface. The numerical results show that fast convergence and better accuracies have been achieved by the present method.

• Journal of Ocean Engineering and Technology
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• v.34 no.6
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• pp.406-418
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• 2020

In this study, a nonlinear wave simulation code is developed using a higher-order spectral (HOS) method. The HOS method is very efficient because it can determine the solution of the boundary value problem using fast Fourier transform (FFT) without matrix operation. Based on the HOS order, the vertical velocity of the free surface boundary was estimated and applied to the nonlinear free surface boundary condition. Time integration was carried out using the fourth order Runge-Kutta method, which is known to be stable for nonlinear free-surface problems. Numerical stability against the aliasing effect was guaranteed by using the zero-padding method. In addition to simulating the initial wave field distribution, a nonlinear adjusted region for wave generation and a damping region for wave absorption were introduced for wave generation simulation. To validate the developed simulation code, the adjusted simulation was carried out and its results were compared to the eighth order Stokes theory. Long-time simulations were carried out on the irregular wave field distribution, and nonlinear wave propagation characteristics were observed from the results of the simulations. Nonlinear adjusted and damping regions were introduced to implement a numerical wave tank that successfully generated nonlinear regular waves. According to the variation in the mean wave steepness, irregular wave simulations were carried out in the numerical wave tank. The simulation results indicated an increase in the nonlinear interaction between the wave components, which was numerically verified as the mean wave steepness. The results of this study demonstrate that the HOS method is an accurate and efficient method for predicting the nonlinear interaction between waves, which increases with wave steepness.

• Journal of Pharmaceutical Investigation
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• v.38 no.1
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• pp.31-38
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• 2008

The objective of this work is to study transdermal delivery of levodopa using iontophoresis and evaluate various factors which affect the transdermal transport. Levodopa is unstable in aqueous solution, and, in order to establish a stable condition for levodopa for the duration of experiment, we investigated the stability of levodopa in aqueous solutions of different pHs with/without the addition of dextrose or the application of current. Using stable aqueous solution, we have studied the effect of pH, polarity and penetration enhancer (ethanol) on transdermal flux and compared the results. We also investigated the iontophoretic flux from hydroxypropyl cellulose (HPC) hydrogel. In vitro flux study was performed at $33^{\circ}C$, using side-by-side diffusion cell. Full thickness hairless mouse skin and rat skin were used for this work. Current densities applied were 0.4 or $0.6mA/cm^2$ and current was off after 6 hour application. Stability study showed that levodopa solution with a pH 2.5 or 4.5 maintained the initial concentration of levodopa for 24 hours with the addition of 5% dextrose. However, at pH 9.5, levodopa was unstable and 30 to 40% of levodopa degraded within 24 hours, even with the addition of 5% dextrose. Hydrogel swollen with dextrose added levodopa solution maintained about 97% of the initial concentration of levodopa for 13 days, when stored in $4^{\circ}C$. The application of current did not affect the stability of levodopa in hydrogel. Flux study from levodopa solution with pH 2.5 showed that cathodal delivery of levodopa was higher than passive or anodal delivery. When the pH of the donor solution was 4.5, anodal delivery of levodopa was higher than passive or cathodal delivery. These results seem to indicate that electroosmosis plays more dominant role than electrorepulsion in the flux of levodopa at pH 2.5, and the reverse situation applies for pH 4.5. The passive flux was unexpectedly high for the ionized levodopa. Similar to the results from aqueous solution, cumulative amount of levodopa transported trom HPC hydrogel by cathodal delivery was significantly higher than passive or anodal delivery. The treatment of 70% ethanol cotton ball by scrubbing increased passive, anodal and cathodal flux, with the largest increase for anodal flux. These results indicate that iontophoretic delivery of zwitterion such as levodopa is much complicated than that can be expected from small ionic molecules with single charge. The results also indicate that the balance between electroosmosis and electrorepulsion plays a very important role in the transport through skin.

• Structural Engineering and Mechanics
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• v.6 no.6
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• pp.583-612
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• 1998

A unified third-order laminate plate theory that contains classical, first-order and third-order theories as special cases is presented. Analytical solutions using the Navier and L$\acute{e}$vy solution procedures are presented. The Navier solutions are limited to simply supported rectangular plates while the L$\acute{e}$vy solutions are restricted to rectangular plates with two parallel edges simply supported and other two edges having arbitrary combination of simply supported, clamped, and free boundary conditions. Numerical results of bending and vibration for a number of problems are discussed in the second part of the paper.

• Publications of The Korean Astronomical Society
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• v.13 no.1 s.14
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• pp.167-180
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• 1998

We have carried out high precision orbit calculation, by using various numerical techniques with accuracy of higher than fourth order, in order for exact prediction on position and velocity of celestial bodies and artificial satellites. General second order ordinary differential equation has been solved numerically to test the performance for each of numerical methods. We have compared computed values with exact solution obtained by using universal variables for two body problem and discussed overall results of numerical methods used in our calculation. As a result, it is found that high order difference table method called as Gauss-Jackson method is best one with easiness and efficiency in the increase of accuracy by number of initial values.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.20 no.4
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• pp.295-308
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• 2016

We propose a projection-based analysis of a new hybridizable discontinuous Gale-rkin method for second order elliptic equations. The method is more advantageous than the standard HDG method in a sense that the new method has higher-order accuracy and lower computational cost, and is more flexible. Notable distinctions of our new method, when compared to the standard HDG emthod, are that our method uses $L^2$-projection and suitable stabilization parameter depending on a mesh size for superconvergence. We show that the error for the solution of the equation converges with order p + 2 when we only use polynomials of degree p + 1 as a finite element space without postprocessing. After establishing the theory, we carry out numerical tests to demonstrate and ensure that the proposed method is effective and accurate in practice.

• Membrane Journal
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• v.23 no.5
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• pp.343-351
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• 2013

This study is to investigate the effects of the draw solution concentration on forward osmosis desalination performance using blended fertilizer as draw solution. As the concentration of blended fertilizer solution (draw solution) increased, the water permeate flux increased nearly linearly, but PR (performance ratio) was reduced. Using sea water and deionized water as the feed solution, respectively, at the blended fertilizer solution of 600 g/L $H_2O$, the PR obtained were 5.39 and 6.50, respectively. And as the concentration of blended fertilizer solution increased, the reverse solute flux for nitrogen (N), phosphorus (P), and potassium (K) increased nearly linearly, but specific reverse solute flux for them was reduced. The reverse solute flux and specific reverse solute flux became higher in the order of N > K > P.

• Analytical Science and Technology
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• v.9 no.4
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• pp.406-410
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• 1996

The adsorption behaviors of transition metal ions on the poly(N,N'-bispalmitoyl-1, 12-diaza-3, 4;9,10-dibenzo-5,8-cyclopentadecane) has been determined by adsorption process in aqueous solution. The order of concentration factor(CF) and the amount of adsorption were Cu(II)

• Journal of the Korean Chemical Society
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• v.62 no.5
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• pp.364-371
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• 2018

Inhibition effects of alanine (Ala), histidine (His), methionine (Met) on the corrosion of aluminum were investigated in deaerated 0.5 M HCl and NaCl solution. In HCl solution the inhibition efficiency for the aluminum corrosion depended on the cathodic inhibition, and the inhibition efficiency was increased in the order of Met$10^{-4\;}M$ the adsorption process can be explained by Langmuir isotherm, however, in the case of higher concentration by Temkin logarithmic isotherm due to the interaction between the adsorbed molecules.