• 한국세라믹학회지
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• 제55권1호
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• pp.50-54
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• 2018

This study investigated the long-term durability of catalyst(Pd or Fe)-infiltrated solid oxide cells for $CO_2$/steam co-electrolysis. Fuel-electrode supported solid oxide cells with dimensions of $5{\times}5cm^2$ were fabricated, and palladium or iron was subsequently introduced via wet infiltration (as a form of PdO or FeO solution). The metallic catalysts were employed in the fuel-electrode to promote $CO_2$ reduction via reverse water gas shift reactions. The metal-precursor particles were well-dispersed on the fuel-electrode substrate, which formed a bimetallic alloy with Ni embedded on the substrate during high-temperature reduction processes. These planar cells were tested using a mixture of $H_2O$ and $CO_2$ to measure the electrochemical and gas-production stabilities during 350 h of co-electrolysis operations. The results confirmed that compared to the Fe-infiltrated cell, the Pd-infiltrated cell had higher stabilities for both electrochemical reactions and gas-production given its resistance to carbon deposition.

• 대한기계학회논문집B
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• 제33권9호
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• pp.709-717
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• 2009

Heat transfer rate is a very important factor for the performance of a steam reformer because a steam reforming reaction is an endothermic reaction. Coaxial cylindrical reactor is the reactor design which can improve the heat transfer rate. Temperature, fuel conversion and heat flux in the coaxial cylindrical steam reformer are studied in this paper using numerical method under various operating conditions. Langmuir-Hinshelwood model and pseudo-homogeneous model are incorporated for the catalytic surface reaction. Dominant chemical reactions are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming (DSR) reaction. Although coaxial cylindrical steam reformer uses 33% less amount of catalyst than cylindrical steam reformer, its fuel conversion is increased 10 % more and its temperature is also high as about 30 degree. There is no heat transfer limitation near the inlet area at coaxial-type reactor. However, pressure drop of the coaxial cylindrical reactor is 10 times higher than that of cylindrical reactor. Operating parameters of coaxial cylindrical steam reformer are the wall temperature, the inlet temperature, and the Gas Hourly Space Velocity (GHSV). When the wall temperature is high, the temperature and the fuel conversion are increased due to the high heat transfer rate. The fuel conversion rate is increased with the high inlet temperature. However, temperature drop clearly occurs near the inlet area since an endothermic reaction is active due to the high inlet temperature. When GHSV is increased, the fuel conversion is decreased because of the heat transfer limitation and short residence time.

• Journal of the Optical Society of Korea
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• 제6권1호
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• pp.5-12
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• 2002

A novel interrogation scheme to detect fine Bragg wavelength shift using a long period fiber grating pair with erbium-doped fiber inserted between the two gratings is reported. The technique is shown to feature high resolution and much more immunity to temperature perturbation compared to the conventioned Mach-Zehnder interferometer demodulation system. For quasi-static strain measurement, this approach provides high wavelength resolution of 0.05 pm that corresponds to 41.7 ne in strain and $3.8 $\times$ 10^{-3}$$^{\circ}C$ in temperature. This interrogation system is also employed in dynamic measurement to obtain the minimum detectable strain perturbation of ~ 8.76 ne/H $z^{{\frac}{1}{2}}$ at 100 Hz. Moreover, this interrogation system has prominent thermal stability. This thermal stability comes from the fact that two arms of the interferometer, the core and cladding in erbium-doped fiber, are exposed to nearly the same environment .

• 한국공작기계학회:학술대회논문집
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• 한국공작기계학회 2000년도 춘계학술대회논문집 - 한국공작기계학회
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• pp.326-331
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• 2000

In this study, residual stress was investigated experimentally to evaluate damaged layer in high-sped machining. In machining difficult-to-cut material, residual stress remaining in machined surface was mainly speared as compressive stress. The scale of this damaged layer depends upon cutting speed, feed per tooth and radial cutting depth. Damaged layer was measured by optical microscope. The micro-structure of damaged layer was a mixed maternsite and austenite. depth of damaged layer is increased with increasing of cutting temperature, cutting force and radial depth. On the other hand, that is slightly decreased with decreasing of cutting force. The increase of tool wear causes a shift of the maximum residual stress in machined surface layer.

• 한국표면공학회지
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• 제47권6호
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• pp.303-310
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• 2014

In this study, the average in-situ stress in metallic thin film was measured during deposition of the Cu thin films on the Si(111) wafer and then the phenomenon of stress shift by the interruption of deposition was measured using Cu thin films. We have observed the stress shift in accordance with changing amount of atom's movement between the surface and grain boundary through altering the grain size of the Cu thin film with variety of parameters. The grain size is known to be affected on the deposition rate, film thickness and deposition temperature. As a experimental results, the these parameters was not adequate to explain stress shift because these parameters affect directly on the amount of atom's movement between the surface and grain boundary as well as the grain size. Thus, we have observed the stress shift toward tensile side in accordance with the grain size changing through the interlayer deposition. From an experiment with inserting interlayer before deposit Cu, in thin film which has big grain size with high roughness, amount of stress movement is higher along direction of tensile stress after deposition that means, after deposition process, driving force of atoms moving in grain boundary and on the surface of the film is relatively higher than before.

• Steel and Composite Structures
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• 제43권3호
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• pp.341-351
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• 2022

This paper presents an inelastic buckling behavior analysis of rectangular hollow steel tubes with geometrical imperfections under elevated temperatures. The main variables are the temperature loads, slenderness ratios, and exposure conditions at high temperatures. The material and structural properties of steels at different temperatures are based on Eurocode (EN 1993-1-2, 2005). In the elastic buckling analysis, the buckling strength decreases linearly with the exposure conditions, whereas the inelastic buckling analysis shows that the buckling strength decreases in clusters based on the exposure conditions of strong and weak axes. The buckling shape of the rectangular steel column in the elastic buckling mode, which depicts geometrical imperfection, shows a shift in the position at which bending buckling occurs when the lower section of the member is exposed to high temperatures. Furthermore, lateral torsional buckling occurs owing to cross-section deformation when the strong axial plane of the model is exposed to high temperatures. The elastic buckling analysis indicates a conservative value when the model is exposed to a relatively low temperature, whereas the inelastic buckling analysis indicates a conservative value at a certain temperature or higher. The comparative results between the inelastic buckling analysis and Eurocode 3 show that a range exists in which the buckling strength in the design equation result is overestimated at elevated temperatures, and the shapes of the buckling curves are different.

• 대한전자공학회논문지TC
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• 제42권9호
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• pp.1-10
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• 2005

본 논문에서는 디지털 방식으로 온도에 의한 왜곡을 보상할 수 있는 사전왜곡제거기 알고리듬을 제안하였다. 사전왜곡제거 알고리듬은 입력레벨에 따른 시스템 비선형 왜곡뿐만 아니라 온도에 따른 왜곡의 보상성분을 산출하여 베이스밴드 영역의 디지털 신호를 사전 왜곡함으로써 발생하는 왜곡을 상쇄시키는 알고리듬이다. 이와 같은 알고리듬의 우수성을 증명하기 위해 Saleh의 고출력 증폭기 모델에 적용하여 컴퓨터 모의실험을 한 결과, 기존의 A&P PD 방식보다 P1dB는 약 0.5dBm 증가하였고, 위상천이는 약 $0.8^{o}$ 감소하였으며, 온도보상 기법을 적용한 사전왜곡제거기 로 증폭기의 PldB를 약 2dBm 개선하였고, 위상천이는 약$0.1^{o}$ 이하로 안정시켰다. 또한 이 증폭기에 UMTS 신호 샘플을 인가 시 온도보상 기법을 적용한 사전왜곡 제거기의 IMD3가 온도보상 기법을 적용하지 않은 경우보다 10dBm 감소하였으며, 왜곡제거기가 없는 신호보다 19dBm 감소시킴으로써 우수한 선형성을 보였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.122-122
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• 2008

Recently, Metal/Alumina/Silicon-Nitride/Silicon-Oxide/Silicon (MANOS) structures are one of the most attractive candidates to realize vertical scaling of high-density NAND flash memory [1]. However, as ANO layers are miniaturized, negative and positive bias temperature instability (NBTI/PBTI), such as the flat band voltage shift, ${\Delta}V_{FB}$, the interfacial trap density increase, ${\Delta}D_{it}$, the gate leakage current, ${\Delta}I_G$. and the retention characteristics, in MONOS capacitors, becomes an important issue in terms of reliability. It is well known that tunnel oxide degradation is a result of the oxide and interfacial traps generation during FN (Fowler-Nordheim) stress [2]. Because the bias temperature stress causes an increase of both interfacial-traps and fixed oxide charge could be a factor, witch can degrade device reliability during the program and erase operation. However, few studies on NBTI/PBTI have been conducted on improving the reliability of MONOS devices. In this work, we investigate the effect of post-annealing gas on bias temperature instability (BTI), such as the flat band voltage shift, ${\Delta}V_{FB}$, the interfacial trap density shift, ${\Delta}I_G$ retention characteristics, and the gate leakage current characteristics of MANOS capacitors. MANOS samples annealed at $950^{\circ}C$ for 30 s by a rapid thermal process were treated via additional annealing in a furnace, using annealing gases $N_2$ and $N_2-H_2$ (2 % hydrogen and 98 % nitrogen mixture gases) at $450^{\circ}C$ for 30 min. MANOS samples annealed in $N_2-H_2$ ambient had the lowest flat band voltage shift, ${\Delta}V_{FB}$ = 1.09/0.63 V at the program/erase state, and the good retention characteristics, 123/84 mV/decade at the program/erase state more than the sample annealed at $N_2$ ambient.

• 마이크로전자및패키징학회지
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• 제24권1호
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• pp.57-65
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• 2017

모바일 기기 내부에 있는 전자부품들은 반도체 칩이나 그 밖의 여러 가지 재료로 구성되어 있다. 이러한 전자부품들은 매우 얇고, 구성된 재료들은 다양한 열팽창 계수를 가지고 있으므로 온도 변화나 외부 하중에 의해서 쉽게 굽힘이 일어난다. 그림자 무아레 방법은 비접촉으로 전체 영역에 걸친 면외변위를 측정하는 광학적 방법이지만 측정 감도를 $50{\mu}m/fringe$ 이내로 하기 어려워서 반도체 패키지의 굽힘변형을 측정하기에는 적당하지 않은 면이 있었다. 본 논문에서는 그림자 무아레 기법의 여러 실험조건들을 최적화하여 $25{\mu}m/fringe$의 향상된 감도를 갖는 측정 방법을 구현하였다. 또한 이로부터 위상이동에 의해 기록되는 4장의 그림자 무늬를 영상 처리하여 감도가 4배 향상된 그림자 무늬를 얻어내고 이를 스마트폰의 소형 전자부품들에 적용하여 온도변화에 따라 발생하는 굽힘 변위를 $5{\mu}m/fringe$의 고감도로 측정하였다.

• Journal of Information Display
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• 제13권1호
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• pp.37-42
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• 2012

An empirical functional form was suggested for the analysis of the emission spectrum of high-power light-emitting diode (LED) consisting of a sharp blue peak from the LED chips and a broad yellow peak from the phosphor layer. The peak positions, half widths, shape parameters, and amplitudes of these two peaks were reliably obtained as a function of the temperature, and the results were discussed qualitatively in relation with the junction temperature. The adoption of an inert liquid was found to have significantly reduced the LED temperature and the color shift of the emitted light. The phenomenological approach used in this study may be helpful in the simulation of the LED spectrum under various thermal conditions, and may thus be helpful in the improvement of the device performance.