• Title/Summary/Keyword: high-order diffusion

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Combustion Characteristics and Soot Formation in a Jet Diffusion Flame (제트 확산화염의 연소특성과 매연생성에 관한 연구)

  • 이교우;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2712-2723
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    • 1994
  • Numerical simulation of an axisymmetric ethylene-air jet diffusion flame has been carried out in order to investigate flame dynamics and soot formation. The model solves the time-dependent Navier-Stokes equations and includes models for soot formation, chemical reaction, molecular diffusion, thermal conduction, and radiation. Numerically FCT(Flux Corrected Transport) and DOM(Discrete Ordinate Method) methos are used for convection and radiation trasport respectively. Simulation was conducted for a 5 cm/sec fuel jet flowing into a coflowing air stream. The maximum flame temperature was found to be approximately 2100 K, and was located at an axial position of approximately 5 cm from the base of the flame. The maximum soot volume fraction was about $7{\times}10^{-7}$, and was located within the high temperature region where the fuel mole fraction ranges from 0.01 to 0.1. The buoyancy-driven low-frequency(12~13 Hz) structures convected along the outer region of the flame were captured. In case without radiation trasport, the maximum temperature was higher by 150 K than in case with radiation. Also the maximum soot volume fraction reached about $8{\times}10^{-6}$. As the the hydrocarbon fuel forms many soot particles, the radiation transport becomes to play a more important role.

Chloride Penetration Resistance of Concrete Mixed with High Volume Blast Furnace Slag (고르슬래그미분말을 다량 혼입한 콘크리트의 염분침투저항성)

  • Park, Ki-Cheol;Kim, Dong-Hun;Park, Shin;Lim, Nam-Gi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.11a
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    • pp.40-41
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    • 2014
  • As a result of strength test on BFS concrete, those mixed with 30% and 50% of BFS8000, respectively, showed higher or equivalent strength compare to OPC. As a result of test of chloride penetration on BFS, diffusion coefficients of concrete mixed with 30% FA4000 and FA5000, respectively, showed to restrain average 6.5% of diffusion coefficient compared to OPC. And in case of BFS concrete, those mixed with BFS6000 and BFS8000, restrained diffusion of chloride ions 253% and 336%, respectively, compared to OPC. Therefore, Mixing 50% of BFS was most efficient in order to maximize restraint of chloride penetration according to metathesis of large amount. In this study, when mixing BFS to concrete for long-run durability and restraint against chloride penetration, for BFS, as fineness was higher and mixing it to concrete with less or equivalent 50% of replacement rate, there were results of higher strength compared to OPC and more efficient restraint of chloride ions.

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Applicability of Theoretical Adsorption Models for Studies on Adsorption Properties of Adsorbents(II) (흡착제의 흡착특성 규명을 위한 흡착모델의 적용성 평가(II)-흡착속도론을 중심으로)

  • Na, Choon-Ki;Park, Hyun-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.804-811
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    • 2011
  • The aim of this study is to evaluate the applicability of adsorption models for understanding adsorption properties of adsorbents. For this study, the adsorption charateristics of $NO_3^-$ by commercial anion exchange resin, PA-308, were investigated in bach process. The adsorption kinetic data for $NO_3^-$ by anion exchange resin showed two stage process comprising a fast initial adsorption process and a slower second adsorption process. Both the pseudo-first-order kinetic model and the pseudo-second-order kinetic model could not be used to predict the adsorption kinetics of $NO_3^-$ onto anion exchange resin for the entire sorption period. Only the fast initial portion ($t{\leq}20min$) of adsorption kinetics was found to follow pseudo-first-order kinetic model and controlled mainly by external diffusion that is very fast and high, whereas, the slower second portion (t > 20 min) of adsorption kinetics seems to be controlled by a second-order chemical reaction and by intraparticle diffusion.

Role of Buffer Layer in Ba-Ferrite/α-Al2O3/SiO2 Magnetic Thin Films (Ba-페라이트/α-Al2O3/SiO2 자성박막에서 버퍼층의 역할)

  • Cho, Tae-Sik
    • Journal of the Korean Magnetics Society
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    • v.16 no.6
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    • pp.283-286
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    • 2006
  • We have studied the role of ${\alpha}-Al_{2}O_{3}$ buffer layer as a diffusion barrier in the Ba-ferrite/$SiO_{2}$ magnetic thin films for high-density recording media. In the interface of amorphous Ba-ferrite $(1900-{\AA}-thick)/SiO_{2}$ thin film during annealing, the interfacial diffusion started to occur at ${\sim}700^{\circ}C$. As the annealing temperature increased up to $800^{\circ}C$, the interfacial diffusion abruptly proceeded resulting in the high interface roughness and the deterioration of the magnetic properties. In order to control the interfacial diffusion at the high temperature, we introduced ${\alpha}-Al_{2}O_{3}$ buffer layer ($110-{\AA}-thick$) in the interface of Ba-ferrite/$SiO_{2}$ thin film. During the annealing of Ba-ferrite/${\alpha}-Al_{2}O_{3}/SiO_{2}$ thin film even at ${\sim}800^{\circ}C$, the interface was very smooth. The magnetic properties, such as saturation magnetization and intrinsic coercivity, were also enhanced, due to the inhibition of interfacial diffusion by the ${\alpha}-Al_{2}O_{3}$ buffer layer. Our study suggests that the ${\alpha}-Al_{2}O_{3}$ buffer layer act as a useful interfacial diffusion barrier in the Ba-ferrite/$SiO_{2}$ magnetic thin films.

Thromboembolic Events after Coil Embolization of Cerebral Aneurysms : Prospective Study with Diffusion-Weighted Magnetic Resonance Imaging Follow-up

  • Chung, Seok-Won;Baik, Seung-Kug;Kim, Yong-Sun;Park, Jae-Chan
    • Journal of Korean Neurosurgical Society
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    • v.43 no.6
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    • pp.275-280
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    • 2008
  • Objective : In order to assess the incidence of thromboembolic events and their clinical presentations, the present study prospectively examined routine brain magnetic resonance images (MRI) taken within 48 hours after a coil embolization of cerebral aneurysms. Methods : From January 2006 to January 2008, 163 cases of coil embolization of cerebral aneurysm were performed along with routine brain MRI, including diffusion-weighted magnetic resonance (DW-MR) imaging, within 48 hours after the embolization of the aneurysm to detect the silent thromboembolic events regardless of any neurological changes. If any neurological changes were observed, an immediate brain MRI follow-up was performed. High-signal-intensity lesions in the DW-MR images were considered as acute thromboembolic events and the number and locations of the lesions were also recorded. Results : Among the 163 coil embolization cases, 98(60.1%) showed high-signal intensities in the DW-MR imaging follow-up, 66 cases (67.0%) involved the eloquent area and only 6cases (6.0%) showed focal neurological symptoms correlated to the DW-MR findings. The incidence of DW-MR lesions was higher in older patients (${\geq}60$ yrs) when compared to younger patients (<60 yrs) (p=0.002, odd's ratio=1.043). The older patients also showed a higher incidence of abnormal DW-MR signals in aneurysm-unrelated lesions (p=0.0003, odd's ratio=5.078). Conclusion : The incidence of symptomatic thromboembolic attacks after coil embolization of the cerebral aneurysm was found to be lower than that reported in previous studies. While DW-MR imaging revealed a higher number of thromboembolic events, most of these were clinically silent and transient and showed favorable clinical outcomes. However, the incidence of DW-MR abnormalities was higher in older patients, along with unpredictable thromboembolic events on DW-MR images. Thus, in order to provide adequate and timely treatment and to minimize neurological sequelae, a routine DW-MR follow-up after coil embolization of cerebral aneurysms might be helpful, especially in older patients.

A Ternary Polymeric Matrix System for Controlled Drug Delivery of Highly Soluble Drug with High Drug Loading : Diltiazem Hydrochloride (염산 딜티아젬의 방출을 제어하기 위한 삼중 폴리머 매트릭스 시스템)

  • Kim, Hyun-Jo;Fassihi, Reza
    • Journal of Pharmaceutical Investigation
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    • v.31 no.1
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    • pp.19-25
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    • 2001
  • The purpose of this study was to use a ternary polymeric matrix system for high drug loading of a highly soluble drug for controlled release delivery. The controlled drug delivery of diltiazem HCl (solubility > 50% in water at $25^{\circ}C$) with high loading dose (the final loading dose of drug was 34%) from a ternary polymeric matrix (gelatin, pectin, HPMC) was successfully accomplished. This simple monolithic system with 240 mg drug loading provided near zero-order release over a 24 hour-period by which time the system was completely dissolved. The release kinetics of diltiazem HCl tablet with high loading dose from the designed ternary polymeric system was dependent on the ratios of HPMC : pectin binary mixture. The release rate increased as pectin : HPMC ratio were increased. Swelling behavior of the ternary system and the ionic interaction of formulation components with cationic diltiazem molecule appear to control drug diffusion and the release kinetics. Comparable release profiles between commercial product and the designed system were obtained. The binding study between gelatin with diltiazem HCl showed the presence of two binding sites for drug interaction with subsequent controlled diffusion upon swelling. This designed delivery system is easy to manufacture and drug release behavior is highly reproducible and offers advantages over the existing commercial product.

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Applications of Innovation Adoption and Diffusion Theory to IPTV Loyalty Formation Process (혁신 수용확산 이론의 IPTV 충성도 형성 프로세스 응용)

  • Han, Hyun-Soo;Joung, Seok-In;Park, Woo-Sung
    • The Journal of Society for e-Business Studies
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    • v.16 no.4
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    • pp.335-357
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    • 2011
  • In this paper, we report the empirical study results theorizing IPTV user's loyalty formation process. Considering the convergent characteristics ofinnovative media and telecommunication, we employed innovation adoption and diffusion as our theoretical framework for research model development. As the purpose of this research includes verification of detail attributes of IPTV service, we formulated structural model which treats relative advantage as the second order factor, of which incorporates the seven detail attributes as the first order factors. Then, using the data collected from 250 Korean IPTV subscribers, the model is validated and relevant attributes are identified through PLS analysis. The results provide insights for future research on the adoption and diffusion of new digital convergent high-tech services.

Forging of 1.9wt%C Ultrahigh Carbon Workroll : Part II - Void Closure and Diffusion Bonding (1.9wt%C 초고탄소 워크롤 단조 공정 : Part II - 기공압착 및 확산접합)

  • Kang, S.H.;Lim, H.C.;Lee, H.
    • Transactions of Materials Processing
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    • v.22 no.8
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    • pp.463-469
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    • 2013
  • In the previous work, a new forging process design, which included incremental upsetting, diffusion bonding and cogging, was suggested as a method to manufacture 1.9wt%C ultrahigh carbon workrolls. The previous study showed that incremental upsetting and diffusion bonding are effective in closing voids and healing of the closed void. In addition, compression tests of the 1.9wt%C ultrahigh carbon steel revealed that new microvoids form within the blocky cementite at temperatures of less than $900^{\circ}C$ and that local melting can occur at temperatures over $1120^{\circ}C$. Thus, the forging temperature should be controlled between 900 and $1120^{\circ}C$. Based on these results, incremental upsetting and diffusion bonding were used to check whether they are effective in closing and healing voids in a 1.9wt%C ultrahigh carbon steel. The incremental upsetting and diffusion bonding were performed using sub-sized specimens of 1.9wt%C ultrahigh carbon steel. The specimen was deformed only in the radial direction during the incremental upsetting until the reduction ratio reached about 45~50%. After deformation the specimens were kept at $1100^{\circ}C$ for the 1 hour in order to obtain a high bonding strength for the closed void. Finally, microstructural observations and tensile tests were conducted to investigate void closure behavior and bonding strength.

Ex Vivo MR Diffusion Coefficient Measurement of Human Gastric Tissue (인체의 위 조직 시료에서 자기공명영상장치를 이용한 확산계수 측정에 대한 기초 연구)

  • Mun Chi-Woong;Choi, Ki-Sueng;Nana Roger;Hu, Xiaoping P.;Yang, Young-Il;Chang Hee-Kyung;Eun, Choong-Ki
    • Journal of Biomedical Engineering Research
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    • v.27 no.5
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    • pp.203-209
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    • 2006
  • The aim of this study is to investigate the feasibility of ex vivo MR diffusion tensor imaging technique in order to observe the diffusion-contrast characteristics of human gastric tissues. On normal and pathologic gastric tissues, which have been fixed in a polycarbonate plastic tube filled with 10% formalin solution, laboratory made 3D diffusion tensor Turbo FLASH pulse sequence was used to obtain high resolution MR images with voxel size of $0.5{\times}0.5{\times}0.5mm^3\;using\;64{\times}32{\times}32mm^3$ field of view in conjunction with an acquisition matrix of $128{\times}64{\times}64$. Diffusion weighted- gradient pulses were employed with b values of 0 and $600s/mm^2$ in 6 orientations. The sequence was implemented on a clinical 3.0-T MRI scanner(Siemens, Erlangen, Germany) with a home-made quadrature-typed birdcage Tx/Rx rf coil for small specimen. Diffusion tensor values in each pixel were calculated using linear algebra and singular value decomposition(SVD) algorithm. Apparent diffusion coefficient(ADC) and fractional anisotropy(FA) map were also obtained from diffusion tensor data to compare pixel intensities between normal and abnormal gastric tissues. The processing software was developed by authors using Visual C++(Microsoft, WA, U.S.A.) and mathematical/statistical library of GNUwin32(Free Software Foundation). This study shows that 3D diffusion tensor Turbo FLASH sequence is useful to resolve fine micro-structures of gastric tissue and both ADC and FA values in normal gastric tissue are higher than those in abnormal tissue. Authors expect that this study also represents another possibility of gastric carcinoma detection by visualizing diffusion characteristics of proton spins in the gastric tissues.

Diffusion-controlled Cure Kinetics of High Performance Epoxy/Carbon Fiber Composite Systems (확산속도에 따라 한계경화도를 갖는 에폭시/탄소섬유 복합재료의 경화반응 속도 연구)

  • 박인경;금성우;이두성;김영준;남재도
    • Polymer(Korea)
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    • v.24 no.1
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    • pp.105-112
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    • 2000
  • Using a commercial epoxy/carbon fiber composite prepreg (DMS 2224) as a model system, the cure kinetics of vitrifying thermoset system were analyzed by isothermal and dynamic-heating experiments. Focusing on the processing condition of high performance composite systems, a phenomenological kinetic model was developed by using differential scanning calorimetry (DSC) and reaction kinetics theories. The model system exhibited a limited degree of cure as a function of isothermal temperature seemingly due to the diffusion-controlled reaction rates. The diffusion-controlled cure reaction was incorporated in the development of the kinetic model, and the model parameters were determined from isothermal experiments. The first order reaction was confirmed from the characteristic shape of isothermal cure thermograms, and the activation energy wes 78.43 kJ/mol. Finally, the proposed model was used to predict a complex autoclave thermal condition, which was composed of several isothermal and dynamic-heating stages.

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