• Title/Summary/Keyword: high temperature high pressure

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Kinetic Study for the Reaction of Pyridine under High Pressure (고압하의 피리딘 반응에 대한 속도론적 연구)

  • 김명자
    • The Korean Journal of Food And Nutrition
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    • v.16 no.4
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    • pp.321-327
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    • 2003
  • The reaction rates of 4-ethyl pyridine with p-methyl benzylbromide have been measured by conductometry in acetonitrile, and the rate constants of these reactions are determined in accordance with various temperatures (20, 25, 30$^{\circ}C$) and pressures (1, 200, 500, 1000 bar). The rate constants increased with the higher pressure and temperature. The activation energies and activation parameter values of these reactions are calculated by determination of the rate constants the same. The activation volume, activation compressibility coefficient and the activation entropy are all negative. The result of kinetic studies for the pressure show that this reaction proceeds in typical bimolecular nucleophilic substitution reaction.

Experimental Study on Spray Structure of a High Pressure 6-Hole Injector by Mie Scattering Technique (미산란 기법에 의한 고압 6공 연료분사기의 분무형상에 대한 실험적 연구)

  • Kim, Seong-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.11
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    • pp.878-883
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    • 2008
  • The spray characteristics of a high pressure 6-hole injector were examined in a single cylinder optical direct injection spark ignition (DISI) engine. The effects of injection timing, in-cylinder charge motion, fuel injection pressure and coolant temperature were investigated using the 2-dimensional Mie scattering technique. It was confirmed that the in-cylinder charge motion played a major role in the fuel spray distribution during the induction stroke while the propagation of fuel spray was restrained during the compression stroke by the increasing pressure and the upward moving piston. In additions, it was confirmed that the liquid fuel droplets existing at the sprays edges were vaporized by the increase of the coolant temperature.

A Study on the Measurement of Temperature and Pressure of High Pressure Sodium Lamp (고압나트륨 램프의 온도와 압력의 측정에 관한 연구)

  • 지철근;김창섭
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.4 no.2
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    • pp.41-45
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    • 1990
  • The previous plasma diagnostics on HPS (high pressure sodium) lamp have analyzed only the average temperature and pressure. But the time change of the plasma state of HPS lamp is great by the small heat inertia. By these properties, the necessity of the diagnostics of time change of plasma state is important. This thesis proposes a new time-varying spectroscopy technics that can get the time-varying plasma state by measuring and analyze Na D line spectrum.

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Zricaloy-4 Oxidation Kinetics in High-Pressure High-Temperature Steam (지르칼로이-4의 고압 고온 수증기에서 산화 반응 속도)

  • 박광헌;김규태
    • Journal of Surface Science and Engineering
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    • v.34 no.1
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    • pp.17-24
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    • 2001
  • A model for quantifying the effect of steam pressure on the oxide thickness growth was developed based on the experimental data available. First, empirical equations for the thickness estimation of oxide formed in 1 atm steam were made. The oxide growth kinetics turned out to be dependent on 0.4th power of oxidation time. With an assumption that the transition oxide thickness be only a function of temperature, a model for the enhancement of steam pressure on oxide growth was developed. The enhancement coefficient for steam pressure is calculated to be 0.01~0.013 $bar^{-}$. The developed model generally well explains the experimental data.a.

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Manufacture of Apparatus for Coolant Mix Performance Test (냉각제 혼합성능 시험용 장치의 제작)

  • Ku, Hyoun-Kon;Bae, Young-Gwan;Kim, Jin-Hee
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.2
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    • pp.73-78
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    • 2022
  • The test apparatus that can be protected from the high-temperature combustion flame and coolant injection was successfully manufactured. In this study, the coolant-injection module had a controllable consistent pressure, and the entire combustion module was protected using a nonflammable composite liner. Every flange was designed in accordance with the DIN standard, and the entire body of the module was designed in accordance with the EN 13445 code. Additionally, the hydraulic pressure test was performed in accordance with the 2014/68/EU directive and EN 13445 standard. Finally, after manufacturing, performance tests (such as pressure tests) were conducted to verify the reliability and safety.

Measurement of Material Properties of Composites for High Temperature using Fiber Bragg Grating Sensors (광섬유 브래그 격자 센서를 이용한 고온용 복합재의 물성 측정)

  • 강동훈;박상욱;김수현;김천곤;홍창선
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.31-36
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    • 2003
  • Recently, composite materials are widely used for nozzle, pressure vessel, skins of satellite and many structures under condition of high temperature due to good thermal characteristics such as low CTE, heat-resistance, etc. Fiber optic sensors, especially FBG(fiber Bragg grating) sensors, can be a good counterproposal of strain gages for the measurement of material properties of composites under high temperature. In this research, T700/Epoxy specimens with embedded FBG sensors were fabricated and tested at the Instron with thermal chamber from room temperature to $400^{\circ}C$. The effects of embedding optical fiber on material properties were also verified. And, the experimental results were discussed and analyzed by microphotographs of the composite specimen.

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The Mechanical Properties of Scoured Fabrics Under Various Conditions (가호조건에 따른 정련포의 물성변화)

  • Park, Myung-Soo
    • Textile Coloration and Finishing
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    • v.20 no.3
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    • pp.1-7
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    • 2008
  • Three kinds of 135D/108F ITY were produced from raw yam 85D/72F + SDY 50D/36F with. interlacing pressure $1.5kg/cm^2$, $2.5kg/cm^2$, $3.5kg/cm^2$ respectively. 72 kinds of sized yams were manufactured from three ITYs by altering sizing speed, sizing temperature and sizing tension. The mechanical characteristics of 72 kinds of plain fabrics which were woven using the sized yam as a warp were analyzed after scouring. The initial modulus of scoured fabric responded sensitively to the sizing speed in high tension. The WT of scoured fabric recorded the. highest1n the conditions of sizing tension 30g, and air pressure $2.5kg/cm^2$ in interlacing treatment. When sizing temperature was high, the WT value appeared low, but when sizing speed was high, the WT value was much affected by air pressure in interlacing raw yam. The MIU value of fabric according to sizing tension variations increased up to sizing tension 40g, but decreased above it. The bulk density decreased up to sizing tension 30-40g, but increased above it. In addition, the bulk density decreased as sizing temperature increased.

Microexplosive Vaporization of Miscible Binary Fuel Droplets (미세폭발을 가진 혼화 이성분 연료 액적의 증발 현상)

  • Ghassemi, Hojat;Baek, Seung-Wook;Khan, Qasim Sarwar
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.120-131
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    • 2005
  • The evaporation characteristics of single and multicomponent droplets hanging at the tip of a quartz fiber are studied experimentally at the different environmental conditions under normal gravity. Heptane and Hexadecane are selected as two fuels with different evaporation rates and boiling temperatures. At the first step, the evaporation of single component droplet of both fuels has been examined separately. At the next step the evaporation of several blends of these two fuels, as a binary component droplet, has been studied. The temperature and pressure range is selected between 400 and 700 $^{\circ}C$, and 0.1 and 2.5 MPa, respectively. High temperature environment has been provided by a falling electrical furnace. The initial diameter of droplet was in range of 1.1 and 1.3 mm. The evaporation process was recorded by a high speed CCD camera. The results of binary droplet evaporation show the three staged evaporation. In the the first stage the more volatile component evaporates. The droplet temperature rises after an almost non evaporating period and in the third stage a quasi linear evaporation takes place. The evaporation of the binary droplet at low pressure is accompanied with bubble formation and droplet fragmentation and leads to incomplete microexplosion. The component concentration affects the evaporation behavior of the first two stages. The bubble formation and droplet distortion does not appear at high environment pressure. Nomenclature

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Manufacturing of the Linear Induction EM Pump for the Liquid Sodium (액체소듐 구동용 선형유동전자펌프 제작)

  • 김희령;남호윤;황중선
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.434-437
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    • 1999
  • An EM pump is used for the purpose of transporting the electrically conducting liquid sodium of the high temperature that is used as a coolant in the liquid metal reactor. In the present study, the pilot pump has been designed and manufactured for the high temperature of $600^{\circ}C$ by the equivalent circuit materials and the consideration of the materials and functions. The length and diameter of the pump are given as 84 cm and 10 cm each due to the fixed geometry of the circulation system to be installed. The characteristic of the developing pressure and efficiency is found out by using Laithewaite\`s standard design formula. It is shown that the developing pressure and efficiency are maximized at the frequency of 15 Hz from the curve. The annular channel gap of 3.95 mm is selected in the range of the reasonable hydraulic frictional loss. The components of the pump consist of the material for the high temperature. And then, the pump is manufactured to have the nominal flowrate of 40 1/min and developing Pressure of 1.3 bar.

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A Study on Fatigue Characteristics and Analysis for A 182 F6a Class 4 Materials (A182 F6A Class4 재료의 피로특성과 피로해석에 대한 연구)

  • Jin-Kyung Lee
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.4_2
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    • pp.585-589
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    • 2023
  • Unlike general carbon steel, stainless steel's mechanical properties change depending on the content of chromium and nickel. In this study, since stainless steel for high-temperature pressure container parts is used as shafts, the fatigue strength and fatigue limit of the materials were evaluated using a rotational bending fatigue test. Meanwhile, fatigue analysis was conducted under the same conditions as the specimen for structural analysis and fatigue analysis of stainless steel for high-temperature pressure container parts. Using the fatigue analysis results, we tried to derive the life of the material and the safety factor for each part. As a result of performing a fatigue test by processing a specimen for the fatigue test of A182 F6A stainless steel, the fatigue limit was 548 MPa. The ratio between the tensile strength and fatigue limit of the material was 0.545, representing 54.5% of the tensile strength.