• Title/Summary/Keyword: high temperature high pressure

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Assessment of Reference Evapotranspiration Equations for Missing and Estimated Weather Data (기상자료의 결측과 산정에 따른 기준작물 증발산량 공식의 비교 평가)

  • Yoon, Pu Reun;Choi, Jin-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.60 no.3
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    • pp.15-25
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    • 2018
  • Estimating the reference evapotranspiration is an important factor to consider in irrigation system design and agricultural water use. However, there is a limitation in using the FAO Penman-Monteith (FAO P-M) equation, which requires various meteorological data. The purpose of this study is to compare three reference evapotranspiration (ETo) equations in the case of meteorological data missing for 11 study weather stations. Firstly, the FAO P-M equation is used for reference potential evapotranspiration estimation with the actual solar radiation data $R_n$ and the actual vapor pressure $e_a$. Then, in the case of $R_n$, and $e_a$ are missed, the reference evapotranspirations applying FAO P-M, Priestley-Taylor (P-T), Hargreaves (HG) equation were calculated using other meteorological factors. Secondly, MAE, RMSE, $R^2$ were calculated to compare ETo relationship from the ETo equations. From the results, ETo with Hargreaves equation in coastal areas and the Priestley-Taylor equation in the inland areas showed relatively high correlation with FAO P-M when $e_a$ data is missed. In the case of $R_n$ data is missed or two weather data, $e_a$, and $R_n$ data are all missed, $R^2$ value in Priestley-Taylor equation was highest in coastal areas, and $R^2$ values in Hargreaves equation were the high values for 7 inland areas. The results of sensitivity analysis showed that net radiation was the most sensitive for P-T and HG equation, and for FAO P-M, the most sensitive factor was net radiation and relative humidity, air temperature and wind speed were follows. Therefore, in considering of the accessibility to the coast, the types of the missing wether data, and the correlation and the magnitude of error, the reference evapotranspiration equations would be selected in sense of different conditions.

Antioxidant and ACE Inhibiting Activities of the Rockfish Sebastes hubbsi Skin Gelatin Hydrolysates Produced by Sequential Two-step Enzymatic Hydrolysis

  • Kim, Hyung-Jun;Park, Kwon-Hyun;Shin, Jun-Ho;Lee, Ji-Sun;Heu, Min-Soo;Lee, Dong-Ho;Kim, Jin-Soo
    • Fisheries and Aquatic Sciences
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    • v.14 no.1
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    • pp.1-10
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    • 2011
  • This study was conducted to obtain hydrolysates with potent antioxidative activity from rockfish skin gelatin. Gelatin was extracted under high temperature/high pressure using a two-step enzymatic hydrolysis with commercial enzymes such as Alcalase, Flavourzyme, Neutrase, and Protamex. The second rockfish-skin gelatin hydrolysate (SRSGH) was prepared by further incubating the first gelatin hydrolysate (FRSGH), which had been hydrolyzed with Alcalase for 1-h (FRSGH-A1), with Flavourzyme for 2-h (SRSGH-F2). The second gelatin hydrolysate showed higher antioxidative activity of 3.72 as measured by a Metrohm Rancimat and superior angiotensin I-converting enzyme (ACE) inhibiting activity of 0.82 mg/mL. Compared with the gelatin, the relative proportion in SRSGH-F2 was markedly decreased in the 100-kDa peak, whereas it was increased in that less than 100-kDa. The amino acid composition of SRSGH-F2 was rich in glycine (25.9%), proline (10.8%), alanine (9.1%), and glutamic acid (9.1%). In contrast, it was poor in cystine (not detected), methionine (1.6%), tyrosine (0.4%), hydroxylysine (0.9%), and histidine (0.9%). In recent years, demand for natural functional foods has been increasing, and SRSGH-F2 can be used as a functional food ingredient in the food industries. However, further detailed studies on SRSGH-F2 with regard to its antioxidant activity in vivo and the various antioxidant mechanisms are needed.

Numerical Analysis of Effects of Mold Cavity Shape on Bubble Defect Formation in UV NIL (UV NIL공정에서 몰드 중공부 형상과 기포결함에 대한 수치해석)

  • Lee, Hosung;Kim, Bo Seon;Kim, Kug Weon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.1
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    • pp.596-602
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    • 2018
  • Nanoimprint lithography (NIL) is an emerging technology that enables cost-effective and high-throughput nanofabrication. In ultraviolet (UV) NIL, low-cost and high-speed production can be achieved using a non-vacuum environment at room temperature and low pressure. However, there are problems with the formation of bubble defects in such an environment. This paper investigates the shape of the mold cavity and the bubble defect formation in UV NIL in a non-vacuum environment. The bubble defect formation was simulated using two-dimensional flow analysis and the VOF method for commonly used cavity mold shapes (rectangular, elliptical, and triangular). The characteristics of the resist flow front and various contact angles were also analyzed. The shape of the mold cavity had a very significant effect on the bubble defect formation. For all cavity shapes, a smaller contact angle with the mold and larger contact angle with the substrate decreased the possibility of bubble defect formation. The elliptical shape was the most effective for preventing bubble defect formation.

A Kinetic Study on the Synthesis of Dimethylcarbonate by Using Immobilized Ionic Liquid Catalyst (고정화된 이온성 액체 촉매를 이용한 디메틸카보네이트 합성 반응에 대한 속도론적 고찰)

  • Kim, Dong-Woo;Kim, Dong-Kyu;Kim, Cheol-Woong;Koh, Jae-Cheon;Park, DaeWon
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.332-336
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    • 2010
  • Ionic liquid immobilized on mesoporous amorphous silica was prepared from the coupling of 1-(triethoxysilylpropyl)-3-n-alkyl-imidzolium halides with tetraethyl orthosilicate(TEOS) through template-free condensation under strong acidic conditions. The immobilized 1-n-butyl-3-methyl imidazolium bromide ionic liquid on amorphous silica(BMImBr-AS) was proved to be an effective heterogeneous catalyst for the synthesis of dimethyl carbonate(DMC) from transesterification of ethylene carbonate(EC) with methanol. High temperature, high carbon dioxide pressure and long reaction time were favorable for the reactivity of BMImBr-AS. Kinetic studies based on two step reactions revealed that the proposed reaction model fitted well the experimental data. The apparent activation energy was estimated to be 67.4 kJ/mol.

Study on Heat Transfer Characteristic in Combustor Nozzle (연소기 노즐에서의 열전달 특성 연구)

  • NamKoung, Hyuck-Joon;Kim, Hwa-Jung;Han, Poong-Gyoo;Lee, Kyoung-Hun;Kim, Young-Soo;Jeong, Hae-Seung;Lee, Sang-Youn
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.34-40
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    • 2006
  • For a cooling performance research of the combustor operated in a extreme environment of a high temperature and high pressure, we accomplished a cooling performance analysis. Generally a heat transfer characteristic in cooling passage is known well experimentally and theoretically, however heat flux in the combustion chamber isn't. In this study, fluid flow combined with heat transfer and thermal structural analysis is accomplished about a combustor nozzle. We tried to analyze the cooling performance with a heat transfer characteristic of a gas and coolant side in the view point of quantity on the mass flow rate to be supplied to the cooling channel. And finally, evaluation on the thermal and structural safety of nozzle wall material was accomplished.

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Study of Internal Flow in the supersonic Nozzle by the Hydraulic Analogy (수력학적 상사를 적용한 초음속 노즐 내부 유동 연구)

  • Lee, Ji-Hyung;Lee, Kyung-Hun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.477-482
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    • 2009
  • Though rocket nozzle flow is very important to the rocket performance, the direct measurement is very difficult because of high temperature and high pressure gas flow. Then the experiment utilizing the hydraulic analogy has been developed for such a problem. Supersonic flows through an axisymmetric De Laval nozzle of solid rocket motor was simulated in a 2-D sluice-type water-table designed and manufactured utilizing hydraulic analogy. Methods to minimize or account for non-analogous effects in the hydraulic system must be reviewed for the quantitative application of the hydraulic analogy. In this application the water table is inclined slightly, so that gravity acceleration has a small component in the direction of motion, thus compensating for the effect of friction. Flow visualization leads to better understanding of the analogous system. Within the experimental errors, it is shown that the hydraulic analogy can be used as an effective tool for the study of two dimensional isentropic flows of gases in many fields.

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Study on Structural Characteristic for Durability Insurance of Turbopump Turbine (터보펌프 터빈의 내구성 확보를 위한 구조적 특성 연구)

  • Lee, Mu-Hyoung;Jang, Byung-Wook;Kwon, Jeong-Sik;Kim, Jin-Han;Jeong, Eun-Hwan;Jeon, Seong-Min;Lee, Soo-Yong;Park, Jung-Sun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.382-386
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    • 2009
  • The life of a component decreases when it was exposed at the extreme condition. A turbine blade of a turbopump used for a liquid rocket engine is operated under the environment of high temperature and pressure, and experienced high centrifugal force. Thus the durability of the turbopump operated under the these conditions become lower than expected because of the severe fatigue and creep influence. The damage of the turbine being considered the fatigue and the creep influence is estimated to ensure the durability of turbopump turbine. ABAQUS/CAE and MSC.Fatigue are used for the fatigue analysis, and Larson-Miller parameter and robinson's rule are used for the creep analysis. In this paper, comparison and analysis of the fatigue and the creep influence were performed to ensure the life expectancy of turbopump turbine.

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Ultrasonic-assisted Micellar Extraction and Cloud-point Pre-concentration of Major Saikosaponins in Radix Bupleuri using High Performance Liquid Chromatography with Evaporative Light Scattering Detection

  • Suh, Joon-Hyuk;Yang, Dong-Hyug;Han, Sang-Beom
    • Bulletin of the Korean Chemical Society
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    • v.32 no.8
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    • pp.2637-2642
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    • 2011
  • A new ultrasonic-assisted micellar extraction and cloud-point pre-concentration method was developed for the determination of major saikosaponins, namely saikosaponins -A, -C and -D, in Radix Bupleuri by high performance liquid chromatography with evaporative light scattering detection (HPLC-ELSD). The non-ionic surfactant Genapol X-080 (oligoethylene glycol monoalkyl ether) was chosen as the extraction additive and parameters affecting the extraction efficiency were optimized. The highest yield was obtained with 10% (w/v) Genapol X-080, a liquid/solid ratio of 200:1 (mL/g) and ultrasonic-assisted extraction for 40 min. In addition, the optimum cloud-point pre-concentration was reached with 10% sodium sulfate and equilibration at $60^{\circ}C$ for 30 min. Separation was achieved on an Ascentis Express C18 column (100 ${\times}$ 4.6 mm i.d., 2.7 ${\mu}M$) using a binary mobile phase composed of 0.1% acetic acid and acetonitrile. Saikosaponins were detected by ELSD, which was operated at a $50^{\circ}C$ drift tube temperature and 3.0 bar nebulizer gas ($N_2$) pressure. The water-based solvent modified with Genapol X-080 showed better extraction efficiency compared to that of the conventional solvent methanol. Recovery of saikosaponins ranged from 93.1 to 101.9%. An environmentally-friendly extraction method was successfully applied to extract and enrich major saikosaponins in Radix Bupleuri.

Fabrication of Thin Solid Oxide Film Fuel Cells

  • Jee, Young-Seok;Chang, Ik-Whang;Son, Ji-Won;Lee, Jong-Ho;Kang, Sang-Kyun;Cha, Suk-Won
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.82-85
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    • 2010
  • Recently, thin film processes for oxides and metal deposition, such as physical vapor deposition (PVD) and chemical vapor deposition (CVD), have been widely adapted to fabricate solid oxide fuel cells (SOFCs). In this paper, we presented two research area of the use of such techniques. Gadolinium doped ceria (GDC) showed high ionic conductivity and could guarantee operation at low temperature. But the electron conductivity at low oxygen partial pressure and the weak mechanical property have been significant problems. To solve these issues, we coated GDC electrolyte with a nano scale yittria-doped stabilized zirconium (YSZ) layer via atomic layer deposition (ALD). We expected that the thin YSZ layer could have functions of electron blocking and preventing ceria from the reduction atmosphere. Yittria-doped barium zirconium (BYZ) has several orders higher proton conductivity than oxide ion conductor as YSZ and also has relatively high chemical stability. The fabrication processes of BYZ is very sophisticated, especially the synthesis of thin-film BYZ. We discussed the detailed fabrication processes of BYZ as well as the deposition of electrode. This paper discusses possible cell structure and process flow to accommodate such films.

The Effect of Web-Aided Laboratory on Molecular Dynamics of High School Physics Course (고등학교 물리의 기체 분자 운동론에서 웹 활용 모의실험이 학습에 미치는 효과)

  • Roh, Hack-Kie;Kong, Youn-Sig;Park, Chang-Young;Chung, Ki-Soo
    • Journal of The Korean Association For Science Education
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    • v.25 no.5
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    • pp.547-554
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    • 2005
  • A developed Web-aided laboratory program visualized invisible gas. In the Web-aided laboratory temperature and pressure were controlled and the resultant findings were presented as types of graphs, disclosed in the form of an analyzed report. A Web-aided laboratory experiment and traditional experiment group(2 classes) were assembled from a farming village co-educational high school and taught the motion of molecule lesson for 2 class hours. Before actual class instruction, to survey learner motivation characteristics, the short-version GALT, the test of attitudes toward science instruction, was administered. After instruction, student learning achievement, TOSRA, and IMMS, were administered to the two groups. To analyze data ANCOVA was administrated. Result found that attitudes towards science instruction did not significantly differ, but learning motivation and achievement were significantly altered.