• Title/Summary/Keyword: high temperature high pressure

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Phase Equilibrium of Binary Mixture for the (Carbon Dioxide + 1-Phenyl-2-Pyrrolidone) System at High Pressure

  • Lee, Ho;Jeong, Jong-Dae;Byun, Hun-Soo
    • Korean Chemical Engineering Research
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    • v.56 no.5
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    • pp.732-737
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    • 2018
  • Experimental data of phase equilibria are reported for the binary mixture of 1-phenyl-2-pyrrolidone in supercritical carbon dioxide. Phase behavior data was measured in a synthetic method at a temperature ranging from 333.2 to 393.2 K and at pressures up to 97.14 MPa. The solubility of 1-phenyl-2-pyrrolidone in the carbon dioxide + 1-phenyl-2-pyrrolidone system increased as temperature increased at a constant pressure and it exhibited the type-I phase behavior. The experimental data for the binary mixture were correlated with the Peng-Robinson equation of state using mixing rule and the critical properties of 1-phenyl-2-pyrrolidone were predicted with the Joback and Lyderson method.

A Study of the Ionization Characteristics of Xenon Gas by Shock Compression (충격 압축에 의한 제논 가스의 이온화 특성 연구)

  • Lee, D.S.;Shin, J.R.;Choi, J.Y.;Choi, Y.S.;Kim, H.W.
    • Journal of the Korea Institute of Military Science and Technology
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    • v.13 no.3
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    • pp.493-502
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    • 2010
  • In this paper, the ionization characteristics of noble gases are studied numerically behind strong shock waves. As a first step, the equilibrium ionization mechanism of noble gases is modeled in wide ranges of temperature and pressure. As a next step the equilibrium ionization model is coupled with fluid dynamic equations to analyze the local thermodynamic equilibrium(LTE) ionization process at high temperature and pressure conditions behind the strong imploding shock waves. The ionization characteristics of xenon gas is studied in a wide range of test conditions with thermal radiation effects. Hence, the results give optimal conditions of maximum ionization and radiation behind the imploding shock waves.

Densification Behavior of Fe-Ni Alloy Nanoparticles

  • Kim, Sang-Phil;Lee, Woo-Seok;Lee, Jae-Wook;Choi, Chul-Jin
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.531-532
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    • 2006
  • The effects of compaction pressure and sintering temperature on the densification of Fe-40wt%Ni alloy nanoparticles were analyzed. The Fe-Ni nanoparticles were fabricated by an arc-discharge method and then, compacted at three different pressures and sintered at 550 to $900\;^{\circ}C$. Densification was completed at temperature as low as $600\;^{\circ}C$ and high-pressure compaction was found to enhance densification. Densification behaviors and microstructure developments have been investigated through density measurements, electron microscopies, and hardness measurements.

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Fabrication and Characteristics of Oxygen Gas Sensor using Fluoride Compaunds (불화물을 이용한 산소센서의 제조및 특성)

  • 이재현;홍영호;장동근;이병택;김태훈;이덕동
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1993.11a
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    • pp.69-71
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    • 1993
  • Fluoride compound potentiometric cell oxygen sensors were fabricated for the measurement of oxygen pressure in the low temperature range (300。K-500。K). The disk type sensors consist of a reference Air(0$_2$):Ag, a solid electrolyte SrF$_2$, and a sensing metel Ag electrode. And the buried reference electrode type sensor have a NiO/Ni reference electrode. The open circuit emf of the cell showed high sensivity to oxygen gas (60mv) at the measuring temperature 20$0^{\circ}C$. Also, The buried reference electrode type sensor showed 30mv from 1% to 10% oxygen pressure range.

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Study of thermoacoustic oscillations in half-open tubes for saturated superfluid helium

  • Wang, Xianjin;Niu, Xiaofei;Bai, Feng;Zhang, Junhui;Chen, Shuping
    • Progress in Superconductivity and Cryogenics
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    • v.24 no.3
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    • pp.68-73
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    • 2022
  • Thermoacoustic oscillations (TAOs) are spontaneous pressure oscillations frequently seen in hydrogen or helium cryogenic systems. Half-open tubes connected to cryogenic fluid with a closed room temperature end have a high potential for oscillation generation. Thermoacoustic oscillations will result in significant pressure fluctuations and additional heat load, endangering the security and stability of the cryogenic system. The goal of this paper is to investigate TAOs in superfluid helium using both theoretical and experimental methods. Five half-open tubes with varied typical inner diameters inserted into superfluid helium were installed in a test cryostat. The onset characteristics of thermoacoustic oscillations were presented and studied. The effect of temperature profile was discussed. Finally, a simple eliminating method was introduced.

Physico-mechanical Properties and Optimum Manufacturing Conditions of Bi-Sn Metal Alloy Impregnated Wood Composites (Bi-Sn 용융합금주입 목재복합체의 최적제조조건 및 물리·기계적 특성)

  • Park, Kye-Shin;Lee, Hwa-Hyoung;Kang, Seog Goo
    • Journal of the Korean Wood Science and Technology
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    • v.42 no.6
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    • pp.691-699
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    • 2014
  • In order to improve the dimensional stability and durability of wood, this study attempted to impregnate bismuth (Bi) - tin (Sn) alloy metal with low melting temperature into solid woods of three species such as radiata pine, red oak and white oak, and investigated to determine an optimum condition of manufacturing the metal alloy-wood composites with natural wood grains. These Bi-Sn alloys were chosen for this study because they were harmless to human and melting at low temperatures. The composites resulted in high dimensional stability and low thickness swelling, and also showed much improved performance such as high bending strength, high hardness, high electric conductivity, and high thermal conductivity as floor materials. A proper impregnating condition of all specimens was determined as 10 minutes of the preliminary vacuum time, and $185^{\circ}C$ of the heating temperature. The proper processing condition for radiata pine wood was 2.5 minutes of the pressuring time at the pressure of $10kgf/cm^2$. For red oak wood, 10 minutes of the pressuring time at the pressure of $30kgf/cm^2$ were the proper condition. The proper manufacture conditions for white oak wood was determined as 10 minutes of the pressuring time at the pressure of $50kgf/cm^2$.

An Theoretical study on Spalling Mechanism of Concrete (콘크리트 폭렬발생 메카니즘에 관한 이론적 고찰)

  • Kim, Hyung-Jun;Kim, Heung-Youl;Kim, Gyeong-Ok
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2008.11a
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    • pp.422-427
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    • 2008
  • The major cause of Concrete Spalling at high temperatures can be divided into the Vapor Pressure Rising, caused by the increase in free water temperature within the concrete, and Pore Pressure Rising induced by the vapor moving into dense pores within the concrete. Although the occurrence of spalling within concrete caused by these pressure increases can be assessed experimentally, a close examination into Mechanistic influence against various spalling factors shall be carried out first by using Mathematical Modeling and Theoretical Equations. The Spalling Prospect Process by theoretical mechanism is expedited in order of the following; selection of heating condition (fire strength and flame heating direction), a selection of constituent elements, an analysis of heat transmission, an analysis of moisture movement, distribution of water content, an analysis of pore/vapor pressure, and assessment of spalling occurrence.

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Fabrication of ZnO films from directly heated Zinc-Acetate and oxygen effects on the deposition (Zinc-acetate 직접 가열에 의한 ZnO막의 제조 및 산소분위기 영향)

  • 마대영;이수철;김상현;박기철;김기완
    • Electrical & Electronic Materials
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    • v.8 no.4
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    • pp.400-405
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    • 1995
  • ZnO films have been grown easily with the conventional thermal evaporation method on SiO$\_$2/ coated Si wafers. Anhydrous zinc acetate has been used as evaporation source. Zinc-acetate was directly heated in the laboratory-made brass boat. Zinc-acetate was sublimed at the boat temperature of about 220.deg. C. The substrates were heated to 600.deg. C with home made tantalium heater. Oxygen has been flowed into the deposition chamber to change the partial pressure of oxygen. X-ray diffraction patterns showed all the films to be amorphous. The films deposited at high oxygen pressure exhibit higher resistivity than films at low pressure. Energy dispersive spectroscopy(EDS) and rutherford backscattering spectrometry(RBS) were conducted on the films to reveal the composition of the ZnO films.

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A Preliminary Study on Submarine Slope Failure of Gas Hydrate-bering Sediments (가스 하이드레이트가 매장된 해저사면의 붕괴에 관한 기초적 연구)

  • Park, Sung-Sik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.399-404
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    • 2008
  • The influence of gas hydrate dissociation on submarine slope stability was studied in this paper. Gas hydrates are stable under high pressure and low temperature conditions. Once gas hydrate dissociates due to natural or human activities, it generates large amount of gas and water. During gas hydrate dissociation, a pore pressure between soil particles increases and results in the loss of an effective stress and degradation of soil stiffness. A pore pressures model was proposed to calculated excess pore pressures generated by gas hydrate dissociation at the Storegga Slide. A slope stability analysis for the Storegga Slide using a two dimensional finite difference method was carried out by considering excess pore pressures due to gas hydrate dissociation. Since the excess pore pressure calculated by the proposed method resulted in the considerable loss of stiffness and strength in slope, a submarine slope failure occurred at the Storegga slide was well simulated.

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Heat-Pressure Characterization of Power Steering Hose by Finite Element Analysis (자동차 파워스티어링 호스의 열내압 특성 유한요소해석)

  • Roh, Gi-Tae;Joen, Do-Hyung;Choi, Ju-Hyung;Cho, Jin-Rae
    • Proceedings of the KSME Conference
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    • 2003.04a
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    • pp.409-414
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    • 2003
  • Power steering hose is device that operation oil passes between steering gear box and oil pump by parts that is used to do steering system. Because this hose is receiving heat and pressure of high temperature, leakage can produce swaging from hitch of steel materials of done part. In this paper, we analyze swaging process of Power steering hose by finite element analysis, and achieved thermal and pressure analysis with this shape. We can analogize weakness part of hose through this result, and examine closely oil leakage and rubber failure mechanism and look for important design benevolence of power steering hose development.

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