• Title/Summary/Keyword: high strength materials

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Resistance to Weathering with Materials for Fisheries Facilities 2. Photodegradation of Plastic Materials for Floatation Unit (수산 시설용 재료의 내후성에 관한 연구 2. 부력재용 플라스틱 재료의 내후성)

  • 김태호
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.37 no.2
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    • pp.140-146
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    • 2001
  • In order to analyze the photodegradation of plastic materials for floats or frames of fisheries facilities, weathering experiment on 3 kinds of plastic materials like high density PE of Korea(KHDPE) and Norway(NHDPE) and high strength PVC(Hi-PVC) was carried out during 900 hours exposure by using xenon light source of weather-Ometer. The results obtained are as follows; With increasing of ultraviolet radiation(UVR) time, a remarkable losses in the mechanical properties of each specimen were observed except for the remaining strain of HDPE materials. As NHDPE lost almost 15% of its initial tensile stress during a 900 hours exposure followed by KHDPE 12% and Hi-PVC 6%. In addition, the remaining tensile stress RS(kg/$mm^2$) decreases almost linearly with the lapse of exposure time to light Y(Year) and the empirical equations of each specimen computed as follows; KHDPE : RS=2.6769-0.0003Y($r^2$=0.63) Hi-PVC : RS=5.3470-0.0003Y($r^2$=0.91) NHDPE : RS=2.4929-0.0004Y($r^2$=0.97) It was observed by scanning electron microscope that all specimens with UVR time had started to decompose and had bubbled areas and small holes.

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Changes in Wet Pressing Response of OCC stock by the Beating Time and the Addition of Polymer Aids (골판고지 지료의 고해처리 및 고분자첨가제에 의한 압착탈수 특성변화)

  • Sung, Yong-Joo;Lee, Han-Ba-Roh;Jeong, Wong-Ki;Jung, Jae-Gwon;Choi, Song-Gu;Im, Chang-Kuk;Gwon, Wan-Oh;Seo, Yong-Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.2
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    • pp.77-82
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    • 2011
  • The changes in the wet pressing response of old corrugated container(OCC) stock depending on the beating treatment and the addition of polymer aids were investigated with laboratory roll press instrument. Two types of polymer aids, such as high molecular weight polymer with low charge density and low molecular weight polymer with high charge density, were applied in this study. The more beaten OCC stock showed the lower dryness after wet pressing. The addition of polymer aids had great influences on the wet pressing efficiency and paper properties. The dryness after wet pressing was increased by the addition of polymer aids, but the pattern of changes in dryness were different depending on the type of polymer and the properties of stock. The higher molecular weight polymer aids showed the greater increase in the dryness. The properties of paper such as air permeability, bulk, formation, tensile strength were also greatly affected by the addition of polymer aids.

A Study on the Die-casting Process of AM50 Magnesium Alloy (AM50 마그네슘 합금의 다이캐스팅 공정에 관한 연구)

  • Kim, Soon-Kook;Jang, Chang-Woo;Lee, Jun-Hee;Jung, Chan-Hoi;Seo, Yong-Gwon;Kang, Choong-Gil
    • Korean Journal of Materials Research
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    • v.16 no.8
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    • pp.516-523
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    • 2006
  • In recent years, Magnesium (Mg) and its alloys have become a center of special interest in the automobile industry. Due to their high specific mechanical properties, they offer a significant weight saving potential in modern vehicle constructions. Most Mg alloys show very good machinability and processability, and even the most complicated die-casting parts can be easily produced. The die casting process is a fast production method capable of a high degree of automation for which certain Mg alloys are ideally suited. In this study, step-dies and flowability tests for AM50 were performed by die-casting process according to various combination of casting pressure and plunger velocity. We were discussed to velocity effect of forming conditions followed by results of microstructure, FESEM-EDX, hardness and tensile strength. Experimental results represented that the conditions of complete filling measured die-casting pressure 400 bar, 1st plunger velocity 1.0 m/s and 2nd plunger velocity 6.0 m/s. The increasing of 2nd plunger velocity 4.0 to 7.0 m/s decreased average grain size of $\alpha$ phase and pore. It was due to rapid filling of molten metal, increasing of cooling rate and pressure followed by increased 2nd plunger velocity. The pressure should maintain until complete solidification to make castings of good quality, however, the cracks were appeared at pressure 800bar over.

Microstructural changes of polyacrylonitrile-based carbon fibers (T300 and T700) due to isothermal oxidation (1): focusing on morphological changes using scanning electron microscopy

  • Oh, Seong-Moon;Lee, Sang-Min;Kang, Dong-Su;Roh, Jae-Seung
    • Carbon letters
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    • v.18
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    • pp.18-23
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    • 2016
  • Polyacrylonitrile (PAN)-based carbon fibers have high specific strength, elastic modulus, thermal resistance, and thermal conductivity. Due to these properties, they have been increasingly widely used in various spheres including leisure, aviation, aerospace, military, and energy applications. However, if exposed to air at high temperatures, they are oxidized, thus weakening the properties of carbon fibers and carbon composite materials. As such, it is important to understand the oxidation reactions of carbon fibers, which are often used as a reinforcement for composite materials. PAN-based carbon fibers T300 and T700 were isothermally oxidized in air, and microstructural changes caused by oxidation reactions were examined. The results showed a decrease in the rate of oxidation with increasing burn-off for both T300 and T700 fibers. The rate of oxidation of T300 fibers was two times faster than that of T700 fibers. The diameter of T700 fibers decreased linearly with increasing burn-off. The diameter of T300 also decreased with increasing burn-off but at slower rates over time. Cross-sectional observations after oxidation reactions revealed hollow cores in the longitudinal direction for both T300 and T700 fibers. The formation of hollow cores after oxidation can be traced to differences in the fabrication process such as the starting material and final heat treatment temperature.

Machinable Ceramics Made by the Reaction Sintering of PSZ, Al2O3 and TiO2 (PSZ, Al2O3, TiO2를 반응소결하여 제조한 쾌삭(快削) 세라믹스)

  • Park, Jeong Hyun;Jung, Dong Sik;Lee, Won Jae;Kim, Il Soo
    • Journal of the Korean Ceramic Society
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    • v.49 no.6
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    • pp.581-585
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    • 2012
  • Machinability is important in engineering applications, especially in the current micro-electronics industry. Most ceramic components have complex shapes and hence require machining generally with diamond tools, which incurs a high production cost. Recently, h-BN-containing machinable ceramics have been developed, but these materials are very expensive due to the high raw materials and production costs. Therefore, the development of low-cost machinable ceramics is necessary. In this study, inexpensive $Al_2TiO_5$ was studied as a replacement for h-BN. $Al_2O_3$, $TiO_2$ and partially stabilized $ZrO_2$(PSZ) powders were mixed with various mole ratios and were sintered at $1500^{\circ}C$ for 1 h. The density, hardness and strength were then measured. The phase analysis and microstructures were observed by XRD and SEM, respectively. The machinability of each specimen was tested by micro-hole machining. The results of this research showed that the produced composites could be used as low-cost machinable ceramics.

Comparison of Properties with Different Sintering Process of 3Y-TZP/WC Composites (3Y-TZP/WC 복합체의 소결 방식에 따른 특성비교)

  • Nam, Min-Soo;Choi, Jae-Hyung;Nahm, Sahn;Kim, Seongwon
    • Journal of Powder Materials
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    • v.29 no.5
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    • pp.424-431
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    • 2022
  • 3Y-TZP ceramics obtained by doping 3 mol.% of Y2O3 to ZrO2 to stabilize the phase transition are widely used in the engineering ceramic industry due to their excellent mechanical properties such as high strength, fracture toughness, and wear resistance. An additional increase in mechanical properties is possible by manufacturing a composite in which a high-hardness material such as oxide or carbide is added to the 3Y-TZP matrix. In this study, composite powder was prepared by dispersing a designated percentage of WC in the 3Y-TZP matrix, and the results were compared after manufacturing the composite using the different processes of spark plasma sintering and HP. The difference between the densification behavior and porosity with the process mechanism was investigated. The correlation between the process conditions and phase formation was examined based on the crystalline phase formation behavior. Changes to the microstructure according to the process conditions were compared using field-emission scanning electron microscopy. The toughness-strengthening mechanism of the composite with densification and phase formation was also investigated.

A Study on the Optimal Design of Ti-6Al-4V Lattice Structure Manufactured by Laser Powder Bed Fusion Process (Laser Powder Bed Fusion 공정으로 제조된 Ti-6Al-4V 격자 구조물의 최적 설계 기법 연구)

  • Ji-Yoon Kim;Jeongmin Woo;Yongho Sohn;Jeong Ho Kim;Kee-Ahn Lee
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.146-155
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    • 2023
  • The Ti-6Al-4V lattice structure is widely used in the aerospace industry owing to its high specific strength, specific stiffness, and energy absorption. The quality, performance, and surface roughness of the additively manufactured parts are significantly dependent on various process parameters. Therefore, it is important to study process parameter optimization for relative density and surface roughness control. Here, the part density and surface roughness are examined according to the hatching space, laser power, and scan rotation during laser-powder bed fusion (LPBF), and the optimal process parameters for LPBF are investigated. It has high density and low surface roughness in the specific process parameter ranges of hatching space (0.06-0.12 mm), laser power (225-325 W), and scan rotation (15°). In addition, to investigate the compressive behavior of the lattice structure, a finite element analysis is performed based on the homogenization method. Finite element analysis using the homogenization method indicates that the number of elements decreases from 437,710 to 27 and the analysis time decreases from 3,360 to 9 s. In addition, to verify the reliability of this method, stress-strain data from the compression test and analysis are compared.

Improvement of Mechanical Properties of Mg alloys through Control of Grain Size and Texture (결정립크기와 집합조직제어를 통한 마그네슘 합금의 기계적 성질 개선)

  • Kim, W.J.;Lee, J.B.;Kim, W.Y.;Jeong, H.G.;Park, J.D.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.57-58
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    • 2006
  • The effects of lowering ECAP temperature during ECAP process and Post-ECAP annealing on microstructure, texture and mechanical properties of the AZ31 alloys have been investigated in the present study. The as-extruded materials were ECAP processed to 2 passes at 553K prior to subsequent pressing up to 6 passes at 523K or 493K. When this method of lowering ECAP temperature during ECAP was used, the rods could be successfully deformed up to 6 passes without any surface cracking. Grain refinement during ECAP process at 553K might have helped the material to endure further straining at lower deformation temperatures probably by increasing the strain accommodation effect by grain boundary sliding, causing stress relaxation. Texture modification during ECAP has a great influence on the strength of Mg alloys because HCP metals have limited number of slip systems. As slip is most prone to take place on basal planes in Mg at room temperature, the rotation of high fraction of basal planes to the directions favorable for slip as in ECAP decreases the yield stress appreciably. The strength of AZ31 Mg alloys increases with decrease of grain size if the texture is constant though ECAP deformation history is different. A standard positive strength dependence on the grain size for Mg alloys with the similar texture (Fig. 1) supports that the softening of ECAPed Mg alloys (a negative slope) typically observed despite the significant grain refinement is due to the texture modification where the rotation of basal planes occurs towards the orientation for easier slip. It could be predicted that if the original fiber texture is restored after ECAP treatment yielding marked grain refinement, yield stress as high as 500 MPa will be obtained at the grain size of ${\sim}1{\mu}m$. Differential speed rolling (DSR) with a high speed ratio between the upper and lower rolls was applied to alter the microstructure and texture of the AZ31 sheets. Significant grain refinement took place during the rolling owing to introduction of large shear deformation. Grain size as small as $1.4{\mu}m$ could be obtained at 423K after DSR. There was a good correlation between the (0002) pole intensity and tensile elongation. This result indicates that tensile ductility improvement in the asymmetrically rolled AZ31 Mg alloys is closely related to the weakening of basal texture during DSR. Further basal texture weakening occurred during annealing after DSR. According to Hall-Petch relation shown in Fig. 1, the strength of the asymmetrically rolled AZ31 is lower than that of the symmetrically rolled one when compared at the same grain size. This result was attributed to weakening of fiber texture during DSR. The DSRed AZ31, however, shows higher strength than the ECAPed AZ31 where texture has been completely replaced by a new texture associated with high Schmid factors.

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A Study of Electro-Discharge-Sintering of Ti-6Al-4V Spherical Powders Doped with Hydroxyapatite by Spex Milling and Its Consolidation Characteristics (Hydroxyapatite가 도핑된 Ti-6Al-4V 구형 분말의 전기방전 소결 및 소결체 특성에 관한 연구)

  • Cho, Y.J.;Kim, Y.H.;Jo, Y.H.;Kim, M.J.;Kim, H.S.;Kim, S.W.;Park, J.H.;Lee, W.H.
    • Journal of Powder Materials
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    • v.20 no.5
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    • pp.376-381
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    • 2013
  • Spherical Ti-6Al-4V powders in the size range of 250 and 300 ${\mu}m$ were uniformly doped with nano-sized hydroxyapatite (HAp) powders by Spex milling process. A single pulse of 0.75-2.0 kJ/0.7 g of the Ti-6Al-4V powders doped with HAp from 300 mF capacitor was applied to produce fully porous and porous-surfaced Ti-6Al-4V implant compact by electro-discharge-sintering (EDS). The solid core was automatically formed in the center of the compact after discharge and porous layer consisted of particles connected in three dimensions by necks. The solid core increased with an increase in input energy. The compressive yield strength was in a range of 41 to 215 MPa and significantly depended on input energy. X-ray photoelectron spectroscopy and energy dispersive x-ray spectrometer were used to investigate the surface characteristics of the Ti-6Al-4V compact. Ti and O were the main constituents, with smaller amount of Ca and P. It was thus concluded that the porous-surfaced Ti-6Al-4V implant compacts doped with HAp can be efficiently produced by manipulating the milling and electro-discharge-sintering processes.

Materials Integrity Analysis for Application of Hyper Duplex Stainless Steels to Korean Nuclear Power Plants

  • Chang, Hyun-Young;Park, Heung-Bae;Park, Yong-Soo;Kim, Soon-Tae;Kim, Young-Sik;Kim, Kwang-Tae;Jhang, Yoon-Young
    • Corrosion Science and Technology
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    • v.9 no.5
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    • pp.187-195
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    • 2010
  • Hyper duplex stainless steels have been developed in Korea for the purpose of application to the seawater system of Korean nuclear power plants. This system supplies seawater to cooling water heat exchanger tubes, related pipes and chlorine injection system. In normal operation, seawater is supplied to heat exchanger through the exit of circulating water pump headers, and the heat exchanged sea water is extracted to the discharge pipes in circulating water system connected to the circulating water discharge lines. The high flow velocity of some part of seawater system in nuclear power plants accelerates damages of components. Therefore, high strength and high corrosion resistant steels need to be applied for this environment. Hyper duplex stainless steel (27Cr-7.0Ni-2.5Mo-3.2W-0.35N) has been newly developed in Korea and is being improved for applying to nuclear power plants. In this study, the physical & mechanical properties and corrosion resistance of newly developed materials are quantitatively evaluated in comparative to commercial stainless steels in other countries. The properties of weld & HAZ (heat affected zone) are analyzed and the best compositions are suggested. The optimum conditions in welding process are derived for ensuring the volume fraction of ferrite(${\alpha}$) and austenite(${\gamma}$) in HAZ and controlling weld cracks. For applying these materials to the seawater heat exchanger, CCT and CPT in weldments are measured. As a result of all experiments, it was found that the newly developed hyper duplex stainless steel WREMBA has higher corrosion resistance and mechanical properties than those of super austenitic stainless steels including welded area. It is expected to be a promising material for seawater systems of Korean nuclear power plants.