• Title/Summary/Keyword: high strength materials

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Surface and Chemical Properties of Surface-Modified UHMWPE Powder and Mechanical and Thermal Properties of Its Impregnated PMMA Bone Cement V. Effect of Silane Coupling Agent on the Surface Modification of UHMWPE Powder

  • Yang Dae Hyeok;Yoon Goan Hee;Shin Gyun Jeong;Kim Soon Hee;Rhee John M.;Khang Gilson;Lee Hai Bang
    • Macromolecular Research
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    • v.13 no.2
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    • pp.120-127
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    • 2005
  • Conventional poly(methyl methacrylate) (PMMA) bone cement has been widely used as an useful biopolymeric material to fix bone using artificial prostheses. However, many patients had to be reoperated, due to the poor mechanical and thermal properties of conventional PMMA bone cement, which are derived from the presence of unreacted MMA liquid, the shrinkage and bubble formation that occur during the curing process of the bone cement, and the high curing temperature ($above 100^{\circ}C$) which has to be used. In the present study, a composite PMMA bone cement was prepared by impregnating conventional PMMA bone cement with ultra high molecular weight polyethylene (UHMWPE) powder, in order to improve its mechanical and thermal properties. The UHMWPE powder has poor adhesion with other biopolymeric materials due to the inertness of the powder surface. Therefore, the surface of the UHMWPE powder was modified with two kinds of silane coupling agent containing amino groups (3-amino propyltriethoxysilane ($TSL 8331^{R}$) and N-(2-aminoethyl)-3-(amino propyltrimethoxysilane) ($TSL 8340^{R}$)), in order to improve its bonding strength with the conventional PMMA bone cement. The tensile strengths of the composite PMMA bone cements containing $3 wt\%$ of the UHMWPE powder surface-modified with various ratios of $TSL 8331^{R}$ and $TSL 8340^{R}$ were similar or a little higher than that of the conventional PMMA bone cement. However, no significant difference in the tensile strengths between the conventional PMMA bone cement and the composite PMMA bone cements could be found. However, the curing temperatures of the composite PMMA bone cements were significantly decreased.

Synthesis and Their Catalytic Performance on Microporous Materials(CHA, ERI and MTT types) (마이크로다공성재료의 합성과 촉매적성능 (CHA, ERI, and MTT types))

  • Kang, Mi-Sook;Park, Jong-Yul;Um, Myeong-Heon
    • Korean Journal of Materials Research
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    • v.9 no.2
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    • pp.117-123
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    • 1999
  • This work was focused on the synthesis and their catalytic performance on microporous materials having various pore types and dimensions in structures, such as the SAPO-34 and the SAPO-44 with CHA type, the SAPO-17 with ERI type of three dimensional structures, and the ZSM-23 with MTT type of one dimensional structure. Synthesized materials exhibited various acidities and the selectivities to olefin in methanol conversion. As a result, the order of their acid strength was as follows; SAPO-44>SAPO-34>SAPO-17>ZSM-5. On the other hand, the CHA type materials, such as SAPO-34 and SAPO-44, had high selectivity to light olefins(ethylene or propylene), and ZSM-23 with MTT typ of one dimensional structure showed high selectivity to paraffins over $\textrm{C}_{5}$~. This result is a proof that the structure in material had strong influence on catalytic performance. In addition, a surprising result is that the catalytic selectivity to ethylene enhanced on Ni-corporated materials compared with the non-corporated.

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Fabrication and Properties of Ti-HA Composites Produced by Pulsed Current Activated Sintering for Biomaterials (통전가압활성소결에 의한 생체재료용 Ti-HA복합재료 제조 및 특성)

  • Woo, Kee Do;Kang, Duck Soo;Kwon, Eui Pyo;Moon, Min Seok;Shon, In Jin;Liu, Zhiguang
    • Korean Journal of Metals and Materials
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    • v.47 no.8
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    • pp.508-515
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    • 2009
  • Ti-6Al-4V biomaterial is widely used as a bone alternative. However, Ti-6Al-4V ELI alloy suffers from numerous problems such as a high elastic modulus and high toxicity. Therefore, non-toxic biomaterials with low elastic moduli need to be developed. Ti-HA(hydroxyapatite) composites were fabricated in the present work by pulsed current activated sintering (PCAS) at $1000^{\circ}C$ under 60 MPa using mixed Ti and HA powders. The effects of HA content on the physical and mechanical properties of the sintered Ti-HA composites have been investigated. X-ray diffraction(XRD) analysis of the Ti-HA composites, including Ti-40 wt%HA in particular, revealed new phases, $Ti_{2}O$, CaO, $CaTiO_3$, and TixPy, formed by chemical reactions between Ti and HA during sintering. The hardness of the Ti-HA composites decreased with an increase in HA content. The corrosion resistance of these composites was observed to be an excellent candidate as a commercial Ti-6Al-4 V ELI alloy. A Ti-5 wt%HA composite fabricated by PCAS is recommended as a new biomaterial, because it offers good corrosion resistance, compressive strength, wear resistance, and biocompatibility, and a low Young's modulus.

Phase Formation and Mechanical Property of YSZ-30 vol.% WC Composite Ceramics Fabricated by Hot Pressing (가압소결로 제조된 YSZ-30 vol.% WC 복합체 세라믹스의 상형성 거동과 기계적 특성)

  • Jin-Kwon Kim;Jae-Hyeong Choi;Nahm Sahn;Sung-Soo Ryu;Seongwon Kim
    • Journal of Powder Materials
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    • v.30 no.5
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    • pp.409-414
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    • 2023
  • YSZ (Y2O3-stabilized zirconia)-based ceramics have excellent mechanical properties, such as high strength and wear resistance. In the application, YSZ is utilized in the bead mill, a fine-grinding process. YSZ-based parts, such as the rotor and pin, can be easily damaged by continuous application with high rpm in the bead mill process. In that case, adding WC particles improves the tribological and mechanical properties. YSZ-30 vol.% WC composite ceramics are manufactured via hot pressing under different pressures (10/30/60 MPa). The hot-pressed composite ceramics measure the physical properties, such as porosity and bulk density values. In addition, the phase formation of these composite ceramics is analyzed and discussed with those of physical properties. For the increased applied pressure of hot pressing, the tetragonality of YSZ and the crystallinity of WC are enhanced. The mechanical properties indicate an improved tendency with the increase in the applied pressure of hot pressing.

Micro Light-Emitting Diodes with 3D-Printed Hydrogel Microlens for Optical Property Enhancements (3D 프린팅된 하이드로젤 마이크로렌즈를 통한 마이크로 LED의 광학적 특성 향상 연구)

  • Yujin Ko;Jeong Hyeon Kim;Sang Yoon Park;Kang Hyeon Kim;Seong Min Hong;Bo-Yeon Lee;Han Eol Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.5
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    • pp.554-561
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    • 2024
  • Micro light-emitting diodes (µLEDs) have been utilized in various fields such as displays, and smart devices, due to their superior stabilities. Since the applications of the µLEDs have been extended to medical devices and wearable sensors, excellent optical properties and uniformity of the µLEDs are important. Hence, several researchers have investigated to enhance the optical efficiency of the µLEDs through micro/nano lens. However, the reported methods for realizing the micro/nano lens have some drawbacks such as complex and high-cost manufacturing processes. Herein, we developed µLEDs with 3D-printed hydrogel microlenses. The printed hydrogel had high transparency and excellent adhesive strength, allowing it to attach onto top surface of the µLEDs without any additional adhesives. Microscale printing technology using a 3D printer achieved quick and fine printing in desired shapes and arrangements, showing the possibility of mass production. The 3D-printed microlens can be applied to improve not only the optical properties of µLEDs but also other optical devices.

GF/PC Composite Filament Design & Optimization of 3D Printing Process and Structure for Manufacturing 3D Printed Electric Vehicle Battery Module Cover (전기자동차 배터리 모듈 커버의 3D 프린팅 제작을 위한 GF/PC 복합소재 필라멘트 설계와 3D 프린팅 공정 및 구조 최적화)

  • Yoo, Jeong-Wook;Lee, Jin-Woo;Kim, Seung-Hyun;Kim, Youn-Chul;Suhr, Jong-Hwan
    • Composites Research
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    • v.34 no.4
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    • pp.241-248
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    • 2021
  • As the electric vehicle market grows, there is an issue of light weight vehicles to increase battery efficiency. Therefore, it is going to replace the battery module cover that protects the battery module of electric vehicles with high strength/high heat-resistant polymer composite material which has lighter weight from existing aluminum materials. It also aims to respond to the early electric vehicle market where technology changes quickly by combining 3D printing technology that is advantageous for small production of multiple varieties without restrictions on complex shapes. Based on the composite material mechanics, the critical length of glass fibers in short glass fiber (GF)/polycarbonate (PC) composite materials manufactured through extruder was derived as 453.87 ㎛, and the side feeding method was adopted to improve the residual fiber length from 365.87 ㎛ and to increase a dispersibility. Thus, the optimal properties of tensile strength 135 MPa and Young's modulus 7.8 MPa were implemented as GF/PC composite materials containing 30 wt% of GF. In addition, the filament extrusion conditions (temperature, extrusion speed) were optimized to meet the commercial filament specification of 1.75 mm thickness and 0.05 mm standard deviation. Through manufactured filaments, 3D printing process conditions (temperature, printing speed) were optimized by multi-optimization that minimize porosity, maximize tensile strength, and printing speed to increase the productivity. Through this procedure, tensile strength and elastic modulus were improved 11%, 56% respectively. Also, by post-processing, tensile strength and Young's modulus were improved 5%, 18% respectively. Lastly, using the FEA (finite element analysis) technique, the structure of the battery module cover was optimized to meet the mechanical shock test criteria of the electric vehicle battery module cover (ISO-12405), and it is satisfied the battery cover mechanical shock test while achieving 37% lighter weight compared to aluminum battery module cover. Based on this research, it is expected that 3D printing technology of polymer composite materials can be used in various fields in the future.

Wave Characteristic in the Axially Loaded Axial-Bending-Shear Coupled Composite Laminated Beams (축 방향 하중을 받는 인장-굽힘-전단이 연성된 복합재 적층보의 파동특성)

  • Jang, In-Joon;Lee, U-Sik
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.2650-2652
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    • 2011
  • The fiber reinforced composite materials have many advantages due to their high strength-to-density ratios. Thus they have been widely used in many industrial applications. As the wave propagation are closely related to dynamic analysis of structures, it is very important to predict them. This paper presents a wave propagation in the axially loaded axial-bending-shear coupled composite laminated beams which are represented by the Timoshenko beam models based on the first-order shear deformation theory.

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Evaluation of Floor Vibration Existing in Apartment Building (기존 RC 아파트 바닥의 수직진동 성능 평가)

  • 이민정;한상환
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.329-334
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    • 2002
  • In recent years building floors become larger and more spacious due to the development of new design methods and high strength and light weight materials, However, such long span floor systems may provide smaller amount of damping and have longer period so that they would be more vulnerable to the floor vibration. This study attempts to evaluate the performance of the floors in typical apartment buildings. Three different floors with the area of $43.2m^2 41.44m^2 and 34.5m^2$, were investigated. The guideline provided by AISC(1997) is used to check the acceptability of the floor vibration.

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An Experimental Study of Fatigue and Static Behavior for Composite Deck Member (복합재료 바닥판 부재의 정적 및 피로거동에 관한 실험적 연구)

  • Kim, Young-Chan;Park, Tai-Young;Kim, Doo-Hwan
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.479-482
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    • 2007
  • For making an application in construction parts of the composite material's complicated theory needs to accumulation of data by the help of study and experiment(demonstrate). Thus, this study is conducted research and analysis about the Influence of repeated loading cycles on Strength Ratio of the high quality material which is Carbon/Epoxy Composite Laminates through the test of tensile and fatigue Characteristics, based on it, construction engineers will can apply composite materials to construction technical without difficulty.

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A Study on Evaluation of Crack Opening Point in Al 2024-T3 Material (Al 2024-T3재의 Crack Opening Point의 평가에 관한 연구)

  • 최병기;국중민
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2002.04a
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    • pp.53-58
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    • 2002
  • This paper aims to synthesize the research on fatigue mechanisms of high strength aluminum alloys which are widely used in motorcars or airplanes to prevent accidents. To measure the data of crack opening ratio, the same materials and methods are used for evaluating the fatigue crack propagation rate as an effective stress intensity factor. But, many researchers have brought different results. An exact crack opening ratio was, therefore, proposed for getting a more accurate fatigue crack propagation rate.

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