• Journal of The Korean Astronomical Society
• /
• v.52 no.3
• /
• pp.57-69
• /
• 2019

We present an analysis of the chemical abundances and kinematics of six low-mass dwarf stars, previously claimed to be candidate hypervelocity stars (HVSs). We obtained moderate-resolution (R ~ 6000) spectra of these stars to estimate the abundances of several chemical elements (Mg, Si, Ca, Ti, Cr, Fe, and Ni), and derived their space velocities and orbital parameters using proper motions from the Gaia Data Release 2. All six stars are shown to be bound to the Milky Way, and in fact are not even considered high-velocity stars with respect to the Galactic rest frame. Nevertheless, we attempt to characterize their parent Galactic stellar components by simultaneously comparing their element abundance patterns and orbital parameters with those expected from various Galactic stellar components. We find that two of our program stars are typical disk stars. For four stars, even though their kinematic probabilistic membership assignment suggests membership in the Galactic disk, based on their distinct orbital properties and chemical characteristics, we cannot rule out exotic origins as follows. Two stars may be runaway stars from the Galactic disk. One star has possibly been accreted from a disrupted dwarf galaxy or dynamically heated from a birthplace in the Galactic bulge. The last object may be either a runaway disk star or has been dynamically heated. Spectroscopic follow-up observations with higher resolution for these curious objects will provide a better understanding of their origin.

• Journal of the Mineralogical Society of Korea
• /
• v.28 no.1
• /
• pp.61-69
• /
• 2015

While the macroscopic properties and eruption style of basaltic and phonolitic melts are different, the microscopic origins including atomic structures are not well understood. Here we report the atomic structure differences of glass in diopside-anorthite eutectic composition (basaltic glass) and phonolitic glass using high-resolution 1D and 2D solid-state Nuclear Magnetic Resonance (NMR). The $^{27}Al$ MAS NMR spectra for basaltic glass and phonolitic glass show that the full width at half maximum (FWHM) of Al for basaltic glass is about twice than phonolitic glass, suggesting the topological disorder of basaltic magma is larger than that of phonolitic magma. The $^{27}Al$ 3QMAS NMR spectra for basaltic glass and phonolite glass show much improved resolution than the 1D MAS NMR, resolving Al and Al. Approximately 3.3% of Al is observed for basaltic glass, demonstrating the configurational disorder of basaltic magma is larger than phonolitic magma. This result confirms that the topological disorder of Al in basaltic glass is larger than that of phonolitic glass. The observed structural differences between basaltic glass and phonolitic glass can provide an atomistic origin for change of the macroscopic properties with composition including viscosity.

• Journal of Microbiology
• /
• v.45 no.6
• /
• pp.499-504
• /
• 2007

A new antagonistic strain of actinomycete, designated AP19-2, was isolated from the feces of giant pandas inhabiting the Foping National Nature Reserve in China. Cultural characteristic studies strongly suggested that this strain is a member of the genus Streptomyces. The nucleotide sequence of the 16S rRNA gene of strain AP19-2 evidenced profound similarity (97-99 %) with other Streptomyces strains. Two pure active molecules were isolated from a fermentation broth of Streptomyces sp. strain AP19-2 via extraction, concentration, silica gel G column chromatography, and HPLC. The chemical structures of the two related compounds (referred to as chromomycin $A_2$ and chromomycin $A_3$) were established on the basis of their Infrared spectra (IR), High Resolution Electrospray Ionization Mass Spectrometry (HR-ESI-MS), and Nuclear Magnetic Resonance (NMR) data, and by comparison with published data.

• Journal of Radiation Protection and Research
• /
• v.35 no.2
• /
• pp.77-80
• /
• 2010

The spectroscopy toolkit has been developed and tested. The toolkit consists of a CsI(Tl)/PIN diode detector, integrated electronics, and a multi.channel.analyzer and its size was 40 cm(width) by 20 cm(length) by 6 cm(high). It is compact, very portable and simpler and cheaper compared to the conventional spectroscopy system. The gamma energy resolutions of the toolkit were 7.9% for the 660 keV of $^{137}Cs$ and 4.9% for 1,332 keV of $^{60}Co$ respectively. The linearity for gamma energies was good. When the energy spectrum of a ceramic sample containing $^{232}Th$ was measured with the spectroscopy toolkit for 20 minutes, there were significant peaks of the heavy metal. These results show that the resolution of the spectroscopy toolkit is sufficient to accumulate a quality spectrum in a few minutes by using weak, encapsulated commercial sources. Furthermore a toolkit experiment that how to measure energy spectra using the toolkit, and how to identify specific isotopes in a pottery piece, could be widely adopted for education and even for more sophisticated and higher level experiments.

• Bulletin of the Korean Chemical Society
• /
• v.33 no.10
• /
• pp.3218-3224
• /
• 2012

Uniform and well dispersed metal sulfide semiconductor nanoparticles incorporated into matrices of alginate biopolymer are prepared by using a facile in situ method. The reaction was accomplished by impregnation of alginate with divalent metal ions followed by reaction with thioacetamide. XRD analysis showed that the nanoparticles incorporated in the polymer matrix were of cubic structure with the average particle diameter of 1.8 to 4.8 nm. Field emission scanning electron microscopy and high resolution transmission electron microscopy images indicated that the particles were well dispersed and distributed uniformly in the matrices of alginate polymer. FT-IR spectra confirmed the presence of alginate in the nanocomposite. The crystalline nature and thermal stability of the alginate polymer was found to be influenced by the nature of the divalent metal ions used for the synthesis. The proposed method is considered to be a simple and greener approach for large scale synthesis of uniform sized nanoparticles.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.9
• /
• pp.2635-2639
• /
• 2013

The rapid and accurate identification of biological agents is a critical step in the case of bio-terror and biological warfare attacks. Recently, matrix-assisted laser desorption/ionization time-of-flight mass spectrometry has been widely used for the identification of microorganisms. In this study, we describe a method for the rapid and accurate discrimination of Bacillus anthracis spores using MALDI-TOF MS. Our direct in-situ analysis of MALDI-TOF MS does not involve subsequent high-resolution mass analyses and sample preparation steps. This method allowed the detection of species-specific biomarkers from each Bacillus spores. Especially, B. anthracis spores had specific biomarker peaks at 2503, 3089, 3376, 6684, 6698, 6753, and 6840 m/z. Cluster and PCA analyses of the mass spectra of Bacillus spores revealed distinctively separated clusters and within-groups similarity. Therefore, we believe that this method is effective in the real-time identification of biological warfare agents such as B. anthracis as well as other microorganisms in the field.

• Carbon letters
• /
• v.24
• /
• pp.73-81
• /
• 2017

Interconnected meso/microporous activated carbons were prepared from pumpkin seeds using a simple chemical activation method. The porous carbon materials were prepared at different temperatures (PS-600, PS-700, PS-800, and PS-900) and demonstrated huge surface areas ($645-2029m^2g^{-1}$) with excellent pore volumes ($0.27-1.30cm^3g^{-1}$). The well-condensed graphitic structure of the prepared activated carbon materials was confirmed by Raman and X-ray diffraction analyses. The presence of heteroatoms (O and N) in the carbon materials was confirmed by X-ray photoemission spectroscopy. High resolution transmission electron microscopic images and selected area diffraction patters further revealed the porous structure and amorphous nature of the prepared electrode materials. The resultant porous carbons (PS-600, PS-700, PS-800, and PS-900) were utilized as electrode material for supercapacitors. To our delight, the PS-900 demonstrated a maximum specific capacitance (Cs) of $303F\;g^{-1}$ in 1.0 M $H_2SO_4 $ at a scan rate of 5 mV. The electrochemical impedance spectra confirmed the poor electrical resistance of the electrode materials. Moreover, the stability of the PS-900 was found to be excellent (no significant change in the Cs even after 6000 cycles).

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.360.2-360.2
• /
• 2016

CuSn thin films were fabricated by rf magnetron co-sputtering method on the Si(100) substrate for evaluation of the antibacterial effect. The co-sputtering process was performed with different rf powers and sputtering times to regulate the thickness of the films and relative atomic ratio of Cu to Sn. The physicochemical properties of the CuSn thin films were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), X-ray induced Auger electron spectroscopy (XAES), Optical microscope (OM), 4-point probe, and antibacterial test. An antibacterial test was conducted with Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) as changing contact times between CuSn fillms and bacteria suspension. We compared to the crystalline structures of films before sterilization and after sterilization by XRD measurement. The changes of oxidation states of Cu and Sn and the chemical environment of films before and after antibacterial test were investigated with high resolution XPS spectra in the regions of Cu 2p, Cu LMM, and Sn 3d. After antibacterial test, the morphology of the films was checked with an OM images. The electrical properties of the CuSn films such as surface resistance and conductivity were measured by using 4-point probe.

• Publications of The Korean Astronomical Society
• /
• v.15 no.spc2
• /
• pp.1-13
• /
• 2000

Through the coupling between the near-earth space environment and the polar ionosphere via geomagnetic field lines, the variations occurred in the magnetosphere are transferred to the polar region. According to recent studies, however, the polar ionosphere reacts not only passively to such variations, but also plays active roles in modifying the near-earth space environment. So the study of the polar ionosphere in terms of geomagnetic disturbance becomes one of the major elements in space weather research. Although it is an indirect method, ground magnetic disturbance data can be used in estimating the ionospheric current distribution. By employing a realistic ionospheric conductivity model, it is further possible to obtain the distributions of electric potential, field-aligned current, Joule heating rate and energy injection rate associated with precipitating auroral particles and their energy spectra in a global scale with a high time resolution. Considering that the ground magnetic disturbances are recorded simultaneously over the entire polar region wherever magnetic station is located, we are able to separate temporal disturbances from spatial ones. On the other hand, satellite measurements are indispensible in the space weather research, since they provide us with in situ measurements. Unfortunately it is not easy to separate temporal variations from spatial ones specifically measured by a single satellite. To demonstrate the usefulness of ground magnetic disturbance data in space weather research, various ionospheric quantities are calculated through the KRM method, one of the magneto gram inversion methods. In particular, we attempt to show how these quantities depend on the ionospheric conductivity model employed.

• The Bulletin of The Korean Astronomical Society
• /
• v.38 no.2
• /
• pp.38.1-38.1
• /
• 2013

We present the Yonsei evolutionary population synthesis (YEPS) models based on the high-resolution empirical spectral energy distributions (SEDs). We have adopted the MILES library in the optical wavelength, and our new models based on the MILES library show good agreements with our previous models presented in the YEPS I. The effect of hot horizontal-branch (HB) stars on the integrated properties of simple stellar populations (SSPs) is again confirmed by our models based on empirical SEDs. In addition, we have extended our empirical models to the near-IR wavelength and predicted the strengths of the calcium II triplet (CaT) and the Paschen triplet (PaT) based on the INDO-US and the Cenarro library. We find that the effect of HB stars and the age of SSPs on the CaT is almost negligible. On the other hands, the PaT models are very sensitive to the existence of hot stars, e.g., HB stars and young turn-off stars, and show very similar results with Balmer lines. Interestingly, the CaT distribution of GCs in NGC 1407, which is at odds with the optical (B-I) color distribution, can be explained by the unique feature of the CaT-[Fe/H] relations that show almost the same equivalent widths in the metal-rich regime. We will also discuss the impact of the second-generation populations on the strength of the CaT.