• Tribology and Lubricants
• /
• 제30권6호
• /
• pp.378-383
• /
• 2014

This study predicts the of the hysteretic friction of a rubber block sliding on an SMA asphalt road. The friction of filled rubber on a rough surface is primarily determined by two elements:the viscoelasticity of the rubber and the multi-scale perspective asperities of the road. The surface asperities of the substrate exert osillating forces on the rubber surface leading to energy dissipation via the internal friction of the rubber when rubber slides on a hard and rough substrate. This study defines the power spectra at different length scales by using a high-resolution surface profilometer, and uses rubber and road surface samples to conduct friction tests. I consider in detail the case when the substrate surface has a self affine fractal structure. The theory developed by Persson is applied to describe these tests through comparison with the hysteretic friction coefficient relevant to the energy dissipation of the viscoelastic rubber attributable to cyclic deformation. The results showed differences in the absolute values of predicted and measured friction, but with high correlation between these values. Hence, the friction prediction model is an appropriate tool for separating the effects of each factor. Therefore, this model will contribute to clearer understanding of the fundamental principles of rubber friction.

• 한국광물학회지
• /
• 제18권1호
• /
• pp.45-52
• /
• 2005

2차원 고상 핵자기 공명기(2-dimensional solid-state NMR, 이하 2차원 고상NMR)와 관련된 기술과 이론의 발전과 더불어 획기적으로 증가한 스펙트럼의 분해능으로 기존의 일차원 NMR 로는 얻을 수 없었던, 비정질 규산염(유리질, 용융체, silicate glasses and melts)의 다양한 원자-분자 단위의 구조를 규명할 수 있다. 본 논문에서는 이러한 2차원 고상 NMR 방법론의 하나인 3QMAS NMR을 이용하여 이전까지 알려지지 않았던 고압환경에서의 비정질 지구물질의 원자/분자 구조에 대한 최근의 연구결과를 간략히 소개한다.

• 천문학회보
• /
• 제45권1호
• /
• pp.42.3-42.3
• /
• 2020

We investigate the observational properties of Wolf-Rayet stars, suggest the constraint of their mass-loss rate and apply our results to the observed progenitor candidates of Type Ib/Ic supernovae (iPTF13bvn and SN 2017ein). For this purpose, we adopt the WR star models with various mass-loss rates and wind terminal velocities. We obtain the high resolution spectra of those models at the pre-supernova phase using the radiative transfer code CMFGEN. We verify the optically faint property of SN Ic progenitors and show that the optical faintness is mainly originated by the high effective temperature at the photosphere. We also show that a simple analytic model for WR winds using a constant opacity can roughly predict the photospheric parameters. We show that the change of the mass-loss rate and the terminal wind velocity critically affects the optical luminosity. We find the optical luminosities of SN Ic progenitor models with our fiducial mass-loss rate prescription are fainter than the detection limits. We also suggest the mass-loss rate of WR stars may not exceed 2 times of our fiducial value by comparing our predictions with the detection limit of SN Ib/Ic progenitors. The directly observed progenitor candidate of iPTF13bvn can be explained by our SN Ib progenitor models. We find that the SN 2017ein progenitor candidate is too bright and too blue to be a SN Ic progenitor.

• 천문학회보
• /
• 제39권2호
• /
• pp.98-98
• /
• 2014

Due to the simple vertical structure of magnetic field, pores can be exploited to study the transport of mechanical energy by waves along the magnetic field to the chromosphere and corona. For a better understanding of physics of pores, we have investigated chromospheric traveling features running across two merged pores from their centers at the speed about 55 km s-1, in the active region AR 11828. The pores were observed on 2013 August 24 by using high time, spatial, and spectral resolution data from the Fast Imaging Solar Spectrograph (FISS) of the 1.6 meter New Solar Telescope (NST). We infer a LOS velocity by applying the bisector method to the Ca II $8542{\AA}$ band and $H{\alpha}$ band, and investigate intensity and the line-of-sight velocity changes at different wavelengths and different positions at the pores. We find that they have 3 minutes oscillations, and the intensity oscillation from the line center is preceded by that from the core ($-0.3{\AA}$) of the bands. There is no phase difference between the intensity and the LOS velocity oscillations at a given wavelength. The amplitude of LOS velocity from near the core spectra is greater than that from the far core spectra. These results support the interpretation of the observed wave as a slow magnetoacoustic wave propagating along the magnetic field lines in the pores. The apparent horizontal motion and a sudden decrease of its speed beyond the pores can be explained by the projection effect caused by inclination of the magnetic field with a canopy.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
• /
• pp.571-571
• /
• 2012

We discovered the formation of C60 aggregates in solution by means of photoluminescence spectroscopic study on C60 in solutions. From the in-depth investigation of temperature dependence of the luminescence of C60 in toluene, benzene and CS2 solutions, we reported that the C60 aggregates are formed during cooling at the freezing temperature of these solvents. Furthermore, the C60 aggregates can be changed to stable structures by irradiating with UV pulse-laser (Nd:YAG laser, 355nm). As a consequence, we could obtain nano-scale photo-polymerized C60 clusters, which appear as round-shaped nano- scale particles in high resolution transmission electron-microscopy (HRTEM) images. However, the yield of the nano-scale C60 clusters obtained by this method is too small. So we designed and developed a system to obtain C60 cluster of macroscopic quantity by using ultrasonic nebulizer. In this system, C60 solution was vaporized to several micro-sized droplets in vacuum, resulting in the formation of C60 aggregates by evaporating solvent (toluene). The system was invented to produce nano-scale carbon clusters by the irradiation of UV light upon C60 aggregates in vacuum. We have characterized the products, C60 cluster, obtained from the system by using UV absorption spectra and HPLC spectra. Although the products have a possibility of inclusion various forms of C60 cluster, results support that the product formed from the system by using vaporizer method establishes a new method to obtain C60 cluster in macroscopic quantity. In the presentation, the details of the system and the results of characterization are reported.

• 대한원격탐사학회지
• /
• 제21권3호
• /
• pp.173-188
• /
• 2005

The present study aims to derive and compare narrow and broad bandwidths of ocean color sensor’s algorithms for the study of monitoring highly dynamic coastal oceanic environmental parameters using high-resolution imagery acquired from Multi-spectral Camera (MSC) on KOMPSAT-2. These algorithms are derived based on a large data set of remote sensing reflectances ($R_{rs}$) generated by using numerical model that relates $b_b/(a + b_b)$ to $R_{rs}$ as functions of inherent optical properties, such as absorption and backscattering coefficients of six water components including water, phytoplankton (chl), dissolved organic matter (DOM), suspended sediment (SS) concentration, heterotropic organism (he) and an unknown component, possibly represented by bubbles or other particulates unrelated to the first five components. The modeled $R_{rs}$ spectra appear to be consistent with in-situ spectra collected from Korean waters. As Kompsat-2 MSC has similar spectral characteristics with Landsat-5 Thematic Mapper (TM), the model generated $R_{rs}$ values at 2 ㎚ interval are converted to the equivalent remote sensing reflectances at MSC and TM bands. The empirical relationships between the spectral ratios of modeled $R_{rs}$ and chlorophyll concentrations are established in order to derive algorithms for both TM and MSC. Similarly, algorithms are obtained by relating a single band reflectance (band 2) to the suspended sediment concentrations. These algorithms derived by taking into account the narrow and broad spectral bandwidths are compared and assessed. Findings suggest that there was less difference between the broad and narrow band relationships, and the determination coefficient $(r^2)$ for log-transformed data [ N = 500] was interestingly found to be $(r^2)$ = 0.90 for both TM and MSC. Similarly, the determination coefficient for log-transformed data [ N = 500] was 0.93 and 0.92 for TM and MSC respectively. The algorithms presented here are expected to make significant contribution to the enhanced understanding of coastal oceanic environmental parameters using Multi-spectral Camera.

• 천문학회보
• /
• 제44권1호
• /
• pp.86-86
• /
• 2019

We present BV photometric observations and high-resolution spectra of AO Ser, which were obtained at the Mt. Lemmon Optical Astronomy Observatory (LOAO) and the Bohyunsan Optical Astronomy Observatory (BOAO), respectively, in 2017. The radial velocities (RVs) for both components were measured, and the effective temperature of the primary star was found to be $T_{eff,1}=8,820{\pm}62K$ by a comparison of the observed spectra and the Kurucz models. A unique set of fundamental parameters of AO Ser were derived for the first time by a simultaneous analysis of the light and RV curves. The results indicate that our program target is a semi-detached eclipsing system with values of $M_1=2.06{\pm}0.11M_{\odot}$ and $M_2=0.41{\pm}0.03M_{\odot}$, $R_1=1.54{\pm}0.03R_{\odot}$ and $R_2=1.30{\pm}0.02R_{\odot}$, and $L_1=12.9{\pm}0.2L_{\odot}$ and $L_2=0.9{\pm}0.3L_{\odot}$. We applied multiple frequency analyses to the eclipse-subtracted light residuals. As a result, two frequencies of $f_1=21.85151days^{-1}$ and $f_2=23.48405days^{-1}$ were detected and their pulsation constants were calculated to $Q_1=0.0344days$ and $Q_2=0.0320days$. The pulsational characteristics and the position in the HR diagram demonstrate that the primary star is a ${\delta}$ Sct pulsator.

• 천문학회보
• /
• 제46권1호
• /
• pp.34.4-35
• /
• 2021

We present the TESS photometry and our high-resolution spectra of the semi-detached Algol EW Boo. For an orbital period study, we collected all available times of minima including ours for the last 30 years. It is found that the eclipse timing variation of the system can be represented by a periodic oscillation of 18.5±1.0 yr plus a secular period increase with a rate of [dP/dt]_orb=-6(±3)×10^-8 d yr^-1. From our observed spectra, the effective temperature of the primary star was determined to be T_eff,1=8560±118 K. From a simultaneous analysis of the TESS light and our double-lined radial velocity curves, the absolute masses, radii, and luminosities are M₁=2.30±0.07M_⊙, M₂=0.38±0.01M_⊙, R₁=1.92±0.02 R_⊙, R₂=1.27±0.01 R_⊙, L₁=1.92±0.02 L_⊙, and L₂=0.752±0.007 L_⊙, respectively. Multiple frequency analyses were carried out for the light residuals after subtracting the binary star model. We detected a total of 75 frequencies in the region of 16.50-104.8 day-1. Our results demonstrate that the more hotter primary star of EW Boo is a δ Sct pulsator by considering its position in the δ Scuti region of the Cepheid instability strip and pulsational characteristics.

• 공업화학
• /
• 제18권3호
• /
• pp.218-226
• /
• 2007

키랄성 말단기의 에폭사이드는 키랄중간체나 여러 출발물질로서 다양하게 이용되기 때문에 입체선택적인 합성방법은 학술적으로나 산업적인 관점에서 대단히 흥미롭다. 본 연구에서는 염화갈륨, 인듐 및 탈륨을 함유한 2분자형의 키랄성 코발트 살렌 촉매를 새로이 합성하고 그 특성을 평가하였다. 촉매가 2분자형을 갖는지의 직접적인 증거를 질량분석과 EXAF분석을 통하여 제시하였다. 합성한 촉매는 여러 종류의 에테르 및 에스테르 그룹을 함유한 에폭사이드 유도체의 가수분해의 속도차에 의한 비대칭 고리열림반응에 적용하여 그 활성과 선택성을 조사하였다. 합성이 용이한 2분자구조의 살렌착체 촉매는 물을 친핵체로 하는 라세믹 에폭사이드의 고리 열림을 통하여 99%ee 이상을 나타낼 정도의 매우 높은 광학선택성을 보였다. 2분자형의 살렌 촉매는 단분자형의 촉매에 비하여 촉매량을 적게 첨가하여도 현저히 향상된 촉매활성을 나타내었다. 본 연구에서 적용한 촉매시스템은 키랄 에폭사이드 및 1,2-디올 중간체의 제조에 매우 효과적이었다

• Korean Chemical Engineering Research
• /
• 제46권4호
• /
• pp.769-776
• /
• 2008

키랄성 말단기의 에폭사이드는 키랄중간체나 여러 출발물질로서 다양하게 이용되기 때문에 그 선택적인 합성법은 매우 유용하다. 본 연구에서는 염화코발트(II), 염화철(III) 및 질산아연(II)을 각각 함유한 키랄 코발트 살렌 촉매를 새로이 합성하고 그 특성을 평가하였다. 질량분석과 EXAF분석을 통하여 형성된 촉매 착체의 구조를 평가하였다. 합성한 촉매는 방향족 에폭사이드인 스타이렌 옥사이드와 페닐글리시딜 에테르의 속도차에 의한 비대칭 가수분해적 고리열림반응과 글리시틸부틸레이트의 합성반응에 적용하여 그 활성과 선택성을 조사하였다. 합성이 용이한 전이금속염함유 살렌착체 촉매는 물을 친핵체로 하는 라세믹 에폭사이드의 고리 열림을 통하여 99%ee 이상을 나타낼 정도의 매우 높은 광학선택성을 보였으며, 적은 양의 첨가로도 높은 활성을 보였다. 본 연구에서 적용한 촉매씨스템은 키랄 에폭사이드 및 1,2-디올 중간체의 제조에 매우 효과적이었다.