• Title/Summary/Keyword: high pressure phase

Search Result 996, Processing Time 0.024 seconds

High Pressure Phase Transition Study of ${\alpha}$-cristobalite $GaPO_4$ (${\alpha}$-크리스토발라이트 구조의 $GaPO_4$에 대한 고압 상변이 연구)

  • Hwang, Gil-Chan;Kim, Young-Ho
    • Journal of the Mineralogical Society of Korea
    • /
    • v.23 no.3
    • /
    • pp.267-272
    • /
    • 2010
  • High pressure x-ray diffraction patterns of ${\alpha}$-cristobalite gallium phosphate ($GaPO_4$) were acquired up to 8.9 GPa at room temperature using Mao-Bell type diamond anvil cell with high flux synchrotron radiation. Starting orthorhombic phase (phase-I) shows the splitting of peak which is possibly resulted from the pressure induced orientation disorder of the framework structure of tetrahedra. This is designated as phase-I'. This phase transforms to the orthorhombic high pressure phase-III between 2 and 3 GPa. Present phase transition sequence is not in accord with the recent high pressure X-ray diffraction results performed on the same starting sample (Ming et al., 2007). X-ray pattern of the unloaded sample to ambient pressure shows that the structure retains that of the high pressure phase prior to decompression.

Phase Transition Study on Graphite at Room Temperature (고압하에서 방사광을 이용한 흑연에 대한 연구)

  • Kim, Young-Ho;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
    • /
    • v.6 no.2
    • /
    • pp.88-95
    • /
    • 1997
  • High pressure X-ray diffraction study was carried out on a polycrystalline graphite to investigate the phase transition(s) at room temperature. Energy dispersive X-ray diffraction method was employed using a Mao-Bell type diamond anvil cell with an Wiggler synchrotron Radiation at the National Synchrotron Light Source. Sodium chloride power was used as the internal pressure sensor for the high pressure determinations as well as the pressure medium for quasihydrostatic pressure environment. Graphite transforms into a hexagonal didose not agree with the previously reported observations and this phase persists when pressure is released down to 0.1 MPa. This result dose not agree with the previously reported observations and this discrepancy would be due to the kinetics in phase transition as well as the uniaxially oriented pressure field in the diamond anvil cell.

  • PDF

A Study on the Flow Characteristic of surroundings of the Extracting Nozzle for Shell Wall Thinning of a Feedwater Heater (고압형 급수가열기 동체 감육 완화를 위한 추기노즐 주변의 유동특성 연구)

  • Seo, Hyuk-Ki;Kim, Yoon-Shin;Kim, Kyung-Hun;Hwang, Kyeong-Mo
    • Proceedings of the SAREK Conference
    • /
    • 2009.06a
    • /
    • pp.841-846
    • /
    • 2009
  • Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction stream line inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. This paper describes operation of experience and numerical analysis composed similar condition with real high pressure feedwater heater. This study applied several impingement baffle plates to feedwater heater same as previous study. In addition, it shows difference of pressure distribution and value between single phase and two phase based on experience and numerical analysis.

  • PDF

A Study on the Relief of Shell Wall Thinning of High pressure Feedwater Heater (고압형 급수가열기 동체 감육 완화에 관한 연구)

  • Kim, Hyung-Joon;Park, Sang-Hoon;Seo, Hyuk-Ki;Kim, Kyung-Hoon;Hwang, Kyung-Mo
    • Proceedings of the KSME Conference
    • /
    • 2008.11b
    • /
    • pp.2664-2669
    • /
    • 2008
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damange, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction stream line- inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes operation of experience and numerical analysis composed similar condition with real high pressure feedwater heater. This study applied squared, curved and new type impingement baffle plates to feedwater heater same as previous study. In addition, it shows difference of pressure distribution and value between single phase and two phase based on experience and numerical analysis.

  • PDF

High pressure X-ray diffraction study on a graphite using Synchrotron Radiation (고압하에서 방사광을 이용한 흑연에 대한 연구)

  • Kim, Young-Ho;Na, Ki-Chang
    • The Journal of the Petrological Society of Korea
    • /
    • v.3 no.1
    • /
    • pp.34-40
    • /
    • 1994
  • High pressure X-ray diffraction study was carried out on a graphite to investigate its compressibility as well as any possible phase transition to the hexagonal diamond structure at room temperature. Energy dispersive X-ray diffraction method was introduced using a Mao-Bell type diamond anvil cell with Synchrotron Radiation. Polycrystalline sodium chloride was compressed together with graphite for the high pressure determinations. Because of the poor resolution of the X-ray diffraction pattern of graphite, its compressibility was estimated to be almost same as that of NaCl by graphite (002) X-ray diffraction peak only. An observation of any new peak from a possible hexagonal diamond phase seems very unplausible for its definite identification based on the present data. Alternative approaches such as an Wiggler Radiation source as well as a Large Volume high pressure apparatus will be necessary for the detailed studies on a graphite in future.

  • PDF

Study on Spray Vaporization and Combustion in High Pressure Environment (고압에서의 분무의 증발 및 연소 현상에 관한 연구)

  • Wang, Tae-Joong;Baek, Seung-Wook
    • 한국연소학회:학술대회논문집
    • /
    • 2002.11a
    • /
    • pp.193-207
    • /
    • 2002
  • The present study is mainly motivated to investigate the vaporization, autoignition, and combustion of liquid fuel spray injected into high pressure environment. In order to represent these phenomena realistically, discrete droplet model (DDM) which simulates the spray using finite number of representative droplets was adopted for detailed consideration of the finite rate of uansport between liquid and gas phases. The Eulerian-Lagrangian formulation was used to analyze the two-phase interactions. The high pressure vaporization model was applied using the thermodynamic and phase equilibrium at droplet surface. The high pressure effect as well as high temperature effect was considered in the calculation of liquid and gas properties. The characteristics of spray in high pressure environment were explained by comparison with normal pressure case.

  • PDF

Unsteady Vaporization of Burning Droplet at High Pressure Environments With Linear Acoustic Mode (강한 음향장에 구속된 고압 액적의 연소)

  • Kim, Sung-Yup;Shin, Hyun-Ho;Yoon, Woong-Sup
    • Proceedings of the KSME Conference
    • /
    • 2004.11a
    • /
    • pp.1122-1127
    • /
    • 2004
  • an isolated droplet combustion exposed to pressure perturbations in stagnant gaseous environment is numerically conducted. Governing equations are solved for flow parameters at gas and liquid phases separately and thermodynamic parameters at the interfacial boundary are matched for problem closure. For high-pressure effects, vapor-liquid interfacial thermodynamics is rigorously treated. A series of parametric calculations in terms of mean pressure level and wave frequencies are carried out employing a n-pentane droplet in stagnant gaseous air. Results show that the operating pressure and driving frequency have an important role in determining the amplitude and phase lag of a combustion response. Mass evaporation rate responding to pressure waves is amplified with increase in pressure due to substantial reduction in latent heat of vaporization. Phase difference between pressure and evaporation rate decreases due to the reduced thermal inertia at high pressure. In addition to this, augmentation of perturbation frequency also enhances amplification of vaporization rate because the time period for the pressure oscillation is much smaller than the liquid thermal inertia time. The phase of evaporation rate shifts backward due to the elevated thermal inertia at high acoustic frequency.

  • PDF

Thermal Stability of Superconductor NdBCO Sintered at Various Oxygen Partial Pressures (다양한 산소분압에서 소결한 NdBCO 초전도체의 열적 안정성)

  • Chung, J.K.;Kim, W.J.;Park, S.C.;Kang, S.G.;Lim, Y.J.;Kim, C.J.
    • Progress in Superconductivity
    • /
    • v.10 no.2
    • /
    • pp.133-138
    • /
    • 2009
  • The $Nd_{1+x}Ba_{2-x}Cu_3O_{7-{\delta}}$(Nd123) superconductor exhibits high performance in high magnetic field and high temperature. We have studied phase stability for Nd123 under reduced oxygen partial pressure and various heat-treatment conditions. The main phase is Nd123 and some samples contain small amounts of Nd422 depending on the temperature and oxygen partial pressure. The decomposition temperature decreases with decreasing oxygen partial pressure from $1052^{\circ}C(P(O_2)$=150 Torr) to about $845^{\circ}C(P(O_2)$=0.1 Torr). The liquidus line was steeper temperature with decreasing oxygen partial pressure. In same condition of oxygen partial pressure, the region of stable Nd123 phase was formed at slightly higher temperature than the region of stable YBCO phase.

  • PDF

Design Modification and Correlation Verification between Reattachment Flow of Dispersed Jet and Local Thinning of Feedwater Heater (충돌로 인해 분산된 2상 제트스팀의 재부착 현상과 국부 감육 상관관계 규명 및 설계개선에 관한 연구)

  • Kim, Hyung-Joon;Kim, Kyung-Hoon;Hwang, Kyeong-Mo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.21 no.9
    • /
    • pp.483-495
    • /
    • 2009
  • Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damange, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle-installed downstream of the high pressure turbine extraction stream line-inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes operation of experience and numerical analysis composed similar condition with real high pressure feedwater heater. This study applied squared, curved and new type impingement baffle plates to feedwater heater same as previous study. In addition, it shows difference of pressure distribution and value between single phase and two phase based on experience and numerical analysis.

A Study on Effects of Piston Pumping Phase on Vibration and Noises of Tandem Swash Plate Type Axial Piston Pump(2) (피스톤 펌핑 위상이 텐덤형 사판식 액셜 피스톤 펌프의 진동, 소음에 미치는 영향에 관한 연구(2))

  • Park, Sung-Hwan;Lee, Jin-Kul
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.16 no.12
    • /
    • pp.31-39
    • /
    • 1999
  • Previous researches and experiments have already verified that the primary noise source of high pressure tandem axial thpe piston pump is fluid-borne noise from the process of oil distribution between the kidney-shaped port and valve plate. So, many researchers have improved pressure gradients and reduced sound levels by applying pre-compression and pre-decompression metering grooves to valve plate. In practice however, the sound level of th high pressure tandem axial type piston pump is still undesirable. This paper testified the effect of pumping phase of the piston on vibration and noise of th high pressure tandem axial type piston pump on the best of theoretical research in $this^(1)$. Therefore considering the pumping phase of the piston when assembling the tandem axial type piston pump, it is possible to reduce 1.5~2[dB]of sound level.

  • PDF