• Title/Summary/Keyword: high curing temperature

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A Study on the Properties of Epoxy Based Powder Coating with Various Curing Agents (에폭시 분체도료의 경화제 종류에 따른 물성에 관한 연구)

  • Park, Jae-Hong;Shin, Young-Jo
    • Applied Chemistry for Engineering
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    • v.9 no.1
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    • pp.58-65
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    • 1998
  • Substituted dicyandiamide(Sub-DICY), Accelerated dicyandiamide(Acc-DICY), Trimellitic anhydride(TMA), Pyromellitic dianhydride(PMDA) and Phenolic curing agent(Ph.C.A.) are mainly used for epoxy powder coating curing agent. Various characteristics of epoxy films fully cured by optimum condition such as mechanical properties like $T_g$, tensile strength, elongation at break hardness, abrasion resistance and chemical properties like water absorption, acid resistance, alkali resistance and electrical properties, corrosion resistance are determined by various measuring devices and analyses devices. In conclusion, phenolic curing agent was shown excellent thoughness but severe color change as temperature increased. Acid anhydride has excellent insulation properties and color stability at elevated temperature but lower thoughness and adhesion to substrate. DICY curing agent was shown high water absorption and severe color chance as temperature increased.

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Studies on the Prevention of Excessive Drying Leaves during Burley Tobacco Curing III. Effect of the Ventilating Conditions on the Occurrence of Excessive Curing Leaves (버어리종 건조시 급건엽발생방지에 관한 연구 III. 환기조건이 급건엽발생에 미치는 영향)

  • 배성국
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.32 no.2
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    • pp.130-136
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    • 1987
  • The studies were carried out to investigate the occurrence of excessive dried leaves during burley tobacco curing. Six different periods of ventilation during the entire stage of curing were applied. And also 3 different heights of rolling up polyethlene film for side ventilation of the curing house combined with 4 different spaces between garlands were applied from after yellowing. The high air temperature and low relative humidity from end of yellowing to end of browning stage were the most critical to occur excessive dried \eaves. As side ventilation was continued for the entire stage of curing, air temperature in curing house was lower and occurrence of excessive dried leaves were remarkably decreased. The air temperature was not affected on hanging spaces, but relative humidity that resulted significantly in decreasing of the excessive dried leaves was increased by narrowing of hanging spaces. As excessive dried leaves were increased, its price per kg was lower, its physical properties was worse and its total nitrogen and total suger were higher than those of normal cured leaves.

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A study on the Fundamental Properties of Concrete with Belite Cement (벨라이트시멘트 콘크리트의 기초적 성질에 대한 연구)

  • 문한영;문대중;하상욱;김기수
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04a
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    • pp.167-170
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    • 1998
  • As construction technology advances, most of concrete structures are becoming larger and taller. Therefore, high strength and high quality concrete is necessary for them. Nowadays, the proposal of using belite rich cement is investigated to satisfy high flowing, low heat, and high strength. In this study, the height difference, the falling time and the maximum temperature of concrete using BRC were lower than that of concrete using OPC. Furthermore the compressive strength of concrete using BRC with and without compacting was not different. And the compressive strength of core specimens was higher than that of specimens in water curing. Compared to OPC, there was a good relationship between the curing temperature and the development of strength in BRC.

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Characteristics of Strength Development of Ultra-High Performance Concrete according to Curing Condition (초고성능 콘크리트의 양생 조건에 따른 강도 발현 특성)

  • Park, Jong-Sup;Kim, Young-Jin;Cho, Jeong-Rae;Jeon, Se-Jin
    • Journal of the Korea Concrete Institute
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    • v.25 no.3
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    • pp.295-304
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    • 2013
  • Ultra-High Performance Concrete (UHPC) has recently been one of the most active research fields in Korea as well as in foreign countries, because it can contribute to a longer life and economic efficiency of structures. Although precast-type UHPC fabricated in a factory is preferable in terms of quality control and reduction of construction period, there exist, even in the precast structure, some parts that need to be cast in-place such as the joints between precast segments. In the cast-in-place UHPC, however, it is probable that an optimum curing condition can hardly be realized in contrast to the factory production. In this study, therefore, the trend of compressive strength development of UHPC was experimentally investigated by assuming various inferior curing conditions that may be anticipated at a construction site. Concrete specimens were fabricated and cured under different conditions with the variables such as curing temperature, delay time before the initiation of curing, duration of curing time and moisture condition. The strengths were compared with those of the specimens cured by standard high temperature steam. Through the analysis of the test results, some minimum requirements for curing have been proposed that are required when the UHPC is cast in-place. It is expected, through this study, that practical use of UHPC in construction sites can be increased.

Variation of Yield and Oxygen Content of SiC-Based Ceramics with the Conversion Processes of PCS (PCS의 전환공정에 따른 SiC세라믹스 수율 및 산소 함량 변화)

  • Kim, Joung-Il;Kim, Weon-Ju;Park, Ji-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.188-192
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    • 2005
  • The conversions to SiC-based ceramics of a polycarbosilane (PCS) with and without oxidation curing were carried out. A yield and an oxygen content of conversed SiC-based ceramics were evaluated. The weight losses of conversed SiC-based ceramics by both processes analyzed to estimate the high temperature stability after heat treatment at high temperature in vacuum. The yield of SiC­based ceramics after oxidation curing was higher than that without curing process. However, the weight loss of SiC-based ceramics with oxidation curing was larger than that without curing process after heat treatment.

Cure Kinetics and Thermal Properties of Epoxy Resin Initiated by Methylanilinium Salts as a Latent Cationic Curing Agent (잠재성 양이온 경화제로서 methylanilinium 염에 의해 개시된 에폭시 수지의 경화 동력학 및 열적 특성)

  • 김택진;박수진;이재락
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.11a
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    • pp.34-37
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    • 2000
  • The effect of novel N-crotyl-N,N-dimethyl-4-methylanilinium hexafluroantimonate (CMH) curing agent on cure behavior and thermal properties of DGEBA epoxy cationic system was investigated. From DSC measurements of DGEBA/CMH system, it was shown that this system exhibits an excellent thermal latent characteristic in a given temperature and reveals complex cure behavior as indicated by multiple exotherms. The conversion and conversion rate of DGEBA/CMH system increased with increasing the concentration of initiator due to high activity of CMH. Viscoelastic properties during gel formation of DGEBA with CMH were investigated by rheological techniques under isothermal condition. The gel time obtained from the modulus crossover. point t(G')=G", was affected by high curing temperature and concentration of CMH, resulting in high degree of network formation in cationic polymerization. The thermal stabilities were discussed in terms of the activation energy for decomposition and thermal factors determined from TGA measurements.ents.

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A Fundamental Test of Temperature Crack Reduction Method Application by Setting Time Control of Large-Scaled Mat Foundation Mass Concrete (초대형 매트기초 매스 콘크리트의 응결시간조정에 의한 온도균열저감 공법적용의 기초적 실험)

  • Han, Cheon-Goo;Lee, Jae-Sam;Noh, Sang-Kyun
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.3
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    • pp.95-101
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    • 2009
  • Constructing large-scale mat foundation mass concrete is increasing for the stability of building structure, because a lot of high rise building are being built in order to make full use of limited space. However, It is of increasing concerns that because limited placing equipments, available job-site and systems for mass concete placement in construction field do not allow to place great quantity of concrete at the same time in large scale mat foundation, consistency between placement lift can not be secured. And also, it is likely to crack due to stress caused by the difference of hydration heat generation time. To find out the solution against above problems, this study is to reconfirm the performance of normal concrete designed by mix proportion and super retarding concrete. The Fundamental test shows what happens if low heat proportioning and control method of setting time are applied at the job-site of newly constructed high rise building. The test result show that slump flow of concrete has been somewhat increased as the target retarding time gets longer, while the air content has been slightly decreased but this is no great difference from normal concrete. The setting time shows to be retarded as target retarding time gets longer, the range of retarding time increases. It is necessary to increase the amount of mix of super retarding agent in the proportion ration by setting curing temperature high since outdoor curing is about 6 hours faster than standard curing, which means the temperature of the concrete will be higher than the temperature of the surrounding environment, due to its high hydration heat when applying in a construction site. The compressive strength of super retarding concrete appears to be lower than normal concrete due to the retarding action in the early stage. However, as the time goes by, the compressive strength gets higher, and by the 28th day the strength becomes the same or higher than normal concrete.

Study on the Development of Super-High-Early-Strength Mortar Using the Hardening catalyst and High early strength cement (조강시멘트를 사용한 초조강 모르타르 개발에 관한 연구)

  • Cho, In-Sung;Hur, Yeon-Ok;Min, Tae-Beom;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.217-219
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    • 2012
  • In this study, the experiment was conducted in the level of mortar as one of the basic studies on pre-cast concrete which acceleration curing is not done. This study has the purpose to develop the strength of mortar into 20MPa within 6 hours in the condition of room temperature using admixtures which can accelerate C3S hydration reaction. In this experiment, W/C was fixed into 20%, PCE which can stimulate C3S was used as an accelerating admixture. From the results of this experiment, maximum content of accelerating admixture was 1%. Also, as more than 20MPa was measured through 6-hour compressive strength, it can be known that strength can be developed without steam-curing.

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An Experimental Study on the Influence of Heat of Hydration in High Strength Concrete during Hardening Process (고강도콘크리트의 내부온도이력과 경화콘크리트의 특성에 관한 실험적 연구)

  • 윤영수;이승훈;박희민;성상래;백승준;장일영;신성우
    • Proceedings of the Korea Concrete Institute Conference
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    • 1994.10a
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    • pp.127-132
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    • 1994
  • This study attemps to investigate the influence of heat of hydration occured during hardening on the strength development of high strength concrete. The concrete design strengths of 500kg/$\textrm{cm}^2$ and 700kg/$\textrm{cm}^2$ were considered to simulated the square columns having $80\times80cm$ and $100\times100cm$, respectively. Both standard curing and field curing specimen were prepared at the specified ages, and the cores were drilled out from the structure. The thermal sensors were installed into the specimen to measure the heat of hydration process occurred during the hardening. This paper tries to uncover the relationship between the temperature history of the concrete and strength development. The correlation of core strength and specimen strength with curing condition is also discussed. Further research is desired to enlight the relationship between strength and heat of hydration of high strength concrete.

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Studies on the Method of Reducing of the Photobleaching Leaves and Shortening the Curing Period in Burley Tobacco Stalk Curing (버어리종담배 대말림시 백화엽발생방지 및 건조기간단축에 관한 연구)

  • 김상범;백기현;추홍구
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.28 no.2
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    • pp.252-257
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    • 1983
  • This study was conducted to find out the stalk curing methods that can reduce photobleaching, and shorten the curing period in burley to bacco stalk curing. The results obtained summarized as follows. In the ventilation window-plot, the temperature within the curing house was high and the curing period was shortened, too. The rate of photobleached leaves of whole plant stalk curing-plot was higher than those of any other plots. In the ventilation window-plot, the labor of operating the curing house was saved and the yield and visual quality of cured leaves were high, too. For reducing the photobleaching of leaves, following procedures are desirable; to prevent the lower leaves from drying up and overripening at maturing stage, cut the stalk after first or second priming, shorten the curing period as possible when the 80% of leaf bodies changed brown.

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