• 한국세라믹학회지
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• 제36권12호
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• pp.1342-1349
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• 1999

In order to improve the density and the mechanical strength without change in chemical composition the hardened pastes of hydroxyapatite cement were reinforced with powders and/or whiskers of hydroxyapatite. The powders behaved as a seed of hydroxyapatite formation rather than a filler while the whiskers were mrerly dispersed in matrix and capillary pores of the hardened bodies leading to increase in mechanical strength. But the increase in strength But the increase in strength was nnt enough owing to the lack of homogeneous dispersion of the fibers. The highest diametral tensile strength of 18.5 MPa was measured at the hardened hydroxyapatite body in which well-dispersed whisker phase formed uniformly during hydro-thermal curing of power-added and dry-formed hydroxyapatite cement.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2015년도 추계 학술논문 발표대회
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• pp.24-25
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• 2015

To secure fundamental materials for the performance change in concrete structure damaged by fire, this study analyzed SEM and XRD of hardened cement depending on high temperature conditions. As a result, at more than 200℃, SEM and XRD were not observed because of dehydration of Ettringite; at more than 500℃, calcium hydroxide was rapidly decomposed; at more than 700℃, calcium oxide was found; at 1000℃, the highest peak point appeared.

• 한국건설순환자원학회논문집
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• 제6권4호
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• pp.103-111
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• 2012

압축강도 50 MPa이상의 압출성형 시멘트 패널은 고온고압 증기양생으로 생산된다. 고온고압 증기양생에서 요구 강도를 얻기 위해서는 시멘트에 포함되어 있는 CaO와의 반응에 필요한 적정량의 $SiO_2$를 공급하는 것이 관건이다. $SiO_2$의 공급원으로 가장 널리 사용되는 원료는 규석분인데, 이는 환경파괴를 전제로 하기 때문에 친환경적인 제품 생산을 위하여 본 연구에서는 규석분을 대신하여 폐석분을 활용한 시멘트 2차 제품을 생산하고 이에 대한 압출성과 물리적인 특성비교를 실시하였다. 이를 위하여 화성 석산에서 채취한 폐석분을 건조 파쇄한 후 이를 규석분 사용량의 최대 50%까지 치환하여 압출성 및 물리적 특성 실험을 수행하였다. 실험결과 평균 입경은 폐석분과 규석분의 크기가 유사하였으나 물리적 특성은 규석분을 폐석분으로 단순 치환하였을 경우, 대부분 낮게 발현되었다. 따라서 폐석분을 활용할 경우 수화활성을 위한 첨가제 등의 활용이 필요할 것으로 판단된다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.727-730
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• 2003

The objective of this work is to understand the deterioration mode of ordinary portland cement pastes and mortars immersed in 5% sodium sulfate solution for 510 days. In order to achieve the goal, x-ray diffraction (XRD) and scanning electron microscopy (SEM) are presented in this experimental work. Strength deterioration (SDF) and length change of the mortars were also measured to evaluate resistances to the attacking solution. The mortars were prepared by using water-cement ratio of 35%, 45% and 55%, respectively, and the water-cement ratio of pastes was fixed at 45%. Conclusively, the deterioration by sodium sulfate attack was primarily due to the formation of ettringite and thaumasite. This process of deterioration may submit the reasonable understanding on the sulfate attack mechanism of hardened cement pastes, mortars, and concretes.

• 콘크리트학회논문집
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• 제16권2호
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• pp.277-282
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• 2004

In a hardened concrete, diffusion of oxygen, carbon dioxide, aggressive ions, and moisture from the environment to the concrete takes place through the pore network. It is well known that making dense cement matrix enhances the durability of concrete as well as all the characteristics including strength of concrete. In this paper,9 mix concretes with water to cementitious material ratio (40,45, and $50\%$) and replacement ratio of GGBFS (40 and $60\%$ of cement by weight) were studied on the micro-pore structure by mercury intrusion porosimetry and the accelerated chloride diffusion test by potential difference. From the results the average pore diameter and accelerated chloride diffusivity of concrete were ordered NPC > G4C > G6C. It is concluded that there is a good correlation between the average pore diameter and the chloride diffusivity, and the mineral admixtures has a filling effect, which increases the tortuosity of pore and makes large pores finer, on the pore structure of cement matrix due to the latent hydraulic reaction with hydrates of cement.

• 콘크리트학회논문집
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• 제17권3호
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• pp.473-480
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• 2005

In this study, a mix design for self compacting concrete was based on Okamura's method and concrete incorporated just a ground granulated blast furnace slag. Replacement ratio of slag is in the range of $20-80\%$ of cement matrix by volume. For the optimal self compactability in mixture incorporating ground granulated blast furnace slag, the paste and mortar tests were first completed. Then the slump flow, elapsed time of 500mm slump flow, V funnel time and filling height by U type box were conducted in concrete. The volume of coarse aggregate in self compacting concrete was in the range of $50-60\%$ to the solid volume percentage of coarse aggregate. Finally, the compressive and splitting tensile strengths were determined in the hardened self compacting concrete incorporating ground granulated blast furnace slag. From the test results, it is desirable for self compacting concrete that the replacement of ground granulated blast furnace slag is in the range of $40-60\%$ of cement matrix by volume and the volume of coarse aggregate to the solid volume percentage of coarse aggregate with a limit of $55\%$.

• Advances in concrete construction
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• 제8권1호
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• pp.21-31
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• 2019

The rich recipe of ultra high performance concrete (UHPC) offers the higher mechanical, durability and dense microstructure property. The variable like cement/sand ratio, amount of supplementary cementitious material, water/binder ratio, amount of fiber etc. alters the UHPC hardened properties to any extent. Therefore, to understand the effects of these variables on the performance of UHPC, inevitably a stage-wise development is required. In the present experimental study, the effect of sand/cement ratio, the addition of finer material (fly ash and quartz powder) and, hybrid fiber on the fresh, compressive and microstructural property of UHPC is evaluated. The experiment is conducted in three phases; the first phase evaluates the flow value and strength attainment of ingredients, the second phase evaluates the efficiency of finer materials (fly ash and quartz powder) to develop the UHPC and the third phase evaluate the effect of hybrid fiber on the flow value and strength of ultra high performance hybrid fiber reinforced concrete (UHP-HFRC). It has been seen that the addition of fly ash improves the flow value and compressive strength of UHPC as compared to quartz powder. Further, the usage of hybrid fiber in fly ash contained matrix decreases the flow value and improves the strength of the UHP-HFRC matrix. The dense interface between matrix and fiber and, a higher amount of calcium silicate hydrate (CSH) in fly ash contained UHP-HFRC is revealed by SEM and XRD respectively. The dense interface (bond between the fiber and the UHPC matrix) and the higher CSH formation are the reason for the improvement in the compressive strength of fly ash based UHP-HFRC. The differential thermal analysis (DTA/TGA) shows the similar type of mass loss pattern, however, the amount of mass loss differs in fly ash and quartz powder contained UHP-HFRC.

• Computers and Concrete
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• 제32권2호
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• pp.185-206
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• 2023

This article aimed to explore the optimization of mineral admixtures and retarding admixture for high-performance concrete. In essence, fresh concrete can be regarded as a mixture in which both coarse and fine aggregates are suspended in a cement-based matrix paste. Based on this view, the test procedure was divided into three progressive stages of binder paste, mortar, and concrete to explore their rheological behavior and mechanical properties respectively. At each stage, there were four experimental control factors, and each factor had three levels. In order to reduce the workload of the experiment, the Taguchi method with an L9(3⁴) orthogonal array and four controllable three-level factors was adopted. The test results show that the use of the Taguchi method effectively optimized the composition of high-performance concrete. The slump of the prepared concrete was above 18 cm, and the slump flow was above 50 cm, indicating that it had good workability. On the other hand, the 28-day compressive strength of the hardened concretes was between 31.3-59.8 MPa. Furthermore, the analysis of variance (ANOVA) results showed that the most significant factor affecting the initial setting time of the fresh concretes was the retarder dosage, and its contribution percentage was 62.66%. On the other hand, the ANOVA results show that the most significant factor affecting the 28-day compressive strength of the hardened concretes was the water to binder ratio, and its contribution percentage was 79.05%.

• Composites Research
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• 제20권2호
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• pp.21-26
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• 2007

이 논문은 합성섬유를 이용하여 포틀랜드 시멘트 모르타르를 보강한 복합재료인 ECC(Engineered Cementitious Composite)의 설계 과정과 건설현장에 이 복합재료를 적용할 수 있도록 시공성을 부여한 연구 내용을 정리하였다. 이 연구에서는 다양한 시공성, 즉 자기충전(self·consolidating)과 스프레이 시공성을 갖는 ECC를 제작하기 위하여 단계적인 재료 개발 방법론을 채택하였다. 우선 마이크로역학(micromechanics)과 안정상태균열이론(steady-state cracking theory)을 이용하여 골재와 섬유를 선정한 후, 굳기 전 재료의 레올로지를 제어하는 방법으로 시공성을 구현하였다. 여기서, 굳기 전 재료의 레올로지를 제어하기 위하여 화학첨가제(chemical admixtures)와 광물첨가재(mineral admixtures)의 양을 소량으로 조절하는 방법을 사용하였다. 이러한 방법을 활용함으로써 굳기 전에는 다양한 시공성을 나타내면서, 굳은 후에는 높은 연성(인장변형경화 거동)을 나타내는 실용적인 ECC 복합재료를 개발하였다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.164-165
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• 2022

In order to solve problems such as acceleration of resource use and environmental pollution, experiments were conducted with the aim of producing indoor finishing materials that can adsorb fine dust and carbon dioxide using gelite and polymer, which are porous materials. Based on the previous experiment, gelite was substituted at each level in a matrix having a polymer S738P substitution rate of 12.5%, and the results are as follows. As the substitution rate of gelite increased, the amount of fine dust and carbon dioxide adsorption increased, which is believed to be due to physical adsorption due to the high porosity of gelite. However, further experiments are needed as the overall adsorption amount is not high due to the filling inside the matrix due to the polymer.