• Title/Summary/Keyword: halide

Search Result 443, Processing Time 0.022 seconds

Halide Perovskites for X-ray Detection: The Future of Diagnostic Imaging

  • Nam Joong Jeon;Jung Min Cho;Jung-Keun Lee
    • Progress in Medical Physics
    • /
    • v.33 no.2
    • /
    • pp.11-24
    • /
    • 2022
  • X-ray detection has widely been applied in medical diagnostics, security screening, nondestructive testing in the industry, etc. Medical X-ray imaging procedures require digital flat detectors operating with low doses to reduce radiation health risks. Recently, metal halide perovskites (MHPs) have shown great potential in high-performance X-ray detection because of their attractive properties, such as strong X-ray absorption, high mobility-lifetime product, tunable bandgap, low-temperature fabrication, near-unity photoluminescence quantum yields, and fast photoresponse. In this paper, we review and introduce the development status of new perovskite X-ray detectors and imaging, which have emerged as a new promising high-sensitivity X-ray detection technology. We discuss the latest progress and future perspective of MHP-based X-ray detection in medical imaging. Finally, we compare the conventional detection methods with quantum-enhanced detection, pointing out the challenges and perspectives for future research directions toward perovskite-based X-ray applications.

A Design of Electronic Ballast for 70W Metal Halide Lamps (70W 메탈핼라이드용 전자식 안정기의 설계)

  • 최명호;임성훈;한병성
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
    • /
    • v.13 no.3
    • /
    • pp.7-13
    • /
    • 1999
  • In this paper, a low wattage high frequency operation electronic ballast for double ended 70W metal halide lamp has been investigated As an input source of the proposed ballast, 220V, 60 Hz ac voltage is used and is converted high frequency ac voltage by power processing system. To prevent a physical destruction of the lamp from acoustic resonance phenorrenon, the proposed ballast sLWlies alternating voltage of 22kHz frequency to a metal halide lamp. It shows sorre efficacious result that reduce the start up tiIre of lamp and electric power consumption. By testing the proposed ballast, lamp voltage and lamp current are 155Vpeak, O.64A, respectively. Lamp luminous flux is 5300lm with 82W input power and ballast efficiency is 64.63 Im/w. The average starting tiIre and restriking tiIre of lamp are 3.9 and 4.5 minutes, respectively.tively.

  • PDF

Simulation of undewater irradiance distribution in coastal squid jigging vessel using the LED and metal halide fishing lamp combination (LED와 메탈헬라이드 집어등을 겸용한 연안 오징어채낚기 어선의 수중 방사조도 분포 시뮬레이션)

  • Bae, Jae-Hyun;An, Heui-Chun;Kim, Mi-Kyung;Park, Hae-Hun;Jung, Mee-Suk
    • Journal of the Korean Society of Fisheries and Ocean Technology
    • /
    • v.50 no.4
    • /
    • pp.511-519
    • /
    • 2014
  • This study is aimed to analyze the three-dimensional underwater irradiance using an optical simulation software and to clarify the propriety and operation method under considering luminous intensity distribution of the luring lamp and penetrability in the seawater, when we use the light diffuser type 300W high powered LED and the metal halide lamp (MHL) on a coastal squid jigging vessel in the 10-ton class, simultaneously. For their attenuation characteristics of each wavelength in relation to the sea, LED lamp was to be effective in the 1.9-fold at 50 m depth and 2.1-fold at 80 m for underwater irradiance more than MHL according to the power consumption. In addition, the underwater irradiance distribution using the LED and MHL combination was rather increased even when reducing total power usage up to 20% depending on the simulation with changing the configuration and lighting angle of the lamp. These results can be utilized as an evaluation method of the operation and performance of the LED lamp according to adjusting its arrangement and lighting angle.

Characteristics and Ring-Opening Isomerization Polymerization of 2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) (2-(1,3,3-Trimethyl-6-azabicyclo[3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline(TAO)의 개환이성화중합과 특성평가)

  • Lee, Chan-Woo;Chung, Jin-Do
    • Polymer(Korea)
    • /
    • v.36 no.3
    • /
    • pp.262-267
    • /
    • 2012
  • 2-(1,3,3-Trimethyl-6-azabicyclo [3,2,1]-oct-6-yl)-4,5-dihydro-1,3-oxazoline (TAO) was polymerized at several conditions to clarify the influence of initiators, alkyl halide ($PhCH_2Br$, $PhCH_2Cl$, MeI) and sulfonate (MeOTf). The reactions were conducted at $100^{\circ}C$ for 24 h. The resultant polymer forms several kinds of structures with different combination of initiators. The sole MeOTf initiator caused chain transfer reaction to form the one-order structure for which the resultant polymer exclusively formed pendant structure, while alkyl halide and MeOTf formed two kinds of structures, pendant and main chain, which is caused by partly-proceeded double isomerization polymerization by highly reactive nucleophilic counter anion of halogen. Merrifield polymer was also utilized as an intiator and copolymerized with TAO, which produced a graft structure.

Cooperative Effects of Solvatochromic Parameters on the Ionizations of tert-Butyl Halides in MeOH-1,1,2,2-Tetrachloroethane Mixtures (MeOH-1,1,2,2-Tetrachloroethane 혼합용매에서 tert-Butyl Halides의 이온화에 미치는 분광용매화변수들의 협동효과)

  • Yeol Sakong;Shi Choon KIm;Jae Bum Choo
    • Journal of the Korean Chemical Society
    • /
    • v.30 no.3
    • /
    • pp.265-272
    • /
    • 1986
  • Kinetic studies for the methanolysis of tert-butyl halides (t-BuCl, t-BuBr, t-BuI) were carried out in MeOH-1,1,2,2-tetrachloroethane mixtures. The solvatochromic comparison method was used with six indicators to analyze solvent effects on the ionizations of tert-butyl halides. It was shown that the cooperative effect of solvent polarity-polarizability was the most important factor influenced on the methanolysis rates of tert-butyl halides, but the electrophilic assistance for halide leaving group and the nucleophilic assistance for tert-butylium ion were considerably influential, too. And it was found that the electrophilic assistance caused by hydrogen bonding and the nucleophilic assistance for carbon center were stronger for more basic leaving group ($I^-) and more polarizable leaving group(t-BuCl

  • PDF

Nucleophilic Displacement at Sulfur Center (I). Halogen Exchange in Benzenesulfonyl Chlorides (유황의 친핵치환반응 (제1보) 염화 벤젠슬포닐의 할로겐 교환반응)

  • Jae Eui Lee;Ik Choon Lee
    • Journal of the Korean Chemical Society
    • /
    • v.17 no.3
    • /
    • pp.154-162
    • /
    • 1973
  • The rates and activation parameters for the halide $(Cl^{-}, Br^{-}, I^{-})$TeX> exchange reactions of substituted benzenesulfonyl-chloride, $XC_6H_4SO_2Cl$(X:p-MeO, H, p-Cl, p-Br, p-NO$_2l$) in dry acetone at two temperatures have been determined. It was found that the ion-pair of metal halide,$M^{+}X^{-}$, have negligible reactivity compared to free halide ions. It was also found that the nucleophilic order is $Cl^{-}>Br^{-}>I^{-}$for electron-donating substituent, and $Cl^{-}>I^{-}>Br^{-}$ for electron-withdrawing substituents. These results and convex nature of the Hammett plot are interpreted in the light of simple $S_N2$mechanism with the bond breaking becoming important for compounds with the electron withdra-wing substituents.

  • PDF

Operating Performance of hair-tail angling vessel using the LED and metal halide fishing lamp combination (LED와 메탈핼라이드 집어등을 겸용한 갈치채낚기 어선의 조업 성능)

  • An, Heui-Chun;Bae, Bong-Seong;Lee, Kyoung-Hoon;Park, Seong-Wook;Bae, Jae-Hyun
    • Journal of the Korean Society of Fisheries and Ocean Technology
    • /
    • v.48 no.4
    • /
    • pp.337-345
    • /
    • 2012
  • One of representative Korean fisheries, jigging and angling has 5,700 vessels for squid and hairtail. Hairtail angling is the most typical fishery in Jeju and has an enormous impact on regional economy. However, the price hike in oil and labor costs triggered the necessity of developing a high efficient and energy saving fish luring lamp in recent times. For that reason, this study aimed to analyze the fishing performance of the aircooled LED lamp targeting hairtail angling fishery. The experiment was conducted from September through October in 2009-2011 for a 9.77 ton of fishing vessel setting up 100 lamps. The fishing performance was tested compared with 6 vessels using metal halide lamps in the same waters. As the LED lamp's performance goes up, different lamps were used in 2008 for 80W, 2009 for 120W and 2011 for 180W respectively. The catch and CPUE of the experimental vessel have gradually increased respectively taking the $4^{th}$ and $6^{th}$ place in 2009, the $4^{th}$ and $2^{nd}$ place in 2010, the $1^{st}$ and $1^{st}$ place in 2011 among the 7 vessels. In summary, the LED fishing lamp showed higher fishing performance than comparison groups. It saved 33% of oil consumption and cut down on operating expenses and greenhouse gases emission.