• 제목/요약/키워드: halide

검색결과 444건 처리시간 0.023초

특정용매 추출계의 억제효과 (Suppression Effect in Some Solvent Extration System)

  • Chin Taik Rhee;Young Sam Jung
    • Nuclear Engineering and Technology
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    • 제14권3호
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    • pp.110-115
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    • 1982
  • 일련의 용매 추출계에서 다량성분원소들이 존재할 때 미량성분원소에 대한 억제효과의 메카니즘에 대해서 검토해 보았다. 할로게노 금속산계에 대해서는 유기상으로 추출된 화합물의 해리가 억제효과의 주된 원인으로 나타났으며 각 미량 및 다량성분의 상대적분배비, 할로겐착음이온의 안전성 등이 억제효과에 미치는 영향등을 계통적으로 살펴 보았으며 이에 대한 관계식을 유도하였다.

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반전표백 방법에 의한 고효율 은염건판 홀로그램 제작 (Fabrication of High Efficiency Silver Halide Holograms by Reversal Bleaching Process)

  • 백성훈;홍석경;김철중
    • 한국광학회지
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    • 제2권2호
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    • pp.89-95
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    • 1991
  • 은염건판을 반전표백 처리하여 위상형 홀로그래픽 회절격자를 제작하였다. 반전표백에 적합한 화학적 현상액을 사용하고, 표백 후 isopropyl alcohol에 의한 급속탈수 방법으로 회절격자의 효율을 높일 수 있었다. 현상액의 종류와 표백액의 조성 변화 그리고 건조 방법에 따른 회절효율의 변화를 실험적으로 측정하였으며, 각각의 경우에 제작된 회절격자의 특성을 이론적으로 분석하였다. 제작된 회절격자는 최적 조건에서 최고 88%의 효율을 보여, 상용표백 방법으로 제작된 회절격자에 비해 산란이 적으면서도 효율이 높은 결과를 얻었다.

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램프 상태 적응형 점등 방법에 관한 연구 (The Study on Adaptive ignition for HID lamps according to lamp state)

  • 조계현;송명석;박종연
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2004년도 춘계학술대회 논문집
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    • pp.205-209
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    • 2004
  • The metal halide lamps are now widely used in the application and commercial lighting due to their attracting properties such as good color rendering and high efficiency. But they have the serious problem of acoustic resonance for high frequency operation and they need the high voltage to ignite. So, they have not been applied to indoors. Over the past few years, a considerable number of studies have been conducted on the electronic ballast together with hot restarting and resonance phenomenon. But very few attempts have been made with the adaptive ignition method according to the lamp state. In this paper, electronic ballast is proposed for metal halide lamps with an igniter for adaptive ignition. The proposed electronic ballast can generate different ignition voltages according to the arc tube state.

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250 Watt 메탈할라이드 램프용 전자식 Dimming 안정기 개발 (The Development of Dimmable Electronic Ballast for 250W Metal Halide Lamp)

  • 박종연;정광현;신동석;박영길
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2006년도 춘계학술대회 논문집
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    • pp.103-107
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    • 2006
  • In this paper, the dimmable electronic ballast for the 250W metal halide lamp was realized by three stage structure. We developed stable the dimming ballast by using a Micro-controller, and measured the output wattage in the dimming range(illumination) from 100% to about 20%. Under the 35% dimming level, it is possible to cause the redution of lamp's life. The dimming performance can reduce the light system's wattage but can reduce the luminance efficiency (lux/watt).

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유기금속 할라이드 페로브스카이트 태양전지의 상용화를 위한 기술의 진전 (Technological Progress Towards Commercialization of Organometal Halide Perovskite Solar Cells)

  • 변선호
    • 한국전기전자재료학회논문지
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    • 제27권12호
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    • pp.776-791
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    • 2014
  • A marvellous solar cell technology system based on organometal halide perovskites has recently shown an unprecedented progress in power conversion efficiency (PCE); the certified one of 17.9% and unconfirmed of 19.3%, as well as the estimated electricity with a generating cost lower than the half of conventional methods based on fossil fuels. In this report the present status of stability with regards to moisture, ambient temperature, ultraviolet and lead toxicity as well as the key technological developments for the early commercialization are covered. Comprehensive understanding of material science for perovskites is required, together with complete encapsulation technologies beyond those for OLEDs, in order to ensure a 20-year-longer-than lifetime of PSCs (perovskite solar cells) and the stability according to the IEC 61646 damp heat test standard, which will result in the replacement of silicon solar cells with PSCs.

Reduction of Alkyl Halides by Homonuclear Bridging Hydride, (μ-H)[(η$^5-MeCp)$Mn(CO)₂]₂-ppn+

  • 박용광;김영웅
    • Bulletin of the Korean Chemical Society
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    • 제17권3호
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    • pp.269-273
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    • 1996
  • Alkyl halides were reduced to the corresponding alkanes by the homonuclear bridging hydride, (μ-H)[(η5-MeCp)Mn(CO)2]2-PPN+ in THF at the elevated temperatures (40-60 ℃) under the pseudo first order reaction conditions where excess of alkyl halide was employed under nitrogen atmosphere. The reaction is of overall second order; first order with respect to [bridging hydride] and first order with respect to [alkyl halide] with the activation parameters, ΔH≠=28.93 kcal/mol and ΔS≠=17.95 e.u. The kinetic data, the ESR evidence and the reaction with cyclopropyl canbinyl bromide ensure that two possible reaction pathways are operable in this reaction: (1) concerted mechanism, and (2) single electron transfer pathway are in competition leading to the same product, the corresponding alkane.

Temperature Driven Phase Transition of Organic-Inorganic Halide Perovskite Single Crystals

  • Byun, Hye Ryung;Kim, Hyo In;Byun, Su Jeong;Park, Dae Young;Jeong, Mun Seok;Byeon, Clare Chisu
    • Journal of the Korean Physical Society
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    • 제73권11호
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    • pp.1729-1734
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    • 2018
  • Organic-inorganic halide perovskite single crystals undergo phase transition of being cubic, tetragonal, or orthorhombic depending on the temperature. We investigated the $CH_3NH_3PbBr_{3-x}I_x$ single crystals grown by the inverse temperature crystallization method with temperature-dependent UV-Vis absorption and photoluminescence. From the temperature-dependent absorption measurement, the optical band gap is extracted by derivation of absorption spectrum fitting and Tauc plot. In our results, $CH_3NH_3PbBr_{3-x}I_x$ single crystals show that an abrupt change in optical band gap, PL peak position and intensity appears around 120 K - 170 K regions, indicating the phase transition temperature.

Polymer Passivation Effect on Methylammonium Lead Halide Perovskite Photodetectors

  • Kim, Hyojung;Byun, Hye Ryung;Kim, Bora;Kim, Sung Hyuk;Oh, Hye Min;Jeong, Mun Seok
    • Journal of the Korean Physical Society
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    • 제73권11호
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    • pp.1675-1678
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    • 2018
  • Methylammonium lead halide ($MAPbI_3$) perovskites are considered as promising materials owing to their excellent optical and electrical properties. However, perovskite materials suffer from degradation in air, which limits their practical applications. Here, we demonstrate successful passivation of the $MAPbI_3$ photodetectors through monochloro-para-xylylene (Parylene-C) deposition. The time-dependent photocurrent characteristics were systematically investigated, and we achieved significantly improved device performance and stability with Parylene-C passivation. Based on the excitation-power-dependent photoluminescence (PL) data, we confirmed that Parylene-C can reduce the carrier losses in $MAPbI_3$, leading to the enhancement of photocurrent and PL in $MAPbI_3$ photodetectors.