• The Transactions of the Korean Institute of Electrical Engineers B
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• v.55 no.4
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• pp.238-243
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• 2006

This paper presents novel ignition method for automotive 35W metal halide discharge lamp electronic ballast. At this study, the novel method of ignition is developed to reduce costs and size of the ballast. By use of the novel method, the voltage needed in ignition is decreased, which result in use of the lower voltage rating power devices compared with conventional method and product compactness was achieved by deleting a circuit generating negative voltage needed in ignition at an conventional circuit. In terms of luminosity, color rendering, light efficiency(lm/W) and lifespan, the metal halide lamp is superior to, but unlike halogen lamp, it have more complicated transient characteristics to reach its steady state than the conventional halogen lamp. Therefore, in this paper, the electronic ballast was designed such that the metal halide lamp could be optimized for the automotive, by applying a method of microcontroller-based digital control. The results of the proposed system is verified through various experiment results.

• Journal of the Korean Chemical Society
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• v.17 no.6
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• pp.406-410
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• 1973

Kinetic study of halide exchange for dimethylsulfamoyl chloride in dry acetone by using radioisotopic halide ions has been carried out at two temperatures. The result of the order of nucleophilicity, as compared with benzenesulfonyl chloride, shows a similar tendency but reaction rate is slower, more than $10^{-2}$times, than benzenesulfonyl chloride. The activation parameter, ${\Delta}H^{\neq}\;and\;{\Delta}S^{\neq}$ decrease in sequence $Cl^-\;>\;Br^-\;>\;I^-$ in dimethylsulfamoyl chloride but it is the reverse order found for benzenesulfonyl chloride. The results are interpreted with bond-breaking, bond-formation, and electronic requirments, and in the light of HSAB Principle.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2008.10a
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• pp.81-84
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• 2008

1960년대 중반부터 이미 고압 나트륨램프에 사용되어 오던 반투명의 세라믹 재료(Polycrystalline Ceramic Alumina ; PCA)를 기존 메탈핼라이드램프의 석영(Quartz) 발광관에 적용시킨 세라믹 메탈핼라이드(Ceramic Metal Halide ; CMH) 램프는 1995년 처음 소개된 이래 색 제어, 연색성, 광속유지율 등에서 전통적인 석영 메탈핼라이드(Quartz Metal Halide ; QMH)램프보다 우수한 특성을 가지고 있어 저와트급(150W이하)에서 고와트급에 이르기까지 폭넓게 사용되어지고 있으며 현재 국내에서도 이러한 CMH램프의 개발이 진행 중이다. 본 논문에서는 CMH램프의 우수한 특성을 살펴보기 위하여 국외 선진제품에 대한 전기적, 광학적 특성을 살펴보았으며 실험 결과 CMH 램프의 광속유지 율이 기존 QMH 램프보다 우수한 특성을 갖는 것을 확인할 수 있었다.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2002.05a
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• pp.301-304
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• 2002

This paper describes a design and fabrication of an electronic ballast for 70［W］ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active PFC, a half-bridge inverter, a LC resonant circuit and a controller. The design also includes a specially designed time circuit which provides reignition of the lamp. Running frequency of the ballast is set at 45［KHz］to avoid acoustic-resonance and flicker. from the test results, input power factor and efficiency of the ballast were estimated 91［%] and 97.7［%］, respectively.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2002.11a
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• pp.435-439
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• 2002

This paper describes a design and fabrication of an electronic ballast for 70[W] ceramic discharge metal halide lamps. The proposed ballast is composed of a rectifier, an active power factor correction circuit (PFC), a half-bridge inverter, a LC resonant circuit and a microprocessor. The developed ballast also includes a specially designed time circuit which provides reignition of lamps. Running frequency of the ballast is set at 40[kHz] to avoid acoustic-resonance and flickering. From the experimental results, input power factor and efficiency of the ballast are estimated 99.8[%] and 93.1[%)] respectively.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.10
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• pp.1989-1994
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• 2009

This study purposes are improvement of system (lamp & ballast) efficacy with and optical characteristics through the developed ceramic arc tube. The designed electronic ballast is substituted for conventional magnetic ballast. These electric signal and optical, thermal characteristics through the improving efficacy of lighting system compared with conventional magnetic ballast. properties of lamp by driving method is researching in ballast. Particularly, electronic ballasts, which improved against weakness of Magnetic Ballast, are researching and applying to control of ceramic metal-halide lamp. but One major limitation is the acoustic resonance problem in CMH lamps at high-frequency operation. In order to avoid acoustic resonance, driving frequency decided 21[kHz]. Before discharge in this paper. The PSpice simulation result obtained sufficient voltage gain and the ignition voltage obtained over 3[kV] at 75[kHz]. After discharge, driving voltage obtained approximately 90[Vrms] at 21[kHz].

• Journal of the Korean institute of surface engineering
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• v.52 no.6
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• pp.334-341
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• 2019

Organometal halide perovskite materials have attracted much attention in the photovoltaic and light emitting devices due to the compositional flexibility with AMX₃ formula (A is an organic amine cation; M is a metal ion; X is a halogen atom). The addition of homovalent or heterovalent metal cations to the bulk organohalide perovskites has been performed to modify their energy band structure and the relevant optoelectronic properties by ligand-assisted ball milling. Here, we report CH₃NH₃Pb_1-xM_xBr₃ nanocrystals substituted by metallic cations (M is Sn²⁺, In³⁺, Bi³⁺; x = 0, 0.01, 0.02, 0.05, 0.1, 0.2). Photoluminescence and quantum yield was significantly reduced with increasing metallic cations content. These quenching effect could be resulted from the metal cations that behave as a non-radiative recombination center.

• Korean Journal of Materials Research
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• v.31 no.9
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• pp.496-501
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• 2021

Metal halide perovskite nanocrystals, due to their high absorption coefficient, high diffusion length, and photoluminescence quantum yield, have received significant attention in the fields of optoelectronic applications such as highly efficient photovoltaic cells and narrow-line-width light emitting diodes. Their energy band structure can be controlled via chemical exchange of the halide anion or monovalent cations in the perovskite nanocrystals. Recently, it has been demonstrated that chemical exfoliation of the halide perovskite crystal structure can be achieved by addition of organic ligands such as n-octylamine during the synthetic process. In this study, we systematically investigated the quantum confinement effect of methylammonium lead bromide (CH₃NH₃PbBr₃, MAPbBr₃) nanocrystals by precise control of the crystal thickness via chemical exfoliation using n-octylammonium bromide (OABr). We found that the crystalline thickness consistently decreases with increasing amounts of OABr, which has a larger ionic radius than that of CH₃NH₃⁺ ions. In particular, a significant quantum confinement effect is observed when the amounts of OABr are higher than 60 %, which exhibited a blue-shifted PL emission (~ 100 nm) as well as an increase of energy bandgap (~ 1.53 eV).

• Corrosion Science and Technology
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• v.18 no.3
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• pp.110-116
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• 2019

Resistances to pitting corrosion of additive manufactured (AM) Ti-6Al-4V alloys in 0.6 M NaBr and 0.6 M NaCl aqueous solutions were compared using micro-droplet cell techniques. With respect to the pitting corrosion resistance, this study focused on two different types of halide anions in aqueous solutions, i.e. $Br^-$ and $Cl^-$. The differences between $Br^-$ and $Cl^-$ halide anions for breakdown on passive films of AM Ti-6Al-4V alloy were explained using Langmuir adsorption model with their equilibrium adsorption coefficients. The results of the analysis showed that the lower resistance to pitting potential of AM Ti-6Al-4V alloy in $Br^-$ aqueous solution was attributed to the higher equilibrium adsorption coefficient of Br-. In addition, micro-electrochemical test results showed that the pitting corrosion resistance of dark grains in additive manufactured Ti-6Al-4V alloy was lower as compared to that of bright grains due to the larger volume of ${\alpha}^{\prime}$ phase that caused the susceptibility to pit initiation.

• Journal of Sensor Science and Technology
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• v.31 no.6
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• pp.383-388
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• 2022

Currently, photodetectors are being extensively studied and developed for next-generation applications, such as in autonomous vehicles and image sensors. In this regard, all-inorganic metal halide perovskite (CsPbX₃; X = Cl, Br, and I) nanocrystals (NCs) have emerged as promising building blocks for various applications owing to their high absorption coefficients, tunable bandgaps, high defect tolerances, and solution processability. These features, which are typically required for the development of advanced optoelectronics, can be engineered by modifying the chemical compositions and surface chemistry of the NCs. Herein, we briefly review various strategies adopted for the application of CsPbX₃ perovskite NCs in photodetectors and for improving device performance. First, modifications of the chemical compositions of CsPbX₃ NCs to tune their optical bandgaps and improve the charge-transport mechanism are discussed. Second, the application of surface chemistry to improve oxidation resistance and carrier mobility is described. In the future, perovskite NCs with prospective features, such as non-toxicity and high resistance to external stimuli, are expected to be developed for practical applications.