RDX (hexahydro-1,3,5-trinitro-1,3,5-triazine) is the most important explosive contaminant, both in concentration and in frequency, at military shooting ranges in which green technologies such as phytoremediation or constructed wetlands are the best option for mitigation of explosive compounds discharge to the environment. A study was conducted with two identical lab-scale plug flow constructed wetlands planted with Amur silver grass to treat water artificially contaminated with 40 mg/L of toxic explosive compound, RDX. The reactor was inoculated with or without RDX degrading mixed culture to evaluate plant-microorganism interactions in RDX removal, transformation products distribution, and kinetic constants. RDX and its metabolites in water, plant, and sediment were analyzed by HPLC to determine mass balance and kinetic constants. After 30 days of operation, the reactor reached steady-state at which more than 99% of RDX was removed with or without the mixed culture inoculation. The major transformation product was TNX (Trinitroso-RDX) that comprised approximately 50% in the mass balance of both reactors. It was also the major compound in the plant root and shoot system. Acute toxicity analysis of the water samples showed more than 30% of toxicity reduction in the effluent than that of influent containing 40 mg/L of RDX. In the Amur silver grass mesocosm seeded with the mixed culture, the specific RDX removal rate, that is 1st order removal rate normalized to plant fresh weight, was estimated to be 0.84 kg−1 day−1 which is 16.7% higher than that in the planted only mesocosm. Therefore, the results of this study proved that Amur silver grass is an effective plant for RDX removal in constructed wetlands and the efficiency can be increased even more when applied with RDX degrading microbial consortia.
Using artificial rainfall simulator, the soil loss, which is deemed as the most cause of muddy water problem among Non-point source (NPS) pollutant, was studied by the analysis of direct runoff, groundwater discharge, and soil water storage properties concerned with rainfall intensity, slope of area, and land cover. The direct runoff showed increasing tendency in both straw covered and bared soil as slope increases from 5% to 20%. The direct runoff volume from straw covered surface were much lower than bared surface. The infiltration capacity of straw covered surface increased, because the surface sealing by fine material of soil surface didn't occur due to the straw covering. Under the same rainfall intensity and slope condition, 2.4~8.2 times of sediment yield were occurred from bared surface more than straw covered surface. The volume of infiltration increased due to straw cover and the direct runoff flow decreased with decrease of tractive force in surface. To understand the relationship of the rate of direct runoff, groundwater discharge, and soil water storage by the rainfall intensity, slope, and land cover, the statistical test was performed. It shows good relationship between most of factors, except between the rate of groundwater storage and rainfall intensity.
In the present study, an enhanced subsurface prediction algorithm based on a non-parametric geostatistical model and a history matching technique through Gibbs sampler is developed and the iterative prediction improvement procedure is proposed. The developed model is applied to a simple two-dimensional synthetic case where domain is composed of three different hydrogeologic media with $500m{\times}40m$ scale. In the application, it is assumed that there are 4 independent pumping tests performed at different vertical interval and the history curves are acquired through numerical modeling. With two hypothetical borehole information and pumping test data, the proposed prediction model is applied iteratively and continuous improvements of the predictions with reduced uncertainties of the media distribution are observed. From the results and the qualitative/quantitative analysis, it is concluded that the proposed model is good for the subsurface prediction improvements where the history data is available as a supportive information. Once the proposed model be a matured technique, it is believed that the model can be applied to many groundwater, geothermal, gas and oil problems with conventional fluid flow simulators. However, the overall development is still in its preliminary step and further considerations needs to be incorporated to be a viable and practical prediction technique including multi-dimensional verifications, global optimization, etc. which have not been resolved in the present study.
Journal of Korean Tunnelling and Underground Space Association
/
v.21
no.5
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pp.699-715
/
2019
Recently, in urban areas, cavities and ground collapse adjacent to underground structures are frequently reported. Several studies on the cavity generation by structure cracks have been made, however they are focused on the cause of cracks and settlement of the ground. In this paper, soil particle and groundwater discharge through pipe cracks and cavity generation mechanism are investigated. The theoretical analysis of the groundwater, which is the main factor of the drainage of the soil particles, and the particle transport mechanism and flow characteristics were investigated. An experimental model test was carried out to identify the mechanism of cavity generation by underground buried pipe cracks. The soil particle weight of discharge through the cracks, and the movement characteristics of the particles were analyzed using PIV. In this study, it is clearly identified that soil particle movements, cavity generation and ground collapse that occur in the ground are basically caused by the movement of groundwater.
A method is developed for the separation of the major base flow in a river hydrograph combining the numerical techniques and the empirical methods. The linearized Boussinesq equation and the storage function are used to obtain the base flow recession. The shape of base flow curve made by the recharge of the groundwater table aquifer resulting from rainfall in determined by the Singh and Stall's graphical method, and the continuous from for the curve is approximated by the multiple and polynomial regression. this procedure was successfully tested for the separation of base flow and the establishment of hydrograph in a natural watershed. It was found that the direct numerical method applied to the homogeneous linear second order ordinary differential equation system is not suited to obtain the recession curve, and the case that the loss is generated in the partially penetrating stream can not be solved by the method of this study.
Confined aquifer, which is separated with upper clayey or silty materials, is partially distributed at the depths of the sediments in Ddan-sum area on the lower Nakdong river. Measurements of groundwater levels at 13 sites explain that groundwater flow shows seasonally various due to seasonal rainfall and agricultural water use. From 9 long-term monitoring data of groundwater levels at 7 sites, 3 types of groundwater levels time series can be classified using principal component analysis. The first type is seen in the center of Ddan-sum and has a round-shape graph due to a weak response to stream water levels. The second type exists in the outer part of Ddan-sum and shows sharply peak-shape graph due to a rapid and strong response to stream water levels and rainfall. The last type, which is seen in a deep layer, has a periodicity by tital effect. From geochemical analysis at each monitoring sites, [$Ca-HCO_3$] type happens in the center of Ddan-sum far from Nakdong river, and [$Na-HCO_3$] and [$Ca-SO_4(Cl)$] types exist in the outer of Ddan-sum affected by river quality.
Lee Jin-Yong;Yi Myeong-Jae;Choi Mi-Jung;Hwang Hyoun-Tae;Moon Sang-Ho;Won Jong-Ho
Tunnel and Underground Space
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v.16
no.1
s.60
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pp.73-84
/
2006
Effects of railway tunnel excavation on water level at a national groundwater monitoring station in Mokpo were evaluated by field investigation and numerical groundwater modeling. The water level at the station has experienced a decline of about 5 m within 1 year since July 2002. From the field investigation, it was concluded that decrease of precipitation oo increase of grundwater use was not reason for the decline. The Mokpo tunnel of new Honam railway, 70 m apart from the national station, appeared most plausible cause and a period of the tunnel excavation generally well matches up that of the drawdown. To quantify the effects of the tunneling on the water level, a groundwater flow modeling was performed. Especially, a most probable conceptual model was optimized through multiple preliminary simulations of various scenarios because there were few hydrogeological data available for the study area. The optimized model was finally used for the quantification. Based on the field investigation and the numerical simulations, it was concluded that the tunnel excavation was one of the most probable reasons for the substantial water level decline but further hydrogeologic investigation and continuous monitoring are essentially required for the surrounding area.
Fluid flow studies of fractured rocks require three-dimensional modeling of the fracture system. The stochastic discrete fracture models constructed by Monte Carlo simulation technique were applied to the analysis of groundwater flow and mass transport in fractured rock for the assessment of tightness criteria of underground LPG storage cavern. The parameters that most affect the conceptual discrete fracture modeling proved either fracture orientation or size and on the fract'lre flow interpretation proved conductive fracture intensity. The fracture transmissivity played important role in solute transport in fractured rock simulated by particle tracking approach. It was partly recognized that the calibrated stochastic discrete fracture model can be used for the tightness criteria of underground LPG storage cavern.
The objective of this research was to characterize the fate and transport of Cr(VI) contaminated groundwater in the Daejeon industrial area. Five subsidiary monitoring wells were newly installed and two existing wells were utilized for the investigation and the reduction process of Cr(VI) contaminated groundwater of the Daejeon(Mun-pyeong) national groundwater monitoring station. The Cr(VI) concentrations at the shallow aquifer well of the station were in the range of 3.2-4.5 mg/L indicating continuous contamination. However, Cr was not detected at the deep bedrock well and the other monitoring wells except MPH-1 and 3. The Cr(VI) concentrations of MPH-1 and MPH-3 were below the drinking water guideline value (0.05 mg/L). Therefore, the plume of the Cr(VI) contaminated groundwater was predicted to be confined within the narrow boundary around the station. The soluble/exchangeable Cr(VI) concentrations were below the detection limit in all core and slime samples taken from the five newly installed wells. Although the exact source of contamination was not directly detected in the study area, the spatial Cr(VI) distribution in groundwater and characteristics of the core samples indicated that the source and the dispersion range were confined within the 100 m area from the monitoring station. The contamination might be induced from the unlined landfill of industrial wastes which was observed during the installation of an subsidiary monitoring well. For the evaluation of the natural attenuation of Cr(VI), available reduction capacities of Cr(VI) with an initial concentration of 5 mg/L were measured in soil and aquifer materials. Dark-gray clay layer samples have high capacities of Cr(VI) reduction ranging from 58 to 64%, which is obviously related to organic carbon contents of the samples. The analysis of reduction capacities implied that the soil and aquifer materials controlled the dispersion of Cr(VI) contamination in this area. However, some possibilities of dispersion by the preferential flow cannot be excluded due to the limited numbers of monitoring wells. We suggest the removal of Cr(VI) contaminated groundwater by periodical pumping, and the continuous groundwater quality monitoring for evaluation of the Cr(VI) dispersion should be followed in the study area.
In Korea, there have been various methods of estimating groundwater recharge which generally can be subdivided into three types: baseflow separation method by means of groundwater recession curve, water budget analysis based on lumped conceptual model in watershed, and water table fluctuation method (WTF) by using the data from groundwater monitoring wells. However, groundwater recharge rate shows the spatial-temporal variability due to climatic condition, land use and hydrogeological heterogeneity, so these methods have various limits to deal with these characteristics. To overcome these limitations, we present a new method of estimating recharge based on water balance components from the SWAT-MODFLOW which is an integrated surface-ground water model. Groundwater levels in the interest area close to the stream have dynamics similar to stream flow, whereas levels further upslope respond to precipitation with a delay. As these behaviours are related to the physical process of recharge, it is needed to account for the time delay in aquifer recharge once the water exits the soil profile to represent these features. In SWAT, a single linear reservoir storage module with an exponential decay weighting function is used to compute the recharge from soil to aquifer on a given day. However, this module has some limitations expressing recharge variation when the delay time is too long and transient recharge trend does not match to the groundwater table time series, the multi-reservoir storage routing module which represents more realistic time delay through vadose zone is newly suggested in this study. In this module, the parameter related to the delay time should be optimized by checking the correlation between simulated recharge and observed groundwater levels. The final step of this procedure is to compare simulated groundwater table with observed one as well as to compare simulated watershed runoff with observed one. This method is applied to Mihocheon watershed in Korea for the purpose of testing the procedure of proper estimation of spatio-temporal groundwater recharge distribution. As the newly suggested method of estimating recharge has the advantages of effectiveness of watershed model as well as the accuracy of WTF method, the estimated daily recharge rate would be an advanced quantity reflecting the heterogeneity of hydrogeology, climatic condition, land use as well as physical behaviour of water in soil layers and aquifers.
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