• Bulletin of the Korean Chemical Society
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• 제29권6호
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• pp.1167-1172
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• 2008

We investigated the glass transition temperatures ($T_g$) of dendrons consisting of conformationally mobile aliphatic polyether dendritic cores plus glassy peripheral polystyrenes (PSs), and linear PSs in the molecular weight range of 1000-8500 g/mol. We compared their $T_g$ behavior depending on their polymeric architecture. The linear PSs show a typical growth of $T_g$ up to 92.5 ${^{\circ}C}$ as the molecular weight increases to 8300 g/mol, while the dendrons display nearly constant $T_g$ values of 58-61 ${^{\circ}C}$, despite the increase of molecular weight with each generation. The striking contrast of Tg behavior would be mainly attributed to the fact that the dendrons keep the ratio of $N_e$/M ($N_e$: number of peripheral chain ends, M: molecular weight) over all the generations. Additionally, for the influence of dendritic spacers on glass transition temperature we prepared dimeric PSs with different linkage groups such as aliphatic ether, ester and amide bonds. We found that the dimer with the ether spacer exhibited the lowest glass transition at 55.4 ${^{\circ}C}$, while the amide linked dimer showed the highest glass transition temperature at 74.2 ${^{\circ}C}$. This indicates that the peripheral PS chains are effectively decoupled by the conformationally flexible ether spacer. The results from this study demonstrated that polymeric architecture and dendritic core structures play a crucial role in the determination of glass transition behavior, providing a strategy for the systematic engineering of polymer chain mobility.

• 열처리공학회지
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• 제14권6호
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• pp.345-349
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• 2001

This study has investigated the effect of thermal stability and mechanical property of $Fe_{80-X}P_{10}C_6B_4M_X$(X=2, 4, 6, M=transition metal) amorphous alloys fabricated by the melt-spun process. The glass transition temperature($T_g$), crystallization temperature($T_x$) and hardness increase with decreasing electron concentration (e/a) from about 7.38 to 7.18. The decrease of e/a implies the increase in the attractive bonding state between the M elements and other constituent element. The decrease in a/e leads to the enhancement of the attractive bonding state among the constituent elements which is favorable for the increase in $T_g$, $T_x$ and hardness.

• 한국초전도ㆍ저온공학회논문지
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• 제15권2호
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• pp.16-19
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• 2013

The magneto-resistivity and electric field-current density (E-J) curves were investigated up to a magnetic field 9 T in the optimally doped $BaFe_{1.8}Co_{0.2}As_2$ single crystal with a superconducting temperature ($T_c$) of 24.6 K. The E-J Scaling behaviors below and above vortex glass transition temperature ($T_g$) were found, confirming the existence of the vortex glass phase transition. The critical exponents for the diverging spatial and time correlations at $T_g$, were obtained as v = $1.1{\pm}0.1$ and z = $4.5{\pm}0.3$, respectively. The obtained critical exponents are in good agreement with the predicted values of v ~ 1 - 2 and z > 4 within the 3D vortex glass theory.

• 폴리머
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• 제26권3호
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• pp.410-414
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• 2002

중심 금속을 안정화시킬 수 있는 ferrocene-based diimine 리간드를 가지고 낮은 산소 친화성을 가진 후전이금속인 Pd 촉매를 합성하여, 극성 단량체인 메틸메타크릴레이트 (MMA)의 중합에 사용하였다. 중합계 내의 impurity scavenger로 triisobutylaluminium (TIBA)를 사용하였을 때에, 중합온도와 [TIBA]/[Pd] 몰비가 생성 중합체(PMMA)의 수율 및 유리전이온도 ($T_g$)에 미치는 영향을 조사하였다. PMMA의 수율은 40~$50^{\circ}C$의 중합온도 및 2000~3000의 [TIBA]/[Pd] 몰비에서 가장 높았다. PMMA의 $T_g$는 중합온도에는 크게 영향을 받지 않으나, [TIBA]/[Pd] 몰비에 의존한다는 것을 관찰할 수 있었다. PMMA의 $T_g$의 변화를 PMMA의 미세구조와 연관시켜 조사한 결과, PMMA의 $T_g$ 이소탁틱도와 직선적 관계를 가짐을 알았다.

• Preventive Nutrition and Food Science
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• 제15권4호
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• pp.356-359
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• 2010

Glass transition phenomena in nine Korean pure honeys (moisture content 18.3~20.1%) and honey-water mixtures by different water contents (0, 2, 5, and 10% w/w) were investigated with modulated different scanning calorimetry (MDSC). The total, reversing, and non-reversing heat flows were quantified during heating using MDSC. Glass transition was observed from reversing heat flow separated from the total heat flow. The glass transition temperatures ($T_g$) of pure honeys, which are in the range of $-42.7^{\circ}C$ to $-50.0^{\circ}C$, varied a lot with low determination coefficient ($R^2$=0.63), whereas those of honey-water mixtures decreased with a decrease in honey content. The $T_g$ values were also more significantly different among honey-water mixtures when compared to pure honeys, indicating that in the honey-water mixture system the $T_g$ values appear to be greatly dependent on moisture content. The measured heat capacity change (${\Delta}C_p$) was not influenced by moisture content.

• 전기학회논문지
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• 제65권9호
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• pp.1504-1510
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• 2016

The aim of this study is to improve properties both glass transition temperature($T_g$) and coefficient of thermal expansion(CTE) using epoxy/micro-nano alumina composites with adding glycerol diglycidyl ether (GDE:1,2,3,5g). This paper deals with the effects of GDE addition for epoxy/micro alumina contents (40, 50, 60wt%)+surface modified nano alumina(1_phr) composites. 20 kinds specimen were prepared with containing micro, nano alumina and GDE as a micro composites(10, 20, 30, 40, 50, 60, 70wt%) or a nano/micro alumina composites(1phr/40, 50, 60wt%). Average particle size of nano and micro alumina used were 30nm and $1{\sim}2{\mu}m$, respectively. The micro alumina used were alpha phase with Heterogeneous and nano alumina were gamma phase particles of spherical shape. The glass transition temperature and coefficients of thermal expansion was evaluated by DSC and TMA. The glass transition temperature decreased and coefficients of thermal expansion become smaller with filled contents of epoxy/micro alumina composites. On the other hand, $T_g$ and CTE as GDE addition variation(1,2,3,5g) of epoxy/micro-nano alumina composites decreased and increased respectively.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.201-201
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• 2006

In this study the glass transition temperature in thin polymer films has been studied. Ellipsometry has been used to measure $T_{g}$ of thin film as a function of film thickness. Empirical equation has been proposed to fit the measured $T_{g}$ pattern with thickness. Also, a continuous multilayer model was proposed and derived to describe the effect of surface on the observed $T_{g}$ reduction in thin films, and the depth-dependent $T_{g}$ profile was obtained. These results showed that $T_{g}$ at the top surface was much lower than the bulk $T_{g}$ and gradually approached the bulk $T_{g}$ with increasing distance from the edge of the film. The model and equation were modified to apply for the polymer coated on the strongly favorable substrate and the freely standing film.

• 한국식품과학회지
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• 제36권2호
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• pp.288-293
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• 2004

전분, 단백질, 지방, 당류 등의 복잡한 다성분계로 구성된 전분질식품의 노화를 억제하기 위한 기초자료를 얻기 위해 전체 수분함량 50%의 동일한 조건에서 밀전분과 sucrose와 글루텐을 모델계로 하여 전분의 유리전이와 호화 및 노화현상을 연구하였다. Sucrose나 글루텐은 밀전분에 대한 첨가비율이 증가함에 따라 밀전분의 유리전이온도($T_G$)를 감소시켰으며 sucrose는 밀전분의 호화온도($T_G$)와 호화엔탈피값(${\Delta}H_G$)을 증가시켰다. 글루텐을 포함한 시료들은 글루텐을 포함하지 않은 시료들보다 낮은 $T_G$와 ${\triangle}H_G$값을 나타내었다. 저장온도 $4^{\circ}C$에서 4주간 저장한 밀전분겔 시료들 중 sucrose와 글루텐을 포함하지 않는 밀전분겔은 4주의 저장기간 동안 재결정이 계속된 반면 밀전분-sucrose계와 밀전분-sucrose-글루텐계는 1주의 저장기간에 거의 재결정이 완료되었다. 저장온도 $32^{\circ}C$에서 모든 전분겔 시료들은 저장기간 1주의 저장기간에서 재결정 발생속도가 컸으며 4주의 저장기간까지 느린 속도이지만 계속적으로 재결정이 발생하였으며 밀전분에 대해 sucrose와 글루텐의 첨가비가 가장 높았던 1 :0.5 :0.12의 밀전분-sucrose-글루텐계의 노화된 정도가 가장 적었다. DSC로 측정한 노화의 결과들은 폴리머재결정원리에서의 결정의 핵형성율과 핵성장율이 노화 endotherm의 peak 폭(${\delta}T$)과 peak온도($T_R$)로 전환된다는 실험적 결과로부터 노화에 대한 해석이 가능하였다.

• Macromolecular Research
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• 제10권1호
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• pp.13-17
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• 2002

An artificial neural network (ANN) was used to study the relationship between the glass transition temperature (T$_{g}$) and the structure of homopolymers. The input is very important for the ANN. In this paper, six kinds of input vectors were designed for the ANN. Of the six approaches, the best one gave the is T$_{g}$ of 251 polymers with a standard deviation of 8 K and a maximum error of 29 K. The trained ANN also predicted the T$_{g}$ of 20 polymers which are not included in the 251 polymers with a standard deviation of 7 K and a maximum error of 21 K. 21 K.

• 한국주조공학회지
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• 제29권4호
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• pp.181-186
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• 2009

The interrelationship between new parameter ${\sigma}$ and maximum diameter $D_{max}$ is elaborated and discussed in comparison with four other glass forming ability (GFA) parameters, i.e. (1) super-cooled liquid region ${\Delta}T_x (=T_x - T_g)$, (2) reduced glass transition temperature $T_{rg} (=T_g/T_l)$, (3) K parameter $K (=[T_x-T_g]/[T_l -T_x])$, and (4) gamma parameter ${\gamma}(=[T_x]/[T_l+T_g])$ in Ca-based bulk metallic glass (BMG) systems. The ${\sigma}$ parameter, defined as ${\Delta}T^*{\times}P^'$, has a far better correlation with $D_{max}$ than the GFA parameters suggested so far, clearly indicating that the liquid phase stability and atomic size mismatch dominantly affect the GFA of Ca-based BMGs. Thus, it can be understood that the GFA of BMGs can be properly described by considering structural aspects for glass formation as well as thermodynamic and kinetic aspects for glass formation.