• Title/Summary/Keyword: glass stability

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Mg-Y-Cu Bulk Metallic Glass Obtained by Mechanical Alloying and Powder Consolidation

  • Lee, P.Y.;Hsu, C.F.;Wang, C.C.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.950-951
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    • 2006
  • [ $Mg_{55}Y_{15}Cu_{30}$ ] metallic glass powders were prepared by the mechanical alloying of pure Mg, Y, and Cu after 10 h of milling. The thermal stability of these $Mg_{55}Y_{15}Cu_{30}$ amorphous powders was investigated using the differential scanning calorimeter (DSC). $T_g$, $T_x$, and ${\Delta}T_x$ are 442 K, 478 K, and 36 K, respectively. The as-milled $Mg_{55}Y_{15}Cu_{30}$ powders were then consolidated by vacuum hot pressing into disk compacts with a diameter and thickness of 10 mm and 1 mm, respectively. This yielded bulk $Mg_{55}Y_{15}Cu_{30}$ metallic glass with nanocrystalline precipitates homogeneously embedded in a highly dense glassy matrix. The pressure applied during consolidation can enhance thermal stability and prolong the existence of amorphous phase within $Mg_{55}Y_{15}Cu_{30}$ powders.

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P2O5-ZnO-SiO2-R2O Glass Frit Materials for Hermetic Sealing of Dye-Sensitized Solar Cells

  • Lee, Hansol;Lee, Choon Yeob;Hwang, Jae Kwun;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.54 no.5
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    • pp.400-405
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    • 2017
  • $P_2O_5-ZnO-SiO_2-R_2O$ glasses were synthesized as a sealing material for large scale dye-sensitized solar cells (DSSC). Compositional effects of $P_2O_5$ and ZnO were examined by varying their contents. Their viscosity and glass stability at sintering temperatures of less than $550^{\circ}C$ were examined by flow button test. Glass transition temperature and structural change upon compositional change were investigated. Chemical stability against electrolyte was also examined by immersing the glasses in the electrolyte for 72 h at $85^{\circ}C$.

Study on Vacuum Packaging of Field Emission Display (Field Emission Display의 고진공 실장에 관한 연구)

  • Lee, Duck-Jung;Ju, Byeong-Kwon;Jang, Jin;Oh, Myong-Hwan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.103-106
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    • 1999
  • In this paper, we suggest the FED packaging technology that have 4mm thickness, using sodalime glass-to-sodalime glass electrostatic bonding. It based on conventional silicon-glass bonding. The silicon film was deposited an around the exhausting hole on FED backside panel. And then, the silicon film of panel was successfully bonded with capping(bare) glass in vacuum environment and the FED panel was vacuum-sealed. In this method, we could achieve more 153 times increased conductance and 200 times increased vacuum efficiency than conventional tube packaging method. The vacuum level in panel, by SRG test, was maintained about low 10$_{-4}$ Torr during above two months And, the light emission was observed to 0.7-inch tubeless packaged FED. Then anode current was 34 $\mu$ A. Emission stability was constantly measured for 10 days.

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Stability Design of a Laser Cutter for the Strengthened Glass (디스플레이 기기용 강화유리 절단기의 안정화 설계)

  • Ro, Seung Hoon;Park, Yu Ra;Ryu, Young Chan;Kim, Young Jo;Lee, Tae Hoon
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.19-25
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    • 2015
  • Strengthened glass is widely used in the display industry for the smart phone and the tablet PC's, the market of which shows steady growth. The strengthened glass is prone to the fracture due to the machined surface defects such as crack and notch. The surface defects are caused mostly by the vibrations of the laser cutter. In this study, the vibrations of the laser cutter were investigated through the frequency response experiment and the computer simulation. The main reasons of the structural vibrations were analyzed, and further the design alterations were deduced and applied to the machine to check the effects of those alterations and to eventually improve the structural stability. The result shows that simple design modifications without major structural change can substantially suppress the vibrations, and improve the quality of the machined surface.

Effect of Organic Processing Parameters in Non-aqueous Tape-casting on Dispersion Stability of Barium Titanate-Borosilicate Glass Based Suspensions (비수계 테잎성형공정의 유기공정변수의 변화에 따른 티탄산바륨-붕규산염유리계 현탁액의 분산안정성)

  • Yeo, Jeong-Gu;Choi, Sung-Churl
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.725-731
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    • 2003
  • The effect of organic processing parameters on the dispersion stability of the BaTiO$_3$-based dielectric particles and borosilicate glass particulate suspensions was investigated in a system where organic solvents, dispersant, binder and modifier were used as processing additives in a low temperature cofired ceramic fabrication processes. Two- and three-component organic solvents were used to disperse ceramic particles and it was found the better stability in the particulate suspension prepared in a bi-solvent, which was consists of toluene and ethanol in a non-azeotropic composition. The addition amount of organic additives had a great impact on dispersion in the present investigation. The flow curves of the suspensions prepared with binder and modifier were fitted according to the power-law equation, which indicates that the internal structure of the suspension could be disturbed under the applied shear stress. Finally, the LTCC green tapes were successfully tape-cast based upon the optimum formulation of LTCC suspension and its microstructure was compared with that of the hard-agglomerates.

A Study on Properties of the Glass Fiber Reinforced PPS Composites for Automotive Headlight Source Module (자동차 전조등 광원 모듈용 유리섬유강화 PPS 복합재료 특성 연구)

  • Heo, Kwang-Yeol;Park, Sung-Min;Lee, Eun-Soo;Kim, Myung-Soon;Sim, Ji-Hyun;Bae, Jin-Seok
    • Composites Research
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    • v.29 no.5
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    • pp.293-298
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    • 2016
  • In this paper, Glass Fiber Reinforced Thermoplastic (GFRTP) for automotive headlight source module was fabricated by compounding and injection molding using PPS (Poly Phenylene Sulfide) resin with glass fiber which has three cross section (round type, cocoon type, flat type). Tensile, flexural, impact properties were investigated on effect of cross section, glass fiber contents. And it was observed flatness, dimensional stability, fluidity depending on glass fiber cross section. As a result, flat glass fiber reinforced thermoplastic's mechanical properties were most excellent. Also, dimensional stability and flatness showed better results when using flat glass fiber.

Characteristics of Heavy Metal Oxide Glasses in BaO-GeO2-La2O3-ZnO-Sb2O3 System for Infrared Lens (적외선 렌즈용 BaO-GeO2-La2O3-ZnO-Sb2O3계 중금속 산화물 유리의 특성)

  • Sang-Jin Park;Bok-Hyun Oh;Sang-Jin Lee
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.414-421
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    • 2023
  • Infrared radiation (IR) refers to the region of the electromagnetic radiation spectrum where wavelengths range from about 700 nm to 1 mm. Any object with a temperature above absolute zero (0 K) radiates in the infrared region, and a material that transmits radiant energy in the range of 0.74 to 1.4 um is referred to as a near-infrared optical material. Germanate-based glass is attracting attention as a glass material for infrared optical lenses because of its simple manufacturing process. With the recent development of the glass molding press (GMP) process, thermal imaging cameras using oxide-based infrared lenses can be easily mass-produced, expanding their uses. To improve the mechanical and optical properties of commercial materials consisting of ternary systems, germanate-based heavy metal oxide glasses were prepared using a melt-cooling method. The fabricated samples were evaluated for thermal, structural, and optical properties using DSC, XRD, and XRF, respectively. To derive a composition with high glass stability for lens applications, ZnO and Sb2O3 were substituted at 0, 1, 2, 3, and 4 mol%. The glass with 1 mol% added Sb2O3 was confirmed to have the optimal conditions, with an optical transmittance of 80 % or more, a glass transition temperature of 660 ℃, a refractive index of 1.810, and a Vickers hardness of 558. The possibility of its application as an alternative infrared lens material to existing commercial materials capable of GMP processing was confirmed.

A STUDY ON THE STAINING OF GLASS IONOMER CEMENT (Glass Ionomer Cement의 착색경향에 관한 연구)

  • Lee, Dong-Hoon;Kim, Shin
    • Journal of the korean academy of Pediatric Dentistry
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    • v.24 no.1
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    • pp.58-64
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    • 1997
  • For the purpose of quantifying the staining rendency of light-cured glass ionomer cements and chemical-cured glass ionomer cements, Glass Ionomer specimens were stained with methylene blue and analyzed quantitatively with spectrophotometry. The data was processed and the result was as follows : 1. Chemical-cured glass ionomer cement showed higher color stability than light-cured glass ionomer cement with significance.(P<0.001) 2. In light-cured glass ionomer cement groups, Vitremer showed higher dye concentration of methylene blue than Fuji II LC. 3. In chemical-cured glass ionomer cement groups, Fuji II showed higher dye concentration of methylene blue than Ketac-fil.

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The stability of $WO_3$ thin film prepared by thermal oxidation method (열산화 방법으로 제작한 $WO_3$박막의 안정성 연구)

  • 조형호;임원택;안일신;이창효
    • Journal of the Korean Vacuum Society
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    • v.8 no.2
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    • pp.136-140
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    • 1999
  • The stability and response time of $WO_3$ thin films for EC device are critical problems being solved. Those are affected by the species of electrolyte, preparation conditions and fabricating methods of specimen. In this paper, we compared the stabilities of three kinds of tungsten oxide film in electrolyte. Each of three films was prepared by different manufacturing conditions, that is, one is a thermal oxidation film of tungsten metal deposited on pure glass substrate, another is a $WO_3$ film made on ITO glass directly, the other is a thermally oxidized film on tungsten plate. It was observed that thermally oxidized $WO_3$ films has a remarkable stability (the lifetime was above $10^6$ cycle). From these results, we found that the stability was closely related to the stoichiometric bonding between tungsten and oxygen atoms in addition to crystallinity and density of film.

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Proton Conductivity of Niobium Phosphate Glass Thin Films

  • Kim, Dae Ho;Park, Sung Bum;Park, Yong-il
    • Korean Journal of Materials Research
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    • v.28 no.5
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    • pp.308-314
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    • 2018
  • Among the fuel cell electrolyte candidates in the intermediate temperature range, glass materials show stable physical properties and are also expected to have higher ion conductivity than crystalline materials. In particular, phosphate glass has a high mobility of protons since such a structure maintains a hydrogen bond network that leads to high proton conductivity. Recently, defects like volatilization of phosphorus and destruction of the bonding structure have remarkably improved with introduction of cations, such as Zr4+ and Nb5+, into phosphate. In particular, niobium has proton conductivity on the surface because of higher surface acidity. It can also retain phosphorus content during heat treatment and improve chemical stability by bonding with phosphorus. In this study, we fabricate niobium phosphate glass thin films through sol-gel processing, and we report the chemical stability and electrical properties. The existence of the hydroxyl group in the phosphate is confirmed and found to be preserved at the intermediate temperature region of $150-450^{\circ}C$.