• 제목/요약/키워드: glass stability

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Thermal Stability of Glass Powder and Rubber-Filled Phenolic Resins and Dynamic Mechanical Properties of Glass Braid/Phenolic Composites (유리분말 및 고무 충진 페놀수지의 열안정성 및 Glass Braid/페놀수지 복합재료의 동역학적 열특성)

  • Yoon, Sung Bong;Cho, Donghwan;Lee, Geon-Woong
    • Journal of Adhesion and Interface
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    • v.8 no.4
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    • pp.14-22
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    • 2007
  • In the present study, the effect of milled glass powder and liquid-type nitrile rubber (NBR) on the thermal stability of phenolic resin and the dynamic mechanical properties of glass braid/phenolic composites has been investigated by means of thermogravimetric analysis and dynamical mechanical analysis. It was found that both milled glass power and NBR filled in the waterborne phenolic resin significantly influenced the thermal stability of phenolic resins and the storage modulus and tan delta of the composites. The presence of glass powder increased the thermal stability of the phenolic resin, whereas the presence of NBR resulted in the weight loss in the specific temperature range. The thermal stability of the phenolic resins without and with the fillers was dependent not only on the cure temperature but also on the cure time. The variation of the storage modulus and tan ${\delta}$ of strip-type glass braid/phenolic composites was also influenced with the introduction of glass powder and NBR to the phenolic matrix as well as by the cure conditions given.

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Evaluations of Sb20Se80-xGex (x = 10, 15, 20, and 25) Glass Stability from Thermal, Structural and Optical Properties for IR Lens Application

  • Jung, Gun-Hong;Kong, Heon;Yeo, Jong-Bin;Lee, Hyun-Yong
    • Journal of the Korean Ceramic Society
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    • v.54 no.6
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    • pp.484-491
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    • 2017
  • Chalcogenide glasses have been investigated in their thermodynamic, structural, and optical properties for application in various opto-electronic devices. In this study, the $Sb_{20}Se_{80-x}Ge_x$ with x = 10, 15, 20, and 25 were selected to investigate the glass stability according to germanium ratios. The thermal, structural, and optical properties of these glasses were measured by differential scanning calorimetry (DSC), X-ray diffraction (XRD), and UV-Vis-IR Spectrophotometry, respectively. The DSC results revealed that $Ge_{20}Sb_{20}Se_{60}$ composition showing the best glass stability theoretically results due to a lower glass transition activation energy of 230 kJ/mol and higher crystallization activation energy of 260 kJ/mol. The structural and optical analyses of annealed thin films were carried out. The XRD analysis reveals obvious results associated with glass stabilities. The values of slope U, derived from optical analysis, offered information on the atomic and electronic configuration in Urbach tails, associated with the glass stability.

Glass Forming Stability in Chalcogenide-based GeSbSe Materials for IR-Lens (적외선 렌즈용 Ge-Sb-Se계 칼코게나이드의 유리안정성 평가)

  • Jung, Gun-Hong;Kong, Heon;Yeo, Jong-Bin;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.4
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    • pp.204-209
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    • 2017
  • Thermal and structural stability in the glass transition region of chalcogenide glasses has been investigated in terms of thermodynamics for application to various optoelectronic devices. In this study, the compositions of $Ge_xSb_{20}Se_{80-x}$ (x = 10, 15, 20, 25, and 30) were selected to investigate the glass stability according to germanium ratios. The chalcogenide bulks were fabricated by using a traditional melt-quenching method. Thin films were deposited by a thermal evaporation system, maintaining the deposition ratio of $3{\sim}5{\AA}$ in order to have uniformity. The thermal and structural properties were measured by a differential scanning calorimeter (DSC) and X-ray diffraction (XRD). The DSC analysis provided thermal parameters and theoretical glass region stabilities. The XRD analysis supported the theoretical stabilities because of where the crystallization peak data occurred.

Combined effect of glass and carbon fiber in asphalt concrete mix using computing techniques

  • Upadhya, Ankita;Thakur, M.S.;Sharma, Nitisha;Almohammed, Fadi H.;Sihag, Parveen
    • Advances in Computational Design
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    • v.7 no.3
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    • pp.253-279
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    • 2022
  • This study investigated and predicted the Marshall stability of glass-fiber asphalt mix, carbon-fiber asphalt mix and glass-carbon-fiber asphalt (hybrid) mix by using machine learning techniques such as Artificial Neural Network (ANN), Support Vector Machine (SVM) and Random Forest(RF), The data was obtained from the experiments and the research articles. Assessment of results indicated that performance of the Artificial Neural Network (ANN) based model outperformed applied models in training and testing datasets with values of indices as; coefficient of correlation (CC) 0.8492 and 0.8234, mean absolute error (MAE) 2.0999 and 2.5408, root mean squared error (RMSE) 2.8541 and 3.3165, relative absolute error (RAE) 48.16% and 54.05%, relative squared error (RRSE) 53.14% and 57.39%, Willmott's index (WI) 0.7490 and 0.7011, Scattering index (SI) 0.4134 and 0.3702 and BIAS 0.3020 and 0.4300 for both training and testing stages respectively. The Taylor diagram also confirms that the ANN-based model outperforms the other models. Results of sensitivity analysis show that Carbon fiber has a major influence in predicting the Marshall stability. However, the carbon fiber (CF) followed by glass-carbon fiber (50GF:50CF) and the optimal combination CF + (50GF:50CF) are found to be most sensitive in predicting the Marshall stability of fibrous asphalt concrete.

V2O5-P2O5-ZnO-Sb2O3 Glass Frit Materials with BaO and Al2O3 for Large-sized Dye-sensitized Solar Cell Sealing

  • Lee, Han Sol;Cho, Jae Kwon;Hwang, Jae Kwon;Chung, Woon Jin
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.114-118
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    • 2015
  • $V_2O_5-P_2O_5-ZnO-Sb_2O_3$ glasses modified with BaO and $Al_2O_3$ are synthesized as a sealing material for large-scale dye-sensitized solar cells (DSSCs). A compositional study is performed in order to determine the glass that can be sintered below $500^{\circ}C$ with a high chemical stability against the electrolyte. The flow size of the glasses after the heat treatment and the glass stability are increased with the addition of $Al_2O_3$ and BaO, while the glass transition temperature is decreased. After the reaction with the electrolyte at $60^{\circ}C$ for 72 h, the addition of 5 mol% of BaO and 2 mol% of $Al_2O_3$ considerably enhances the chemical stability of the glass. X-ray diffraction (XRD) and scanning electron microscope (SEM) are used to examine the reaction between the electrolyte and glasses. The structural contribution of the additives is also investigated and discussed.

The Effect of Glass Fiber and Coupling Agents in the Blends of Silicone Rubber and Liquid Crystalline Polymers

  • Das T.;Banthia A.K.;Adhikari B.;Jeong Hye-Won;Ha Chang-Sik;Alam S.
    • Macromolecular Research
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    • v.14 no.3
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    • pp.261-266
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    • 2006
  • Blends of silicone rubber (VMQ) and liquid crystalline polymer (LCP) were prepared using a melt blending technique in the presence and absence of glass fiber and coupling agents. The effect of glass fiber and coupling agents on the thermal, dynamic mechanical, morphological pro-perties and cure characteristics of VMQ/LCP blends were studied. The vinyl silane coupling agent showed a significant effect on the above mentioned properties of VMQ/LCP blends by reacting at the interface between VMQ and LCP. The viscosity of the VMQ/LCP blends decreased with the addition of a coupling agent. A substantial improvement in storage modulus of VMQ/LCP blends was observed in the presence of glass fiber and coupling agents. However, as a coupling agent vinyl silane proved to be better than amine for the VMQ/LCP-glass-containing blends. The thermal stability of the pure silicone rubber was higher than those of the blends. This high thermal stability of silicone rubber was attributed to the Si-O-Si bonds. However, the thermal stability of the blends decreased further in the presence of a coupling agent, possibly due to a decrease in blend crystallinity.

Color stability of laboratory glass-fiber-reinforced plastics for esthetic orthodontic wires

  • Inami, Toshihiro;Tanimoto, Yasuhiro;Minami, Naomi;Yamaguchi, Masaru;Kasai, Kazutaka
    • The korean journal of orthodontics
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    • v.45 no.3
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    • pp.130-135
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    • 2015
  • Objective: In our previous study, glass-fiber-reinforced plastics (GFRPs) made from polycarbonate and glass fibers were prepared for esthetic orthodontic wires using pultrusion. These laboratory GFRP wires are more transparent than the commercially available nickel-titanium wire; however, an investigation of the color stability of GFRP during orthodontic treatment is needed. Accordingly, in the present study, the color stability of GFRP was assessed using colorimetry. Methods: Preparation of GFRP esthetic round wires (diameter: 0.45 mm [0.018 inch]) using pultrusion was described previously. Here, to investigate how the diameter of fiber reinforcement affects color stability, GFRPs were prepared by incorporating either $13-{\mu}m$ (GFRP-13) or $7-{\mu}m$ glass (GFRP-7) fibers. The color changes of GFRPs after 24 h, and following 1, 2, and 4 weeks of coffee immersion at $37^{\circ}C$, were measured by colorimetry. We evaluated the color stability of GFRPs by two evaluating units: the color difference (${\Delta}E^*$) and National Bureau of Standards (NBS). Results: After immersion, both GFRPs showed almost no visible color change. According to the colorimetry measurements, the ${\Delta}E^*$ values of GFRP-13 and GFRP-7 were 0.73-1.16, and 0.62-1.10, respectively. In accordance with NBS units, both GFRPs showed "slight" color changes. As a result, there were no significant differences in the ${\Delta}E^*$ values or NBS units for GFRP-13 or GFRP-7. Moreover, for both GFRPs, no significant differences were observed in any of the immersion periods. Conclusions: Our findings suggest that the GFRPs will maintain high color stability during orthodontic treatment, and are an attractive prospect as esthetic orthodontic wires.

Thermochemical Stability and Mechanical Properties of Ceramic-Filler Added BaO-ZnO-$B_2O_3$ Based Glass for Application to Barrier Rib in Plasma Display Panels

  • Kim, Sang-Gon;Shin, Hyun-Ho;Park, Jong-Sung;Hong, Kug-Sun;Kim, Hyung-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.220-222
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    • 2004
  • Feasibility of BaO-ZnO-$B_2O_3$ (BZB) based glass system in the light of dielectric and thermal expansion properties are reported in the literature. Effects of addition of various types of ceramic fillers to the BZB-based glass on the thermochemical stability and mechanical properties were investigated in the present work. The studied filler-glass system demonstrated a capability to host various types of ceramic fillers to form thermochemically stable microcomposites at the processing temperature suitable for PDP systems. At the same time, mechanical strength of the filler-glass composites was much improved as compared to the glass itself These observations brighten the feasibility of the Pb-free BZB-based glass system as a host to employ various types of crystalline ceramic fillers so that it can be applied to barrier rib material in plasma display panels.

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A Study on Glass/Mo/ZnO/Glass Thin-film-heaters for Water Heating (수중 발열을 위한 Glass/Mo/ZnO/Glass 구조의 박막형 발열체 연구)

  • Kim, Jiwoo;Choi, Dooho
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.43-47
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    • 2022
  • In this study, we demonstrated an eco-friendly thin-metallic-film-based heater which can be operated in water. Based on the materials stability, Mo was selected as the heating element to secure long-term stability. Using a magnetron sputtering, 40 nm-thick Mo layers were deposited onto a glass substrate, followed by the deposition of 60-nm-thick ZnO layer to prevent oxidation during the heater fabrication process. Then, PVB (Polyvinyl Butyral) was applied on top of ZnO layer and an additional glass substrate was placed, which were heated at 150℃ for 2 hr. The PVB was cured with strong adhesion by the processing condition. We operated the Glass/Mo/ZnO/Glass heater in water, and it was shown that the water temperature reached 50℃ within 2 minutes, with a minimal resistance change of the heater. Finally, the heaters exhibit a semi-transparency, and this aesthetic advantage is expected to contribute to the added value of the heater.