• Bulletin of the Korean Chemical Society
• /
• v.16 no.12
• /
• pp.1193-1203
• /
• 1995

In this work, we focused on the setup of the tools for the analysis of the final rotational state distribution of photofragments in vibrational predissociations of triatomic van der Waals molecules A-B2. We found that reflection principle used for the direct photodissociation processes can also be applied to find out the final rotational state distributions for indirect photodissociation processes. The quantity which represents the strength of rovibrational coupling between the quasi-bound state and the final state is reflected into the mirror of the classical angular momentum function, instead of the initial state before light absorption used in the reflection principle of direct processes. The sign change in the first derivative of the interaction potential with respect to the bond distance of B2 is found to be the source of the binodal structures in the final rotational distributions of photofragments in the model system studied in this work. In MQDT analysis, short range eigenchannel basis functions were found to be localized in angle, in the previous work [Lee, C.W. Bull. Korean Chem. Soc. 1995, 16, 957.] and may be called angle functions. Angle functions enjoy simple geometrical structures which have simple functional relations with the final state distributions of photofragments. Two processes take place along the angle functions which resemble the quasi-bound state and dominate over other processes. Two such angle functions are found to be not only localized angularly but also localized either one of ends of B2 in motions along the bond of B2. These dominating photodissociation processes, however, cancel each other. This cancellation causes photodissociation to depend sensitively on the interaction potential at other angles than the dominant one. Part of potential surface where much larger torque exists can now play an important role in photodissociation. MQDT also enables us to see which processes play important roles after cancellation. This is done by examining the amounts of time delayed by asymptotic eigenchannels.

• Journal of Hydrogen and New Energy
• /
• v.32 no.4
• /
• pp.228-235
• /
• 2021

Polymer electrolyte membrane fuel cells (PEMFC) are currently being used in various transport applications such as drones, unmanned aerial vehicles, and automobiles. The power required is different according to the type of use, purpose, and the conditions adjusted using a cell stack. The fuel cell stack is compressed to reduce the size and prevent fuel leakage. The unit cells that make up the cell stack are subjected to compression by clamping force, which makes geometrical changes in the porous media and it impacts on cell performance. In this study, finite elements method (FEM) and computational fluid dynamics (CFD) analysis for the deformed unit cell considering the effects of clamping force is performed. First, structural analysis using the FEM technique over the deformed gas diffusion layer (GDL) considering compression is carried out, and the resulting porosity changed in the GDL is calculated. The PEMFC model is then verified by a three-dimensional, two-phase fuel cell simulation applying the physical properties and geometry obtained before and after compression. The detailed simulation results showed different concentration distributions of fuel between the original and deformed geometry, resulting in the difference in the distribution of current density is represented at compressed GDL region with low oxygen concentration.

• Steel and Composite Structures
• /
• v.39 no.1
• /
• pp.51-64
• /
• 2021

This paper presents a high-order shear and normal deformation theory for the bending of FGM plates. The number of unknowns and governing equations of the present theory is reduced, and hence makes it simple to use. Unlike any other theory, the number of unknown functions involved in displacement field is only four, as against five or more in the case of other shear and normal deformation theories. Based on the novel shear and normal deformation theory, the position of neutral surface is determined and the governing equilibrium equations based on neutral surface are derived. There is no stretching-bending coupling effect in the neutral surface-based formulation, and consequently, the governing equations of functionally graded plates based on neutral surface have the simple forms as those of isotropic plates. Navier-type analytical solution is obtained for functionally graded plate subjected to transverse load for simply supported boundary conditions. The accuracy of the present theory is verified by comparing the obtained results with other quasi-3D higher-order theories reported in the literature. Other numerical examples are also presented to show the influences of the volume fraction distribution, geometrical parameters and power law index on the bending responses of the FGM plates are studied.

• Tribology and Lubricants
• /
• v.38 no.3
• /
• pp.73-83
• /
• 2022

This paper is concerned with an analysis of a surface edge crack emanated from a sharp contact edge. For a geometrical model, a square wedge is in contact with a half plane whose materials are identical, and a surface perpendicular crack initiated from the contact edge exists in the half plane. To analyze this crack problem, it is necessary to evaluate the stress field on the crack line which are induced by the contact tractions and pseudo-dislocations that simulate the crack, using the Bueckner principle. In this Part I, the stress filed in the half plane due to the contact is re-summarized using an asymptotic analysis method, which has been published before by the author. Further focus is given to the stress field in the half plane due to a pseudo-edge dislocation, which will provide a stress solution due to a crack (i.e. a continuous distribution of edge dislocations) later, using the Burgers vector. Essential result of the present work is the corrective functions which modify the stress field of an infinite domain to apply for the present one which has free surfaces, and thus the infiniteness is no longer preserved. Numerical methods and coordinate normalization are used, which was developed for an edge crack problem, using the Gauss-Jacobi integration formula. The convergence of the corrective functions are investigated here. Features of the corrective functions and their application to a crack problem will be given in Part II.

• Structural Engineering and Mechanics
• /
• v.84 no.3
• /
• pp.423-435
• /
• 2022

In this article, we present torsion-bending analysis of a composite FGM beam with an open section, according to the advanced and refined theory of 1D / 3D beams based on the 3D Saint-Venant's solution and taking into account the edge effects. The (initially one-dimensional) model contains a set of three-dimensional (3D) displacement modes of the cross section, reflecting its 3D mechanical behaviour. The modes are taken into account depending on the mechanical characteristics and the geometrical form of the cross-section of the composite FGM beam. The model considered is implemented on the CSB (Cross-Section and Beam Analysis) software package. It is based on the RBT/SV theory (Refined Beam Theory on Saint-Venant principle) of FGM beams. The mechanical and physical characteristics of the FGM beam continuously vary, depending on a power-law distribution, across the thickness of the beam. We compare the numerical results obtained by the three-beam theories, namely: The Classical Beam Theory of Saint-Venant (Classical Beam Theory CBT), the theory of refined beams (Refined Beam Theory RBT), and the theory of refined beams, using the higher (high) modes of distortion of the cross-section (Refined Beam Theory using distorted modes RBTd). The results obtained confirm a clear difference between those obtained by the three models at the level of the supports. Further from the support, the results of RBT and RBTd are of the same order, whereas those of CBT remains far from those of higher-order theories. The 3D stresses, strains and displacements, obtained by the present study, reflect the 3D behaviour of FGM beams well, despite the initially 1D nature of the problem. A validation example also shows a very good agreement of the proposed models with other models (classical or higher-order beam theory) and Carrera Unified Formulation 1D-beam model with Lagrange Expansion functions (CUF-LE).

• Advances in aircraft and spacecraft science
• /
• v.10 no.1
• /
• pp.51-65
• /
• 2023

In this paper, the effect of deepness on in-plane free vibration behavior of a curved functionally graded (FG) nanobeam based on nonlocal elasticity theory has been investigated. Differential equations and boundary conditions have been developed based on Hamilton's principle. In order to figure out the size effect, nonlocal theory has been adopted. Properties of material vary in radial direction. By using Navier solution technique, the amount of natural frequencies has been obtained. Also, to take into account the deepness effect on vibrations, thickness to radius ratio has been considered. Differences percentage between results of cases in which deepness effect is included and excluded are obtained and influences of power-law exponent, nonlocal parameter and arc angle on these differences percentage are studied. Results show that arc angle and power law exponent parameters have the most influences on the amount of the differences percentage due to deepness effect. It has been observed that the inclusion of geometrical deep term and material distribution results in an increase in sensitivity of dimensionless natural frequency about variation of aforementioned parameters and a change in variation range of natural frequency. Finally, several numerical results of deep and shallow curved functionally graded nanobeams with different geometry dimensions are presented, which may serve as benchmark solutions for the future research in this field.

• Structural Engineering and Mechanics
• /
• v.86 no.4
• /
• pp.443-459
• /
• 2023

This study investigates the theoretical thermal buckling analyses of thick porous rectangular functionally graded (FG) plates with different geometrical boundary conditions resting on a Winkler-Pasternak elastic foundation using a new higher-order shear deformation theory (HSDT). This new theory has only four unknowns and involves indeterminate integral variables in which no shear correction factor is required. The variation of material properties across the plate's thickness is considered continuous and varied following a simple power law as a function of volume fractions of the constituents. The effect of porosity with two different types of distribution is also included. The current formulation considers the Von Karman nonlinearity, and the stability equations are developed using the virtual works principle. The thermal gradients are involved and assumed to change across the FG plate's thickness according to nonlinear, linear, and uniform distributions. The accuracy of the newly proposed theory has been validated by comparing the present results with the results obtained from the previously published theories. The effects of porosity, boundary conditions, foundation parameters, power index, plate aspect ratio, and side-to-thickness ratio on the critical buckling temperature are studied and discussed in detail.

• Structural Engineering and Mechanics
• /
• v.91 no.6
• /
• pp.539-549
• /
• 2024

In this paper, thermal buckling analysis was conducted using trigonometric shear deformation theory, which employs only four unknowns instead of five. This present theory is variationally consistent, and accounts for a trigonometric variation of the transverse shear strains across the thickness and satisfies the zero traction boundary conditions on the top and bottom surfaces of the plate without using shear correction factors. The grading is provided along the thickness of the plate as per power law volume fraction variation of metal-matrix ceramic reinforced composite. The non-linear governing equation problem was solved for simply supported boundary conditions. Three types of thermal loads are assumed in this work: uniform, linear and non-linear distribution through-the-thickness. It is well known that material properties change with temperature variations and so the analysis was performed for both the cases: temperature-dependent (TD) and temperature-independent (TID) material properties. The impact on thermal buckling for both linear and non-linear temperature variation was considered. The results were validated for the TID case with other theories and were found to be in good agreement. Furthermore, a comprehensive analysis was performed to study the impact of grading indices and geometrical parameters, such as aspect ratio (a/b) and side-to-thickness ratio (a/h), on the thermal buckling of the FG plate.

• Tunnel and Underground Space
• /
• v.22 no.2
• /
• pp.106-119
• /
• 2012

Roughness of rock joint has generally been characterized based upon geometrical aspects of a two-dimensional surface profile. The appropriate description of joint roughness, however, should consider the features of roughness mobilization at contact areas under normal and shear loads. In this study, direct shear tests were conducted on the replicas of tensile fractured gneiss joints and the influence of the shear direction on the shear behavior and effective roughness was examined. In this procedure, a joint surface was represented as a group of triangular planes, and the steepness of each plane was characterized using the concepts of the active and inactive micro-slope angles. The contact areas at peak strength which were estimated by a numerical method showed that the locations of the contact areas were mainly dependent on the distribution of the micro-slope angle and the shear behavior of joint was dominated by only the fractions with active micro-slope angles. Therefore, a three-dimensional coefficient for the quantification of rock joint roughness is proposed based on the distribution of active micro-slope angle: active roughness coefficient, $C_r$. Comparison of the active roughness coefficient and the peak shear strength obtained from the experiment suggests that the active roughness coefficient is the effective parameter to quantify the surface roughness and estimate the shear behavior of rock joint.

• The Journal of Engineering Geology
• /
• v.15 no.3
• /
• pp.257-268
• /
• 2005

In situ rock mass is generally heterogeneous and discontinuous, with varying degrees of strength along the planes of weakness. The planes of weakness such as joints, faults, cracks and bedding planes, control the strength and deformation characteristics of the rock mass. Subsequently, the stability of underground opening depends upon the spatial distribution of discontinuities and their mechanical properties in relation with geometrical shape of openins as well as the mechanical properties of intact rock materials. Understanding the behaviour of a discontinuous rock mass remains a key issue for improving excavation design in hiかy stressed environments. Although recent advances in rock mechanics have provided guidelines for the design of underground opening in isotropic rock mass, prediction and control of deformation in discontinuous rock masses are still unclear. In this study, parametric study was performed to investigate the plastic zone size, stress distribution and deformation behavior around underground opening in a discontinuous rock mass using a continuum joint model. The solutions were obtained by an elasto-plastic finite difference analysis, employing the Mohr-Coulomb failure criteria. Non-associated flow rule and perfectly plastic material behavior are also assumed.