• Journal of the Korean Institute of Gas
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• v.21 no.2
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• pp.50-57
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• 2017

Shale gas reservoir are composed of very fine grained particles, and their pores are very small, at the scale of nanometers. In this study, a parametric study was implemented to investigate the effect of knudsen diffusion, relative permeability and permeability reduction in shale gas reservoir. Shale gas reservoir model in Horn-River was developed to confirm the productivity for different design parameters such as diffusion, relative permeability, connate water saturation, and permeability reduction.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.28 no.9
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• pp.367-372
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• 2016

Gas diffusion layer (GDL) of PEMFCs plays a role that it diffuses the reactant gases to the catalyst layer on the membrane and discharge water from the catalyst layer to the channel. Physical parameters related to the mass transport of GDL are mostly from the uncompressed GDLs while actual GDLs in the assembled stacks are compressed. In this study, the relation of compression and strain of GDLs with various Polytetrafluoroethylene (PTFE) loading is measured experimentally and In-plane gas permeability is measured at the condition that the GDLs are in compressive strain. The gas permeability decreased with the loading of PTFE and the presentation of gas permeability under compressive stain is expected to improve the accuracy of modeling work of mass transport in the GDL.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.36 no.2
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• pp.207-217
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• 2016

Permeability can not be expressed as a function of porosity alone, it depends on the porosity, pore size and distribution, and tortuosity of pore channels in concrete. There has been considerable interest in the relationship between microstructure and transport in cementitious materials, however, it is very rare to deal with the theoretical study on gas permeability coefficient in connection with carbonation of concrete and the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. In this study, fundamental approach to compute gas permeability of (non)carbonated concrete is suggested. For several compositions of cement pastes, the gas permeability coefficient was calculated with the analytical formulation, followed by a microstructure-based model. For carbonated concrete, reduced porosity was calculated and this was used for calculating the gas permeability coefficeint. As the result of calculation of gas permeability for carbonated concrete, carbonation leaded to the significant reduction of gas permeability coefficient and this was obvious for concrete with high w/c ratio. Meanwhile, the relationship between gas permeability and water permeability has a linear function for cement paste based on Klinkenberg effect, however, which is not effective for concrete. For the evidence of the modeling, YOON's test was accomplished and these results were compared to each other.

• Journal of Korea Soil Environment Society
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• v.5 no.3
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• pp.35-54
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• 2001

It is difficult to accurately predict each flow rate of landfill gas and leachate extracted from many of wells, which have been completed into a waste landfill containing gas and water. However it may be approximately predicted if we can define only relative fluid permeability of gas and leachate flowing through landfill porous media. Therefore numerical simulation using multi-phase flow equations makes use of ei s input data of the relative permeability which is measured and calculated in laboratory environment like in-situ, and consequently we can quantitatively obtain each flow rate of gas and leachate from collection wells. These series of technologies can provide with the important informations to determine the success or failure of landfill gas energy and landfill stabilization. This paper analyses the characteristics of landfill gas collection by six classes of case studies for none described landfill.

• Proceedings of the Membrane Society of Korea Conference
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• 1997.10a
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• pp.69-70
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• 1997

Polyimides and related polymers, when synthesized from aromatic monomers, have generally rigid chain structures resulting in a low gas permeability. The rigidity of polymer chains reduces the segmental motion of chains and works as a good barrier against gas transport. To overcome the limit of use as materials of gas separation membranes due to low gas permeability, block copolymers with the incorporation of flexible segments like siloxane linkage and ether linkage have been studied. These block copolymers have microphase-separated structures composed of microdomains of flexible poly(dimethylsiloxane) or polyether segments and of rigid polyimides segments. In case of rigid-flexible block copolymers, the characteristics of both phases for gas permeation are of great difference. The permeation of gas molecules occurs favorably through microdomains of flexible segments, whereas those of rigid segments hinder the permeation of gas molecules. Accordingly the increase of content of flexible segments in a rigid polymer matrix will increase the gas permeability of the membrane linearly. However, this prediction does not satisfy enough many experimental results and in particular the drastic increase of the permeability is observed in a certain volume fraction. It was proposed that the gas transport mechanism is dominated by diffusion rather than gas solubility in a certain content of flexible phase if solution-diffusion mechanism is adopted. However, the transition from solubility-dependent to diffusion-dependent cannot be explained by the understanding of mechanism itself. Therefore, we consider an effective chemical path which permeable phase can form in a microheterogenous medium, and percolation concept is introduced to describe the permeability transition at near threshold where for the first time a percolation path occurs. The volume fraction of both phases is defined as V$_{\alpha}$ and V$_{\beta}$ in block copolymers, and the volume of $\beta$ phase in the threshold forming geometrically a traversing channel is defined as V$_{\betac}$. The formation mechanism of shortest chemical channel is schematically depicted in Fig. 1.

• Journal of the Korean institute of surface engineering
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• v.40 no.6
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• pp.245-249
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• 2007

Amorphous IZO films were deposited on PET substrate by DC magnetron sputtering without substrate heating. In order to investigate effect of reactive gas addition on film properties, 0.2-0.4% of $H_2$ or $O_2$ gas was introduced during the deposition. Deposited IZO films were evaluated with mechanical property, electrical property, and water permeability. In the case of $H_2$ gas addition, mechanical property showed clear degradation compared to $O_2$ gas. In the case of $O_2$ gas, water permeability of the IZO film was increased compared to $H_2$ gas which could be attributed to the low adhesion of the film caused by bombardment of high energy negative oxygen ion. As a result, it is confirmed that water permeability of the film could be strongly affected by adhesion of the film.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.8
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• pp.767-773
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• 2013

This study suggested the variations of porosity and gas permeability of gas diffusion layers (GDLs), which are easily deformed among the components of a highly compressed PEMFC stack. The volume change owing to compression was measured experimentally, and the variations in the porosity and gas permeability were estimated using correlations published in previous literature. The effect of polytetrafluoroethylene (PTFE) which is added to the GDLs to enhance water discharge was investigated on the variations of porosity and gas permeability. The gas permeability which strongly affects the mass transport through GDL, decreases sharply with increasing compression when the GDL has high PTFE loading. As a result, the mass transport through the pore network of GDL can be changed considerably according to the PTFE loading even with the same clamping force. The accuracy of modeling of transport phenomena through GDL can be improved due to the enhanced correlations developed based on the results of this study.

• Geomechanics and Engineering
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• v.13 no.2
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• pp.285-300
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• 2017

Shallow coal resources are increasingly depleted, the mining has entered the deep stage. Due to "High stress, high gas, strong adsorption and low permeability" of coal seam, the gas drainage has become more difficult and the probability of coal and gas outburst accident increases. Based on the flow solid coupling theory of coal seam gas, the coupling model about stress and gas seepage of coal seam was set up by solid module and Darcy module in Comsol Multiphysics. The gas extraction effects were researched after applying hydraulic technology to increase permeability. The results showed that the effective influence radius increases with the expanded borehole radius and drainage time, decreases with initial gas pressure. The relationship between the effective influence radius and various factors presents in the form: $y=a+{\frac{b}{\left(1+{(\frac{x}{x_0})^p}\right)}}$. The effective influence radius with multiple boreholes is obviously larger than that of the single hole. According to the actual coal seam and gas geological conditions, appropriate layout way was selected to achieve the best effect. The field application results are consistent with the simulation results. It is found that the horizontal stress plays a very important role in coal seam drainage effect. The stress distribution change around the drilling hole will lead to the changes in porosity of coal seam, further resulting in permeability evolution and finally gas pressure distribution varies.

• Geomechanics and Engineering
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• v.27 no.6
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• pp.583-594
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• 2021

The gas permeability behavior of unsaturated bentonite-based materials is of major importance for ensuring effective sealing of high-level radwaste repositories. This study investigated this by taking a sample of Granular Bentonite Material (GBM) at the end of the Engineered Barrier Emplacement (EB) experiment in the Opalinus Clay, placing it under different humidity conditions until it achieved equilibration, and testing the change in the gas permeability under loading and unloading. Environmental humidity is shown to have a significant effect on the water content, saturation, porosity and dry density of GBM and to affect its gas permeability. Higher sensitivity to confining pressure is exhibited by samples equilibrated at higher relative humidity (RH). It should be noted that for the sample at RH=98%, when the confining pressure is raised from 1 MPa to 6 MPa, gas permeability can be reduced from 10^-16 m² to 10^-19 m², which is close to the requirements of gas tightness. Due to higher water content and easier compressibility, samples equilibrated under higher RH show greater irreversibility during the loading and unloading process. The effective gas permeability of highly saturated samples can be increased by 2-3 orders of magnitude after 105℃ drying. In addition, cracks possibly occurred during the dehydration and drying process will become the main channel for gas migration, which will greatly affect the sealing performance of GBM.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.1
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• pp.164-170
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• 2000

Important factors in a casting mold are strength at the mold surface and gas permeability of the mold. This study investigates the effects of pre-pressure and sand particle hardness on gas permeability, with a constraint that the norm of a stiffness array at the mold surface should be higher than a certain value. The constitutive relation is obtained using a hypoplasticity model. This study is firstly attempted to investigate sand behavior in mold fabrication, and will give a theoretical base for fabricating better molds.