• Title/Summary/Keyword: gas measurement method

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Development of a Raman Lidar System Using the Photon-counting Method to Measure Carbon Dioxide (이산화탄소 원격 계측을 위한 광 계수 방식의 라만 라이다 장치 개발)

  • Sun Ho Park;In Young Choi;Moon Sang Yoon
    • Korean Journal of Optics and Photonics
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    • v.35 no.2
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    • pp.71-80
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    • 2024
  • We developed a Raman lidar system for remote measurement of carbon dioxide present in atmospheric space. An air-cooled laser with 355-nm wavelength and a 6-inch optical receiver was used to miniaturize the Raman lidar system, and a scanning Raman lidar system was developed using a two-axis scanning device and a photon counter. To verify the performance of the developed Raman lidar system, a gas chamber capable of maintaining a concentration was located at a distance of about 87 m, and the change in Raman signal according to the change in the concentration of carbon dioxide was measured. As a result, it was confirmed that the change in the Raman scattering signal of carbon dioxide that appeared for a change in carbon dioxide concentration from about 0.67 to 40 vol% was linear, and the coefficient of determination (R2) value, which indicates the correlation between the carbon dioxide concentration and Raman scattering signal, showed a high linearity of 0.9999.

A Study on Port's Decarbonization Strategies : focusing on its Barriers and Solutions (항만의 탈탄소 전환에 관한 연구: 장애요인과 해결방안을 중심으로)

  • Han, Chul-Hwan
    • Journal of Korea Port Economic Association
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    • v.40 no.2
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    • pp.137-155
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    • 2024
  • To achieve the national goal of "2050 Carbon Neutrality" in the era of the climate crisis, it is important to support the decarbonization of ports, which are the vital node of the global supply chain. Following the establishment of the concept of port's decarbonzation, this study reviewed the obstacles and solutions to port decarbonization through literature research. Furthermore, the goals and strategies for decarbonization implementation of world major ports were examined through case analysis, and the level of decarbonization implementation of the five Korean major ports was quantitatively evaluated using a performance-based score measurement method. As a result of the analysis, the level of decarbonization of Korean ports is generally far behind that of advanced countries. In particular, measures for environment-friendly inland transportation, future alternative fuel bunkering facilities, and various market-based incentive policies are needed. As a policy task for the decarbonization of Korean ports, first, the necessity of establishing a emission inventory, monitoring, and reporting system and the disclosure of related information, second, the mixing strategy of various greenhouse gas reduction measures, and third, the increase in the proportion of renewable energy at ports were suggested.

Preparation and Characterization of Iron Phthalocyanine Thin Films by Vacuum Sublimation (진공증착법을 이용한 철프탈로시아닌 박막의 합성과 그 특성)

  • Jee, Jong-Gi;Lee, Jae-Gu;Hwang, Dong-Uk;Lim, Yoon-Mook;Yang, Hyun-Soo;Ryu, Haiil;Park, Ha-Sun
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.644-651
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    • 1999
  • In this experiment the Iron phthalocyanine (FePc) films on Si-wafer and alumina pallet were prepared using vacuum sublimation with conditions of changing reaction time, temperature, and deposition rate. Then, some samples were annealed following annealing. Techniques such as XRD, SEM, and resistance measurement method, were dedicated to characterize the changes of surface structure, phase transformation and electric resistance sensitivity in accordance with change of film thickness. In proportion to the decrease of deposition temperature from $370^{\circ}C$ to $350^{\circ}C$, intensities of (200), (011), (211) and (114) planes of $\alpha$-phase were decreased and (100) plane of $\beta$-phase were appeared. The film thickness were controlled by regulating the volume of precursor material during rapid deposition. As a result, it was observed that crystalline particle size had been increased according to the increase of film thickness and $\alpha$-phase transformed to $\beta$-phase. In consequence of measuring the crystallinity of films annealed between $150^{\circ}C$ and $350^{\circ}C$, $\alpha$- to $\beta$-phase transformation was appeared to begin at $150^{\circ}C$ and completely transformed to $\beta$-phase at $350^{\circ}C$. Electric resistance sensitivity of FePc film to $NO_x$ gas along temperature change of FePc films was observed to be more stable with the decrease of the film thickness.

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Seismic attenuation from VSP data in methane hydrate-bearing sediments (메탄 하이드레이트 부존 퇴적층으로부터 획득한 수직탄성파 (VSP) 자료에서의 탄성파 진폭 감쇠)

  • Matsushima, Jun
    • Geophysics and Geophysical Exploration
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    • v.10 no.1
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    • pp.29-36
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    • 2007
  • Recent seismic surveys have shown that the presence of methane hydrate (MH) in sediments has significant influence on seismic attenuation. I have used vertical seismic profile (VSP) data from a Nankai Trough exploratory well, offshore Tokai in central Japan, to estimate compressional attenuation in MH-bearing sediments at seismic frequencies of 30-110 Hz. The use of two different measurement methods (spectral ratio and centroid frequency shift methods) provides an opportunity to validate the attenuation measurements. The sensitivity of attenuation analyses to different depth intervals, borehole irregularities, and different frequency ranges was also examined to validate the stability of attenuation estimation. I found no significant compressional attenuation in MH-bearing sediments at seismic frequencies. Macroscopically, the peaks of highest attenuation in the seismic frequency range correspond to low-saturation gas zones. In contrast, high compressional attenuation zones in the sonic frequency range (10-20 kHz) are associated with the presence of methane hydrates at the same well locations. Thus, this study demonstrated the frequency-dependence of attenuation in MH-bearing sediments; MH-bearing sediments cause attenuation in the sonic frequency range rather than the seismic frequency range As a possible reason why seismic frequencies in the 30-110 Hz range were not affected in MH-bearing sediments, I point out the effect of thin layering of MH-bearing zones.

The Economic Comparision through LCC Analysis on each Graded Alternatives for Green Remodeling of Public Building (공공건축물의 그린리모델링 수준별 LCC (Life Cycle Cost) 분석을 통한 경제성 비교)

  • Kim, Jaemoon;Lee, Junghyuk;Lee, Duhwan
    • Korean Journal of Construction Engineering and Management
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    • v.19 no.2
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    • pp.38-49
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    • 2018
  • Since the ratification of the Paris Agreement (COP21), the government is continuously strengthening policies for the reduction of greenhouse gas of the construction industry in accordance with the growing importance of reducing greenhouse gas and obligation of the government. Especially, the government emphasizes the need to improve the energy performance of old public buildings. Since 2014, the government is running a pilot project in which the government supports the construction cost of the green remodeling project of old public buildings and it is intended to develop the best practice of green remodeling and activate the green remodeling in the private sector. In this study, we analyzed the economical efficiency of the old public buildings by each level through green remodeling and conducted building related investigation and equipment measurement to plan the alternatives of the corresponding buildings. The improvement plan is a green remodeling plan that integrates alternatives. Five improvement plans were developed for each level to analyze the economic feasibility of each plan. As for the analysis method, the first energy demand amount calculation and the LCC analysis were performed through ECO2. In the LCC aspect, the improved 3/4 plan (middle level plan) was the most excellent and results were obtained in the order of the highest cost plan followed by the lowest cost plan. As a result, it is expected that it can be utilized as a basic data for future green remodeling performance plan and economic feasibility analysis in the future.

The properties of AlGaN epi layer grown by HVPE (HVPE에 의해 성장된 AlGaN epi layer의 특성)

  • Jung, Se-Gyo;Jeon, Hun-Soo;Lee, Gang-Seok;Bae, Seon-Min;Yun, Wi-Il;Kim, Kyoung-Hwa;Yi, Sam-Nyung;Yang, Min;Ahn, Hyung-Soo;Kim, Suck-Whan;Yu, Young-Moon;Cheon, Seong-Hak;Ha, Hong-Ju
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.1
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    • pp.11-14
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    • 2012
  • The AlGaN layer has direct wide bandgaps ranging from 3.4 to 6.2 eV. Nowadays, it is becoming more important to fabricate optical devices in an UV region for the many applications. The high quality AlGaN layer is necessary to establish the UV optical devices. However, the growth of AlGaN layer on GaN layer is difficult due to the lattice mismatch and difference thermal expansion coefficient between GaN layer and AlGaN layer. In this paper, we attempted to grow the LED structure on GaN template by mixed-source HVPE method with multi-sliding boat system. We tried to find the optical and lattice transition of active layer by control the Al content in mixed-source. For the growth of epi layer, the HCl and $NH_3$ gas were flowed over the mixed-source and the carrier gas was $N_2$. The temperature of source zone and growth zone was stabled at 900 and $1090^{\circ}C$, respectively. After the growth, we performed the x-ray diffraction (XRD) and electro luminescence (EL) measurement.

Fabrication of Electrolyte for Direct Carbon Fuel Cell and Evaluation of Properties of Direct Carbon Fuel Cell (직접탄소 연료전지용 전해질 제조 및 직접탄소 연료전지 특성 평가)

  • Pi, Seuk-Hoon;Cho, Min-Je;Lee, Jong-Won;Lee, Seung-Bok;Lim, Tak-Hyoung;Park, Seok-Joo;Song, Rak-Hyun;Shin, Dong-Ryul
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.786-789
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    • 2011
  • In order to estimate the possibility of applying electrolytes generally used in solid oxide fuel cells(SOFCs) to direct carbon fuel cells(DCFCs), properties of YSZ(yttria stabilized zirconia) electrolyte were evaluated. In this study, vacuum slurry coating method was adapted to coat thin layer on anode support substrate. After sintering the electrolyte at $1400^{\circ}C$ for 5hrs, microstructure was analyzed by using SEM image. Also, gas permeability and ionic conductivity were measured to find out the potential possibility of electrolyte for DCFCs. The YSZ electrolyte represented dense coating layer and low gas permeability value. The ionic conductivity of YSZ electrolyte was high over $800^{\circ}C$. After measurement of the electrolyte properties, direct carbon fuel cell was fabricated and its performance was measured at $800^{\circ}C$.

Relationship between Interfacial Tension and Solubility of Diesel Fuel in Surfactant Solutions (계면활성제용액-경유 간 계면장력과 용해도 상관관계 연구)

  • Jeong, Seung-Woo;Hur, Jeong-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.70-73
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    • 2013
  • Solubility of oil contaminants in surfactant solutions plays an important role in selecting a suitable surfactant type for soil remediation. Solubility measurement procedures consist of making an equilibrium between surfactant solution and oil, solvent extraction using dichloromethane, and condensation for gas chromatography analysis. Solubility measurement requires time consumption and lots of materials. Interfacial tension is the contracting force between two immiscible liquids, surfactant solution and oil, and also closely related to solubility of oil. This study established a relationship between the interfacial tension and solubility of diesel fuel in surfactant solution and suggested a quick method to estimate solubility of oil in a surfactant solution by measuring its interfacial tension. The results of this study showed that the solubility of diesel fuel in surfactant solution was exponentially increased by decreasing the interfacial tension between two immiscible liquids. The solubility of diesel fuel was significantly increased under the interfacial tension conditions below 1 dyne/cm, while the solubility change was not apparent under the interfacial tension conditions beyond 5 dyne/cm. Interfacial tension measurements may allow us to quickly select an efficient surfactant and its concentration for soil remediation.

Characteristics Evaluation on Welding Metal Zones Welded with Inconel 625 Filler Metal to Cast Steel for Piston Crown Material

  • Jeong, Jae-Hyun;Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.5
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    • pp.542-547
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    • 2015
  • Since the oil price has been significantly jumped for several years, a heavy oil of low quality has been mainly used in the diesel engine of the merchant ship. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone revealed the lowest value, having the highest value of hardness. The corrosive products with red color and local corrosion like as a pitting corrosion were considerably observed at the base metal zone, while these morphologies were not wholly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the Inconel 625 electrode.

Size measurement of electrosprayed droplets using shadowgraph visualization method (Shadowgraph 가시화 기법을 활용한 정전분무액적의 크기 측정)

  • Oh, Min-Jeong;Kim, Sung-Hyun;Lee, Myong-Hwa
    • Particle and aerosol research
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    • v.13 no.4
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    • pp.151-158
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    • 2017
  • Electrostatic precipitator is widely used to remove particulate matters in indoor air and industrial flue gas due to low pressure drop and high collection efficiency. However, it has a low collection efficiency for the submicrometer sized particles. Electrospraying is a potential method to increase the particle charging efficiency, which results in increased collection efficiency. Although particle charging efficiency is highly dependent upon droplet size, the effective measuring method of the droplets is still uncertain. Tap water was electrosprayed in this study, and the images of electrosprayed droplets were taken with a high speed camera coupled with several visualization methods in order to measure the droplets size. The droplet size distribution was determined by an image processing with an image-J program. As a result, a droplet measured by a laser visualization, had a half size of that by a Xenon light visualization. In addition, the experimentally measured droplet sizes were a good agreement with the predicted values suggested by $Fern{\acute{a}}ndez$ de la Mora and Loscertales(1994).