• Journal of the Korean Graphic Arts Communication Society
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• v.29 no.3
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• pp.133-142
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• 2011

We produce a photosensitive convex plate to research a Nickel metal relief printing plate using galvanic process. A Method for preparing DLC convex plate that is metalized on Nickel metal relief printing plate using CVD(Chemical Vapor Deposition) process and $N_2DLC$-convex plate that is DLC metalized thin film layer of $N_2$ plasma surface treatment are comprised. DLC thin film layers on Nickel surface are fragile. The results of the research indicate that the coefficient of friction on DLC metalized thin film layer is relatively low than Nickel surface and the durability of Nickel surface coated DLC metalized thin film layer is superior to Nickel surface. A relative evaluation of three form plate wetting properties using varnish liquid-drop plate indicates superior printing aptitudes for $N_2DLC$, DLC, Nichel plate order as above.

• Journal of Welding and Joining
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• v.15 no.5
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• pp.124-133
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• 1997

Corrosion behavior of welded SWS400 steel used for bridges was studied in a range of the acid-rain environment using immersion, potentiodynamic polartization, polarization resistance, and galvanic corrosion tests. The SWS400 steel exhibited active corrosion behavior in the range of acid-rain environment, i.e. no passivation. As the results of immersion corrosion test, Tafel extrapolation method, and polarization resistance measurement, the average corrosion rats of the steels were 0.31-0.72 mm/year in the pH of 4-5, and 0.17 mm/yera in the pH 6, respectively. The steel showed a resistance to corrosion in the pH 6. The observed active behavior of SWS400 steel in chloride-containing environment indicated that the chloride ions exerts a detrimental influence on the formation of passive films. Galvanic corrosion was observed between the weld and the base metals because the weld is anodic to the base metal.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.16 no.1
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• pp.1-10
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• 2018

A simplified flowsheet for pyroprocessing commercial spent fuel is proposed in which the only salt treatment step is actinide drawdown from electrorefiner salt. Actinide drawdown can be performed using a simple galvanic reduction process utilizing the reducing potential of gadolinium metal. Recent results of equilibrium reduction potentials for Gd, Ce, Nd, and La are summarized. A description of a recent experiment to demonstrate galvanic reduction with gadolinium is reviewed. Based on these experimental results and material balances of the flowsheet, this new variant of the pyroprocessing scheme is expected to meet the objectives of minimizing cost, maximizing processing rate, minimizing proliferation risk, and optimizing the utilization of geologic repository space.

• Journal of the Korean Society for Railway
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• v.4 no.2
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• pp.62-70
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• 2001

Pure copper, Cu-1.1wt%Cd and ACSR(Aluminum Conductor Steel Reinforced) have been used as catenary materials of the electric railway system. Since these materials may be exposed to the corrosive environments like polluted air, acid rain and sea water, it is important to investigate the corrosion rates in various corrosive environments. The aqueous corrosion characteristics of catenary materials in aerated acid, neutral and alkali solutions were studied by using immersion corrosion tests, electrochemical measurements and analytical techniques. In order to examine corrosion characteristics according to the dissolved oxygen content, pH, chloride ion concentration ion, and the addition of Cd to Cu, a series of tests such as potentiodynamic polarization, a.c impedance spectroscopy and galvanic corrosion tests were carried out with these materials. Results showed that the addition of Cd to Cu and chloride ion in the solution have an adverse effects on the resistance to corrosion. Additionally, Galvanic currents between Al and steel wires of ACSR were confirmed by using ZRA(zero resistance ammeter) method.

• Journal of the Korean Chemical Society
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• v.11 no.1
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• pp.38-43
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• 1967

In order to explain the positive catalytic action of copper compound for the rate of leaching of zinc sulfide minerals, the electrode and redox potentials of both synthetic and natural sulfides were measured at various conditions of temperatures and pressures. The potentials of Chalcopyrite and copper sulfide were considerably higher than that of zinc sulfide, whereas lead sulfide and Galena had slightly lower potentials than that of zinc sulfide. At elevated temperatures and pressures, the same tendency was obtained. By means of comparing the calculated and measured values of potentials for sulfides, it was suggested that the electrode potentials in acid solution were generated by oxidation of sulfur ion. As a result, it was concluded that the catalytic action of copper compound in the leaching of synthetic zinc sulfide should be arised from the galvanic action between sulfides keeping intimate contact one another in which copper sulfide worked as cathodic and zinc sulfide as anodic part analogous to the metal corrosion under galvanic action.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.59 no.11
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• pp.2026-2031
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• 2010

The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.

• Korean Journal of Materials Research
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• v.6 no.4
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• pp.401-411
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• 1996

전기방식법중의 하나인 음극방식법은 많은 해수설비를 갖추고 있는 발전소에 적용되고 있는 설비지만 운용의 측면에서는 적절하지 못한 방식조건으로 많은 문제점이 노출되고 있다. 본 연구에서는 설비지만 운용의 측면에서는 적절하지 못한 방식조건으로 많은 문제점이 노출되고 있다. 본 연구에서는 해수설비중의 하나인 발전소 복수기의 음극방식설비를 해석 대상으로 하여 가장 많이 사용되는 희생양극 재질인 Zn 양극을 입구측 파이프, 수실벽 및 천장등 여러위치에 부착한 경우 전위분포 및 전류밀도분포를 구하여 최적방식조건을 찾아보았다. 또한 전류밀도값을 Faraday 법칙을 이용부식속도로 환산하여 galvanic 부식정도와 방식정도를 평가하였다. 그 결과 희생양극을 galvanic 부식이 심하게 일어날 것으로 예상되는 위치에 부착하면 방식효과가 가장 크게 나타남을 알 수 있었다.

• Journal of the Korean institute of surface engineering
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• v.53 no.6
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• pp.322-329
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• 2020

The utilization of aluminum scrap is a subject of great importance in terms of reducing energy consumption and environmental protection. However, aluminum scrap contains impurities, which can degrade the properties of aluminum alloy, especially corrosion resistance. This study examines the effect of scrap charge rate of aluminum alloys about microstructures and corrosion characteristics. According to the metallographic examinations, Mg2Si tended to become coarser and its uniformity was decreased by increasing aluminum scrap charge rate. The immersion test exhibited corrosion progressed through the eutectic areas due to micro-galvanic interactions. Electrochemical measurements revealed that excess aluminum scrap could reduce the intergranular corrosion resistance of aluminum alloys. Results showed that the scrap charge rate is important factor in the design of corrosion resistance of aluminum die casting alloys.

• Nuclear Engineering and Technology
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• v.54 no.10
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• pp.3778-3787
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• 2022

The stress-assisted oxidation behaviour of Inconel 52 M/316 austenitic stainless-steel (SS) dissimilar weld joints (DMWJ) in a simulated pressurised water reactor environment was investigated. A corrosion galvanic couple formed between the Inconel 52 M and 316 SS due to differences in their nonferrous metal content. The electric field from the corrosion couple attracted metal cations (e.g. Fe²⁺, Cr³⁺) to the Inconel 52 M that were deposited as FeCr₂O₄. An additional corrosion galvanic couple was generated due to variations in the plastic deformation of the DMWJ. The superposition of electric fields from the different couples resulted in ridge-like oxide depositions in the fusion zone.

• Journal of Electrochemical Science and Technology
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• v.14 no.4
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• pp.349-360
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• 2023

This study investigated the tri-metallic galvanic coupling of different metals in the tubes, fillers, and fins of a heat exchanger. The goal was to prevent corrosion of the tubes using the fin as a sacrificial anode while ensuring that the filler metal has a more noble potential than the fin, to avoid detachment. The metals were arranged in descending order of corrosion potential, with the noblest potential assigned to the tube, followed by the filler metal and the fin. To address a reduction in protection current of the fin, the filler metal was modified by adding Zn to decrease its corrosion potential. However, increasing the Zn content of filler metal also increases its corrosion current. The study examined three different filler metals, considering their corrosion potential, and kinetics. The results suggest that a filler metal with 1.5 wt.% Zn addition is optimal for providing cathodic protection to the tube while reducing the reaction rate of the sacrificial anode.