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Fractionation and Rare-Element Mineralization of Kenticha Pegmatite, Southern Ethiopia (에티오피아 남부 켄티차 페그마타이트의 분화양상과 희유원소 광화작용)

  • Kim, Eui-Jun;Kim, Soo-Young;Moon, Dong-Hyeok;Koh, Sang-Mo
    • Economic and Environmental Geology
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    • v.46 no.5
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    • pp.375-390
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    • 2013
  • The Kenticha rare-element (Ta-Li-Nb-Be) mineralized zone is located in ophiolitic fold and thrust complex of southern Ethiopia and was firstly discovered by joint exploration program of Ethiopia-Soviet in 1980s. It includes Dermidama, Kilkele, Shuni Hill, Kenticha, and Bupo pegmatites from south to north. The Kenticha pegmatite intruded parallel to NS-striking serpentinite and talc-chlorite schist, and is exposed approximately 2 km length and 400-700 m width. The Kenticha pegmatite is internally zoned and subdivided into lower quartz-muscovite-albite granite, intermediate muscovite-quartz-albite-microcline pegmatite, and upper spodumene-quartz-albite pegmatite, based on their mineral assemblage. The major, trace elements (e.g., Rb, Li, Nb, Ta, and Ga), and element ratios (e.g., K/Rb, Nb/Ta, Mg/Li, and Al/Ga) suggest that the fractionation and solidification of pegmatite have progressed from the lower towards upper pegmatite. In contrast, unlike general magmatic fractionation, Mg/Li ratios of the Kenticha pegmatite tend to be increased towards the upper pegmatite. It may result from post-magmatic hydrothermal alteration and/or interaction with upper ultramafic rock. Rare-element mineralization in Kenticha pegmatite concentrates on the upper pegmatite, which contains up to 3.0 wt % $Li_2O$, 3,780 ppm Rb, 111 ppm Cs, 1,320 ppm Ta, and 332 ppm Nb. Ore minerals in Kenticha pegmatite mostly include tantalite, spodumene, and lepidolite, and tantalite has an association with coarser quartz-spodumene and relatively fine sacchroidal albite. The tantalite is classified into Mn-tantalite as a function of $Mn^*[Mn/(Mn+Fe)]$ and $Ta^*[Ta/(Ta+Nb)]$ values. Its compositions ($Mn^*$, $Ta^*$, and Nb/Ta) between coarse and fine tantalites are different and the former is strongly enriched in Ta and depleted in Nb compared to latter one. In conclusion, rare-element mineralization in the Kenticha pegmatite may has occurred in the latest stage of magmatic fractionation.

Fabrication and characteristics of NbTi superconducting wires with Cu-Si matrix for AC use (Cu-Si 기지금속을 사용한 교류용 초전도선재 제조 및 특성)

  • Ha, D.W.;Oh, S.S.;Oh, B.H.;Kwon, Y.G.;Cho, J.W.;Ryu, K.S.;Han, I.Y.;Baik, H.K.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1165-1167
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    • 1995
  • The Cu-Si alloy has been proposed as a new matrix materal for filamentary Nb-Ti wires in AC use. The Cu-Si alloy shows approprite mechanical and electrical properties, and is economically more favourable than the Cu-Ni alloy matrix used currently. Moreover, the addition of Si to Cu prevents the formation of intermetallic compounds around the filaments. After we investigated resistivity and hardness of Cu-Si alloy as matrix materal, investigated CuSi/NbTi interface reactions and superconductivities of superconducting wires that were made by various heat treatment.

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$La_2O_3$ 첨가에 따른 (Ka,K)$NbO_3$ 세라믹스의 미세구조 및 압전 특성

  • Seo, Byeong-Ho;Seong, Geum-Hyeon;No, Jeong-Rae;Lee, Sang-Ho;Ryu, Ju-Hyeon;Kim, In-Seong;Song, Jae-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03a
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    • pp.12-12
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    • 2010
  • The piezoelecric properties of $(K_{0.5}Na_{0.5})(Nb_{0.96}Sb_{0.04})O_3$+$1.2mol%K_4CuNb_8O_{23}$+$xmol%La_2O_3$ lead-free piezoelecric ceramics were investigated as a function x. These ceramics were fabricated by conventional ceramics processing. Piezoelectric constant ($d_{33}$) and piezoelectric charge coefficient ($g_{33}$) of x=0.2 mol% composition exhibited good properties of 160.3pC/N and 37.4($10^{-3}Vm/N$), respectively.

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The Effect of Calcination Temperature on Physical Properties of $Ba[Mg_{1/3}(Nb_{0.2}Ta_{0.8})_{2/3}]O_3$ Ceramics (하소온도가 $Ba[Mg_{1/3}(Nb_{0.2}Ta_{0.8})_{2/3}]O_3$ 세라믹스의 물리적 특성에 미치는 영향)

  • 김재윤;김부근;김강언;정수태;조상희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.252-255
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    • 1999
  • The effect of calcination temperature(1st and 2nd calcining at 110$0^{\circ}C$ , 120$0^{\circ}C$ and 130$0^{\circ}C$ respectively) on physical properties of BMNT Ceramics ware investigated. The optimum 1st and 2nd calcination temperature were 120$0^{\circ}C$ , and sintering temperature was 155$0^{\circ}C$. In this condition, the sintering density was 7.53 [g/㎤] and the dielectric constant, Q.f$_{0}$ and $\tau$$_{r}$ were 26, 80, 300[GHz] and +1.5[ppm/$^{\circ}C$] respectively in the microwave range.e.e.

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Electron Spin Resonance Investigation of Fe3+ in Crystalline LiNbO3 Under the Polarized External Radiation

  • Park, Jung-Il;Cheong, Hai-Du
    • Journal of the Korean Magnetic Resonance Society
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    • v.17 no.2
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    • pp.92-97
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    • 2013
  • We study the electron spin resonance line-width (ESRLW) of $Fe^{3+}$ in crystalline $LiNbO_3$ ; the ESRLW is obtained using the projection operator method (POM) developed by Argyres and Sigel. The ESRLW is calculated to be axially symmetric about the c-axis and is analyzed by the spin Hamiltonian with an isotopic g factor at a frequency of 9.5 GHz. The ESRLW increases exponentially as the temperature increases, and the ESRLW is almost constant in the high-temperature region (T>8000 K). This kind of temperature dependence of the ESRLW indicates a motional narrowing of the spectrum when $Fe^{3+}$ ions substitute the $Nb^{5+}$ ions in an off-center position. It is clear from this feature that there are two different regions in the graph of the temperature dependence of the ESRLW.

Synthesis and Characterization of Molecular Composite Prepared from Layered Perovskite Oxide, $HLa_2Ti_2NbO_{10}$

  • 홍영식;김시중
    • Bulletin of the Korean Chemical Society
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    • v.18 no.6
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    • pp.623-628
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    • 1997
  • A layered perovskite oxide, $RbLa_2Ti_2NbO_{10}$, was prepared and investigated for proton exchange and intercalation behaviors. Its protonated form, $Hla_2Ti_2NbO_{10}$, exhibits the Bronsted acidity and reacts with organic amines. Polyoxonuclear cation, 4Al_{13}$, was then introduced into the interlayer by refluxing octylamine-intercalated compound with an $Al_{13}$ pillaring solution. These layered oxides were characterized by X-ray diffractometer, thermogravimeter, FT-infrared spectrometer and elemental analyzer. It is observed that the polyoxonuclear cation-pillared material exhibits a bilayer structure and is thermally more stable than organic counterpart at higher temperatures. The surface area of the pillared material annealed at 400 ℃ was the value of 25.1 m²/g.

The Design and Driving Characteristics of Piezoelectric Ceramic Oscillator for Spraying of Liquid Material (액체 연료의 분무를 위한 압전 세라믹 진동자의 설계 및 동작 특성)

  • Lee, S.H.;Seok, J.Y.;Ryu, G.H.;Kim, H.G.;Kim, J.G.;Yoo, J.H.;SaGong, G.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.686-689
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    • 2002
  • The application of the ultrasonic nozzle has been extended because it is possible atomization of liquid material. In this study, the characteristics of the ultrasonic nozzle and ceramic oscillator were investigated. The oscillator for the ultrasonic nozzle were made piezoelectric ceramic of $Pb[(Sb_{1/2}Nb_{1/2})_{0.035}-(Mn_{1/3}Nb_{2/3})_{0.065}-(Zr_{0.49}Ti_{0.51})_{0.90}]O_3$. The electromechanical coupling factor$(k_p)$ and mechanical quality factor$(Q_m)$ showed the values of 0.555, 1,214 respectively when the Zr/Ti ratio was 49/51. Moreover, this oscillator will have the temperature stability because it's curie temperature is $322[^{\circ}C]$. The driving current of ultrasonic nozzle showed the value of 80[mA] when the driving time was 10[min.]. Also, The surface temperature of ceramic oscillator showed $80[^{\circ}C]$ at driving time 10[min.] We knew that the ultrasonic nozzle had stabile driving above 10[min.].

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Analysis of the IP Spoofing Attack Exploiting Null Security Algorithms in 5G Networks

  • Park, Tae-Keun;Park, Jong-Geun;Kim, Keewon
    • Journal of the Korea Society of Computer and Information
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    • v.27 no.9
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    • pp.113-120
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    • 2022
  • In this paper, we analyze the feasibility of the IP spoofing attack exploiting null security algorithms in 5G networks based on 3GPP standard specifications. According to 3GPP standard specifications, the initial Registration Request message is not protected by encryption and integrity. The IP spoofing attack exploits the vulnerability that allows a malicious gNB (next generation Node B) to modify the contents of the initial Registration Request message of a victim UE (User Equipment) before forwarding it to AMF (Access and Mobility Management Function). If the attack succeeds, the victim UE is disconnected from the 5G network and a malicious UE gets Internet services, while the 5G operator will charge the victim UE. In this paper, we analyze the feasibility of the IP spoofing attack by analyzing whether each signaling message composing the attack conforms to the 3GPP Rel-17 standard specifications. As a result of the analysis, it is determined that the IP spoofing attack is not feasible in the 5G system implemented according to the 3GPP Rel-17 standard specifications.