• Title/Summary/Keyword: functional transfer

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Highly efficient ortho-fluoro-dimeric cinchona-derived phase-transfer catalysts

  • Park, Hyeung-Geun;Jeong, Byeong-Seon;Lee, Jeong-Hee;Yoo, Mi-Sook;Jew, Sang-Sup
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.250.3-251
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    • 2003
  • A series of cinchona alkaloid-derived dimeric quaternary ammonium salts were prepared as chiral phase-transfer catalysts by the introduction of various functional groups on the phenyl ligand. Among them. the 2-F-substituted derivative 21 showed the highest enantioselectivity in the alkylation of the glycine anion equivalent 1 (97->99 % ee).

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Dipole-Forming Photochemical Group Transfer Reactions of Phthalimides and ${\alpha}-Ketoamides$

  • Yoon, Ung-Chan;Mariano Patrick S.
    • Journal of Photoscience
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    • v.12 no.3
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    • pp.155-162
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    • 2005
  • Results of studies of SET-promoted dipole-forming photochemical group transfer reactions of phthalimide and ${\alpha}-ketoamide$ derivatives are discussed. Azomethine ylide forming photochemical reactions, which are initiated by intramolecular SET from tethered silylmethyl-, carboxymethyl-, and ${\beta}-hydroxyethyl$ containing electron donors to excited states of phthalimides, related maleimides, and conjugated imides, are presented first. Following this, investigations of regioselective 1,4-dipole forming photochemical reactions of N-trialkylsilylmethyl- and N-trialkylstannyl-${\alpha}$-ketoamides are described.

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Quantum Mechanical Studies for Structures and Energetic of Double Proton Transfer in Biologically Important Hydrogen-bonded Complexes

  • Park, Ki-Soo;Kim, Yang-Soo;Kim, Kyung-Hyun;Kim, Yong-Ho
    • Bulletin of the Korean Chemical Society
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    • v.32 no.10
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    • pp.3634-3640
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    • 2011
  • We have performed quantum mechanical calculations to study the geometries and binding energies of biologically important, cyclic hydrogen-bonded complexes, such as formic acid + $H_2O$, formamidine + $H_2O$, formamide + $H_2O$, formic acid dimer, formamidine dimer, formamide dimer, formic acid + formamide, formic acid + formamidine, formamide + formamidine, and barrier heights for the double proton transfer in these complexes. Various ab initio, density functional theory, multilevel methods have been used. Geometries and energies depend very much on the level of theory. In particular, the transition state symmetry of the proton transfer in formamidine dimer varies greatly depending on the level of theory, so very high level of theory must be used to get any reasonable results.

Recent Advances in High-performance Functional Ceramics using 3D Nanostructuring Techniques (3차원 나노구조화 기술을 이용한 고성능 기능성 세라믹 연구개발 동향)

  • Ahn, Changui;Park, Junyong;Jeon, Seokwoo
    • Ceramist
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    • v.22 no.3
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    • pp.230-242
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    • 2019
  • Functional ceramics are widely utilized in a variety of application fields such as structural materials, sensors, energy devices, purification filter and etc due to their high strength, stability and chemical activity. With the breakthrough development of nanotechnology, many researchers have studied new types of nanomaterials including nanoparticle, nanorod, nanowire and nanoplate to realize high-performance ceramics. Especially several groups have focused on the 3D nanostructured ceramics because of their large surface area, efficient load transfer, ultra-fast ion diffusion and superior electrical (or thermal) conductivity. In this review, we introduce the reported fabrication strategies of the 3D nanostructured and functional ceramics, also summarized the 3D nanostructured ceramic based high-performance applications containing photocatalysts, structural materials, energy harvesting and storage devices.

From the synthesis of functional RAFT agents to the design of functional latex particles

  • Bathfield M.;D'Agosto F.;Spitz R.;Charreyre M.T.;Delair T.;Dos Santos A.M.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.319-319
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    • 2006
  • RAFT polymerization can produce under controlled conditions polymer chains incorporating well-defined chain ends. By designing a simple way of producing functional RAFT agents, a variety of ${\Box}-end$ groups was successfully introduced onto hydrophilic polymer chains. The ${\Box}-end$ group being a thiocarbonyl thio function was used as efficient chain transfer agent in dispersion or emulsion polymerization to produce original functional latex particles.

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Transfer Methods of Inorganic Thin Film Materials for Heterogeneously- Integration Flexible Semiconductor System (이종 집적 유연 반도체 시스템 구현을 위한 무기물 박막소재의 전사 방법)

  • Gyeong Hyeon Ju;Jeong Hyeon Kim;Sang Yoon Park;Kang Hyeon Kim;Han Eol Lee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.3
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    • pp.241-252
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    • 2024
  • With the recent development of emerging technologies, information acquisition and delivery between users has been actively conducted, and inorganic thin film transfer technology that effectively transfers various materials and devices is being studied to develop flexible electronic devices accordingly. This is aimed at innovative structural changes and functional improvement of electronic devices in the era of the Internet of Things (IoT). In particular, advanced technologies such as microLEDs are used to realize high-resolution flexible displays, and the possibility of heterogeneous integrated technologies can be presented by precisely transferring materials to substrates through various transfer process. This paper introduced physical, chemical, and self-assembly transfer methods based on inorganic thin film materials to implement heterogeneous integrated flexible semiconductor systems and introduces the results of application studies of semiconductor devices obtained through different transfer technologies. These studies are expected to bring about innovative changes in the field of smart devices, medical technology, and user interfaces in the future.

Tendocutaneous Free Flap Transfer from Dorsum of the Foot (족배부 유리편을 이용한 생건 피부편이식)

  • Lee, Kwang-Suk;Park, Sang-Won;Byun, Young-Soo;Kang, Ki-Hoon;Kang, Oh-Yong
    • Archives of Reconstructive Microsurgery
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    • v.1 no.1
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    • pp.24-30
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    • 1992
  • Tendocutaneous free flap transfer has been usually used to treat troublesome wounds, which had extensive defect of skin and tendons, since Daniel and Taylor had reported successful free flap transfer in 1973. Among the numerous types of free flap, the dorsalis pedis flap, which could include superficial peroneal nerve, extensor tendon and second metatarsus, was widely used as composite free flap. The authors analysed 13 cases of tendocutaneous free flap transfer from dorsum of the foot which were operated at Korea University Hospital from March 1981 to August 1991. The results were as follows: 1. The average size of these flaps was $53.7cm^2$(mazimum $82cm^2$, minimum $30cm^2)$, the average number and length of tendons were 2.9(maximum, 5, minimum 1), and 9.2cm (maximum 17cm, minimum 5cm). 2. The survival rate of flaps was 100%, and functional results by Dargan's criteria were 4 in excellent, 4 good, 3 fair and 2 poor. 3. The delayed healing on donor site could prevented by the meticulous skin graft and repair of extensor retinaculum. 4. The cases of electrical burn were more worse than the traumatic cases in functional results.

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