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Impacts of C60-Ionic Liquids (ILs) Interactions and IL Alkyl Chain Length on C60 Dispersion Behavior: Insights at the Molecular Level

  • Wang, Zhuang;Tang, Lili;Wang, Degao
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2679-2683
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    • 2014
  • Mechanisms underlying the impacts of interactions between carbon nanoparticles (CNPs) and ionic liquids (ILs) on the physicochemical behavior of CNPs need to be more full worked out. This manuscript describes a theoretical investigation at multiple levels on the interactions of fullerene $C_{60}$ with 21 imidazolium-based ILs of varying alkyl side chain lengths and anionic types and their impacts on $C_{60}$ dispersion behavior. Results show that ${\pi}$-cation interaction contributed to mechanism of the $C_{60}$-IL interaction more than ${\pi}$-anion interaction. The calculated interaction energy ($E_{INT}$) indicates that $C_{60}$ can form stable complex with each IL molecule. Moreover, the direction of charge transfer occurred from IL to $C_{60}$ during the $C_{60}$-IL interaction. Quantitative models were developed to evaluate the self-diffusion coefficient of $C_{60}$ ($D_{fullerene}$) in bulk ILs. Three interpretative molecular descriptors (heat of formation, $E_{INT}$, and charge) that describe the $C_{60}$-IL interactions and the alkyl side chain length were found to be determinants affecting $D_{fullerene}$.

Design of the timing controller for automatic magnetizing system

  • Yi Jae Young;Arit Thammano;Yi Cheon Hee
    • Proceedings of the IEEK Conference
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    • 2004.08c
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    • pp.468-472
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    • 2004
  • In this paper a VLSI design for the automatic magnetizing system has been presented. This is the design of a peripheral controller, which magnetizes CRTs and computers monitors and controls the automatic inspection system. We implemented a programmable peripheral interface(PPI) circuit of the control and protocol module for the magnetizer controller by using a O.8um CMOS SOG(Sea of Gate) technology of ETRI. Most of the PPI functions has been confirmed. In the conventional method, the propagation/ramp delay model was used to predict the delay of cells, but used to model on only a single cell. Later, a modified "apos;Linear delay predict model"apos; was suggested in the LODECAP(LOgic Design Capture) by adding some factors to the prior model. But this has not a full model on the delay chain. In this paper a new "apos;delay predict equationapos;" for the design of the timing control block in PPI system has been suggested. We have described the detail method on a design of delay chain block according to the extracted equation and applied this method to the timing control block design.

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Growth of GaN on sapphire substrate by GSMBE(gas source molecular beam epitaxy) using ammonia as nitrogen source (Nitrogen source로 ammonia를 사용해 GSMBE로 성장된 GaN 박막 특성)

  • Cho Hae-jong;Han Kyo-yong;Suh Young-suk;Misawa Yusuke;Park Kang-sa
    • Proceedings of the IEEK Conference
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    • 2004.06b
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    • pp.501-504
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    • 2004
  • High quality GaN layer was obtained on 0001 sapphire substrate using ammonia($NH_3$) as a nitrogen source by gas source molecular beam epitaxy. As a result, RHEED is used to investigate the relaxation processes which take place during the growth of GaN. In-situ RHEED(reflection high electron energy diffraction) appeared streaky-like pattern. The full Width at half maximum of the x-ray diffraction(FWHM) rocking curve measured from plane of GaN has exhibited as narrow as 8arcmin and surface roughness was 7.83nm. Photoluminescence measurement of GaN was investigated at room temperature, where the intensity of the band edge emission is much stronger than that of deep level emission. The GaN epitaxy layer according to various growth condition was investigated.

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Frequency-Dependent Line Capacitance and Conductance Calculations of On-Chip Interconnects on Silicon Substrate Using Fourier cosine Series Approach

  • Ymeri, H.;Nauwelaers, B.;Vandenberghe, S.;Maex, K.;De Roest, D.;Stucchi, M.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.1 no.4
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    • pp.209-215
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    • 2001
  • In this paper a method for analysis and modelling of coplanar transmission interconnect lines that are placed on top of silicon-silicon oxide substrates is presented. The potential function is expressed by series expansions in terms of solutions of the Laplace equation for each homogeneous region of layered structure. The expansion coefficients of different series are related to each other and to potentials applied to the conductors via boundary conditions. In the plane of conductors, boundary conditions are satisfied at $N_d$ discrete points with $N_d$ being equal to the number of terms in the series expansions. The resulting system of inhomogeneous linear equations is solved by matrix inversion. No iterations are required. A discussion of the calculated line admittance parameters as functions of width of conductors, thickness of the layers, and frequency is given. The interconnect capacitance and conductance per unit length results are given and compared with those obtained using full wave solutions, and good agreement have been obtained in all the cases treated

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A real-time acoustic echo canceller implemented on the multimedia PC (멀티미디어 PC상에 구현된 실시간 음향 반향제거기)

  • Cha, Youn-Cheul;Yoo, Jae-Ha;Youn, Dae-Hee
    • Journal of the Korean Institute of Telematics and Electronics S
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    • v.35S no.11
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    • pp.184-193
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    • 1998
  • In this paper, a real-time acoustic echo canceller is implemented using only PC's CPU without extra help from a DSP chip. The adaptive digital filter is designed efficiently so that it can be implemented in real-time and has a proper cancellation performance. It is proposed that a new double talk detector consumes a small computational complexity and guarantees the fast detection and robust operation. The real-time acoustic echo canceller consists of the full-duplex sound card and 166 MHz Pentium PC, and requires less than 10% CPU time.

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Controlling Brightness Compensation of Full Color LED Vision (천연색 LED 정보표시 시스템의 휘도보정 제어장치)

  • Hwang, Hyun-Hwa;Yim, Hyung-Kun;Park, Jung-Hwan;Lee, Jong-Ha
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.1291-1296
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    • 2005
  • In this paper, we prevent a display quality drop for image of characteristics brightness ununiformity depend on LED use to LED vision. It is about that method also a control system development equipped with brightness compensation function of LED vision which is done easily for LED set up of LED vision. Generally, It is calculate driving current value is attended by each brightness to brightness characteristics mathematical function establish by "Y=aX+b", When is doing brightness value for "Y", driving current value for "X", brightness compensation value by using time for "b", characteristics value for "a" ground with characteristics curve of LED. So much, First It is create brightness data of each pixel take a photograph red, green and blue of LED vision. Second It is get average error about each pixel which get average brightness value of entire. Last, It is handle a complicated for about gradationally regulation to color and brightness of image send to LED vision. Also It raise the whole average brightness value of vision adjust for "b" value to solve brightness drop problem of LED using the long time.

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Modeling of Organic Schottky Diodes for Circuit Simulations (회로 시뮬레이션을 위한 유기물 쇼트기 다이오드 모델링)

  • Kim, Hyo-Jong;Baatar, Nyambayar;Kim, Shi-Ho
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.6
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    • pp.7-12
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    • 2010
  • A semi-empirical organic schottky diode model is proposed for circuit simulation. We have set up a full custom design environment for organic schottky diode circuit using Spectre AHDL, which is widely used commercial EDA tool. We measured frequency response from fabricated rectifier, and it was compared to circuit simulation results using the AHDL model. The frequency response of the fabricated rectifier circuit is not sufficient for 13.56MHz RFID, however, it is enough for 135kHz-band RFID.

Board Gender Diversity and Corporate Sustainability Performance: Mediating Role of Enterprise Risk Management

  • FAKIR, A.N.M. Asaduzzaman;JUSOH, Ruzita
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.6
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    • pp.351-363
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    • 2020
  • The objective of this paper is to explore how board gender diversity affects corporate sustainability performance. Therefore, this paper examines the direct association between board gender diversity with corporate sustainability performance and the mediation effect of enterprise risk management (ERM) on this association. The study employed a cross-sectional survey method. Data were collected from annual reports, websites, and through the questionnaires that were distributed to Chief Financial Officers (CFOs) of all the listed companies of Dhaka Stock Exchange, Bangladesh. The partial least square technique of Structural Equation Modelling (SEM) approach was employed for data analysis. The result did not find support for the direct association between board gender diversity and sustainability performance in Bangladesh context. This implies that contextual factors, such as, male-dominant board, appointment of female directors based on family ties, lack of education and expertise etc. may discount gender diversity direct influence on sustainability performance. However, the study finds strong support for the mediating role of ERM use within the corporate structure. Further analysis of indirect effect suggests that ERM use mediates the relationship of board gender diversity and sustainability performance in full. This implies that in the Bangladesh context effective use of ERM is highly recommended.

Consideration of NDVI and Surface Temperature Calculation from Satellite Imagery in Urban Areas: A Case Study for Gumi, Korea

  • Bhang, Kon Joon;Lee, Jin-Duk
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.35 no.1
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    • pp.23-30
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    • 2017
  • NDVI (Normalized Difference Vegetation Index) plays an important role in surface land cover classification and LST (Land Surface Temperature Extraction). Its characteristics do not full carry the information of the surface cover typically in urban areas even though it is widely used in analyses in urban areas as well as in vegetation. However, abnormal NDVI values are frequently found in urban areas. We, therefore, examined NDVI values on whether NDVI is appropriate for LST and whether there are considerations in NDVI analysis typically in urban areas because NDVI is strongly related to the surface emissivity calculation. For the study, we observed the influence of the surface settings (i.e., geometric shape and color) on NDVI values in urban area and transition features between three land cover types, vegetation, urban materials, and water. Interestingly, there were many abnormal NDVI values systematically derived by the surface settings and they might influence on NDVI and eventually LST. Also, there were distinguishable transitions based on the mixture of three surface materials. A transition scenario was described that there are three transition types of mixture (urban material-vegetation, urban material-water, and vegetation-water) based on the relationship of NDVI and LST even though they are widely distributed.

Performance Analysis of a Korean Word Autocomplete System and New Evaluation Metrics (한국어 단어 자동완성 시스템의 성능 분석 및 새로운 평가 방법)

  • Lee, Songwook
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.6
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    • pp.656-661
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    • 2015
  • The goal of this paper is to analyze the performance of a word autocomplete system for mobile devices such as smartphones, tablets, and PCs. The proposed system automatically completes a partially typed string into a full word, reducing the time and effort required by a user to enter text on these devices. We collect a large amount of data from Twitter and develop both unigram and bigram dictionaries based on the frequency of words. Using these dictionaries, we analyze the performance of the word autocomplete system and devise a keystroke profit rate and recovery rate as new evaluation metrics that better describe the characteristics of the word autocomplete problem compared to previous measures such as the mean reciprocal rank or recall.