• Title/Summary/Keyword: free gas

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The Influence of Sintering Atmosphere on the Reduction Behaviour of Refractory Bricks and the Basic Properties of $UO_{2}$ Pellet

  • Lee, Seung-Jae;Kim, Kyu-Tae;Chung, Bum-Jin
    • The Korean Journal of Ceramics
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    • v.4 no.4
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    • pp.279-285
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    • 1998
  • The $UO_2$ pellets are usually sintered under hydrogen gas atmosphere. Hydrogen gas may cause unexpected early failure of the refractory bricks in the sintering furnace. In this work, nitrogen was mixed with hydrogen to investigate the effect of nitrogen gas on a failure machanism of the refractory bricks and on the microstructure of the $UO_2$ pellet. The hydrogen-nitrogen mixed gas experiments show that the larger nitrogen the mixed gas contains, the less the refractory materials are reduced by hydrogen. The weight loss measurements at $1400^{\circ}C$ for fire clay and chamotte refractories containing high content of $SiO_2$ indicate that the weight loss rate for the mixed gas is about half of that for the hydrogen gas. Based on the thermochemical analyses, it is proposed that the weight loss is caused by hydrogen-induced reduction of free $SiO_2$ and/or $SiO_2$ bonded to $Al_2O_3$ in the fire clay and chamotte refractories. However, the retardation of the hydrogen-induced $SiO_2$ reduction rate under the mixed gas atmosphere may be due to the reduction of the surface reaction rate between hydrogen gas and refractory materials in proportion to volume fraction of nitrogen gas in the mixed gas. On the other hand, the mixed gas experiments show that the test data for $UO_2$ pellet still meet the related specification values, even if there exists a slight difference in the pellet microstructural parameters between the cases of the mixed gas and the hydrogen gas.

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Preliminary Tests on Change of Free Jet Flow in Laminar with Applying Electric Fields (교류 전기장이 인가된 층류 자유제트유동의 변화에 관한 예비 조사)

  • Kim, Gyeong Taek;Lee, Won June;Park, Jeong
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.383-386
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    • 2014
  • The characteristics of gas free jet flows in laminar with having applied electric fields have been investigated experimentally. A single electrode configuration was adopted such that electric fields were applied directly to nozzle and thus the surrounding could be an infinite ground. The experimental results showed that breakdown point at laminar flow has been measured by varying the applied voltage and frequency of AC. The effect of applying electric fields to free jet flow in laminar was discussed in detail.

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Properties and Development of Halogen Free Flame Retardant Cable (Halogen Free 난연 케이블의 제특성 및 개발)

  • Choi, W.K.;Choi, W.;Seo, S.J.;Yang, H.J.;Won, J.H.
    • Proceedings of the KIEE Conference
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    • 1992.07b
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    • pp.768-770
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    • 1992
  • Conventional flame retardant cable using PVC or CR materials generate considerable amount of toxic and acidic gas (HCI etc.) together with excessive black smoke during a fire. The newly developed halogen free materials have dissolved the problem of halogen acid gases. This paer describes the development of this power cable insulation and sheath, using halogen free materals.

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Field emission from hydrogen-free DLC

  • Suk Jae chung;Han, Eun-Jung;Lim, Sung-Hoon;Jin Jang
    • Journal of Korean Vacuum Science & Technology
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    • v.3 no.1
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    • pp.49-53
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    • 1999
  • We have studied the field emission characteristics of diamond-like-carbon (DLC) films deposited by a layer-by-layer technique using plasma enhanced chemical vapor deposition, in which the deposition of a thin layer of DLC and a CH4 plasma exposure on its surface were carried out alternatively. The hydrogen-free DLC can be deposited by CH4 plasma exposure for 140 sec on a 5 nm DLC layer. N2 gas-phase doping in the CH4 plasma was also carried out to reduce the work function of the DLC. The optimum [N2]/[CH4] flow rate ratio was found to be 9% for the efficient electron emission, at which the onset-field was 7.2 V/$\mu\textrm{m}$. It was found that the hydrogen-free DLC has a stable electron emitting property.

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Lift-Off Voltage and Partial Discharge Characteristics of Free Conducting Particles in GIS (GIS 내 금속입자의 부상전압과 부분방전특성 연구)

  • Yoon, Jin-Yeol;Han, Sang-Ok
    • Proceedings of the KIEE Conference
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    • 1998.07e
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    • pp.1684-1686
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    • 1998
  • Gas Insulated Switchgear(GIS) acts as an indispensible part in power transmission network. In order that GIS may have its high reliability, it is necessary to pay careful attention to its whole process e.g., designing, manufacturing, installation, and operation. The main hazard in GIS comes from free conducting particles, which can move and cause breakdown under the influence of the electric field. Although the concentration on protecting the GIS inner part against the free conducting particles is made, it is, actually, almost impossible to avoid the hazard from the particles throughly. In this paper, using the EHV test chamber, partial discharge quantity in GIS was measured when free conducting particles initiate to discharge for providing fundamental data for the purpose of developing predictive diagnosis technology on site GIS.

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Corona Discharge In GIS Initiated by Free Conducting Particles (자유이물에 의한 GIS 내부 코로나특성 연구)

  • Yoon, Jin-Yeol
    • Proceedings of the KIEE Conference
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    • 1997.07e
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    • pp.1801-1803
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    • 1997
  • The Gas Insulated Switchgear(GIS) has made it an indispensible part of power transmission network. In order that the GIS may have its high reliability, it is necessary to pay careful attention to its whole process e.g., designing, manufacturing, installation, and operation. The main hazard in GIS comes from free conducting particles, which can move and cause breakdown under the influence of the electric field. Although the concentration on protecting the GIS inner part against the free conducting particles is made, it is, actually, almost impossible to avoid the hazard from the particles throughly. In this paper, the corona discharge in GIS initiated by the free conducting particles was discribed through laboratorial experiment The magnitude of the corona discharge voltage was measured using current measuring method by the impedance. The purpose of this experiment is to get fundamental data which is essential to develop GIS diagnosis technology.

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Ginseng Extract Protects Unsaturated Fatty acid from Decomposition Caused by Iron-Mediated Lipid Peroxidation

  • Okada, Shi-Geru;Zhang, Da-Xian
    • Proceedings of the Ginseng society Conference
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    • 1998.06a
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    • pp.57-62
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    • 1998
  • We hypothesized the primary effect of ginseng was to protect cell membrane fatty acids from decomposition caused by free radicals. To confirm the antioxidant effect of ginseng, we measured the inhibitory effect on the formation of thiobarbituric acid-reactive substances, an indicator of lipid peroxidation, and evaluated the free radical scavenging effect of ginseng by electron spin resonance spectrometer, and gas chromatography. The results showed that thiobarbituric acid-reactive substances formed and the loss of arachidonic acid during lipid peroxidation, and that hydroxyl (-like) radical peak formed by the iron complex (ferric nitrilotriacetate, an known free radical generator in vitro) were completely inhibited by ginseng extract. This antioxidant effect of ginseng may be responsible for its wide pharmacological actions in clinical practice. As the free radical reactions in general are rapid and non-specific, ginseng seems to act as a normalizer, rather than a general tonic, at the stages of acute or chronic active phase of the various diseases.

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Studies of Antipyretic Component of the Earthworm (지렁이(지룡)의 해열성분에 관한 연구)

  • 김영은;이왕규;윤희정
    • YAKHAK HOEJI
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    • v.25 no.4
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    • pp.137-143
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    • 1981
  • In order to confirm the exact antipyretic component in the earthworm, etherial extract of American earthworm(Red Worm) was fractionated into five fractions by using silica gel column chromatography and thin layer chromatography. The fraction including free fatty acids was found to possess artipyretic response and standard arachidonic acid showed marked antipyretic response on typhoid vaccinated rabbits. Arachidonic acid was identified from the free fatty acid fraction of the earthworm by using gas liquid chromatography. Thus it was considered that the antipyretic activity of the free fatty acid may be due to the presence of arachidonic acid. Lipid-free earthworm powder was extracted with phosphate buffer (pH, 8.0, 0.1M) and all the proteins was salted out by ammonium sulfate. The crude precipitate was dialyzed and the impure proteins were eliminated at pH 5.4 and 4.6. The remaining protein solution was fractionated with various concentrations of acetone. The acetone fractions were identified by using S.D.S. polyacrylamide gel electrophoresis and disc gel electrophoresis. The precipitate at 85% acetone concentration and the remaining proteins in the supernatant did not exhibit the antipyretic activity.

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An Analysis on Structure of Impinging and Free Diesel Spray with Exciplex Fluorescence Method in High Temperature and Pressure Field

  • Yeom, Jeong-Kuk;Park, Jong-Sang;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • v.19 no.12
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    • pp.2281-2288
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    • 2005
  • Because an injected spray development process consists of impinging and free spray in the diesel engine, it is needed to analyze the impinging spray and free spray, simultaneously, in order to study the diesel spray behavior. To dominate combustion characteristics in diesel engine is interaction between injected fuel and ambient gas, that is, process of mixture formation. Also it is very important to analyze liquid and vapor phases of injected fuel on the investigation of mixing process, respectively and simultaneously. Therefore, in this study, the behavior characteristics of the liquid phase and the vapor phase of diesel spray was studied by using exciplex fluorescence method in high temperature and injection pressure field. Finally, it can be confirmed that the distribution of vapor concentration is more uniform in the case of the high injection than in that of the low injection pressure.

Calculation of the Entropies and Chemical Potentials of Hard-Sphere Solutes Solvated in Hard-Sphere Solids Using the Radial Free-Space Distribution Function

  • 윤병집
    • Bulletin of the Korean Chemical Society
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    • v.20 no.10
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    • pp.1209-1212
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    • 1999
  • The entropies and chemical potentials of hard-sphere solutes solvated in hard-sphere solids were calculated by Monte Carlo method using the radial free-space distribution function. This method is based on calculating the entropy by comparing the free volume of a molecule with that of an ideal gas, and is applicable even when the size of solute is very large and the solvent is a solid. When the diameter of hard-sphere solute is small the solute molecule behaves as like as a fluid in solid structures, but when the diameter of solute becomes large, a fluid-to-solid phase transition takes place. The fluid-to-solid phase transition occurs at the region of the smaller size of solute with the more increase of solvent density. The least square fit values of analytical form of the radial free-space distribution functions of solute molecules are presented for future uses.