• Journal of the Korean Institute of Gas
• /
• v.25 no.1
• /
• pp.40-47
• /
• 2021

In this study, hazards of decomposition and explosion for tert-butylperoxymaleate(TBPM), an organic peroxide, were evaluated by using various equipment to determine the cause of a fire explosion accident. As a result of DSC analysis, the instantaneous power density of TBPM was 26,401 kW/ml, and the NFPA reactive index(Nr) was classified as 4. And the positive value of EP(explosive propagation) and SS(shock sensitivity) showed that the TBPM had a potential hazard of explosion. From the experimental results, the shock sensitivity and friction sensitivity was rated as class 4 and 5, respectively. In the pressure vessel test, TBPM was ranked USA-PVT No.4 and evaluated as a self-reactive substance. In the combustion rate test, TBPM had the combustion rate of 167 mm/sec and was evaluated as the flammable solid classification 2 in GHS.

• Journal of the Korean Institute of Gas
• /
• v.26 no.1
• /
• pp.20-26
• /
• 2022

The results of experimental, theoretical, and numerical analysis were compared regarding the concentrations and velocities of flammable gas jets generated by pressurized leakage of methane gas. The concentration was measured through experiments for the jet dispersion process, and the velocities was calculated by applying the self-similarity theory. And the velocities and concentrations were calculated using CFD tools - FLACS and CFX- compared with the results. The difference between self-similarity model and CFD is due to the buoyancy term, which increases as the distance from a leak source increases. The results are compared with dimensionless parameters using the leak source radius and velocity components along the leak axis.

• Journal of the Korean Society of Safety
• /
• v.37 no.2
• /
• pp.1-9
• /
• 2022

Most factories deal with toxic or flammable chemicals in their industrial processes. These hazardous substances pose a risk of leakage due to accidents, such as fire and explosion. In the event of chemical release, massive casualties and property damage can result; hence, quantitative risk prediction and assessment are necessary. Several methods are available for evaluating chemical dispersion in the atmosphere, and most analyses are considered neutral in dispersion models and under far-field wind condition. The foregoing assumption renders a model valid only after a considerable time has elapsed from the moment chemicals are released or dispersed from a source. Hence, an initial dispersion model is required to assess risk quantitatively and predict the extent of damage because the most dangerous locations are those near a leak source. In this study, the dispersion model for initial consequence analysis was developed with three-dimensional unsteady advective diffusion equation. In this expression, instantaneous leakage is assumed as a puff, and wind velocity is considered as a coordinate transform in the solution. To minimize the buoyant force, ethane is used as leaked fuel, and two different diffusion coefficients are introduced. The calculated concentration field with a molecular diffusion coefficient shows a moving circular iso-line in the horizontal plane. The maximum concentration decreases as time progresses and distance increases. In the case of using a coefficient for turbulent diffusion, the dispersion along the wind velocity direction is enhanced, and an elliptic iso-contour line is found. The result yielded by a widely used commercial program, ALOHA, was compared with the end point of the lower explosion limit. In the future, we plan to build a more accurate and general initial risk assessment model by considering the turbulence diffusion and buoyancy effect on dispersion.

• Journal of the Korean Institute of Gas
• /
• v.25 no.2
• /
• pp.42-51
• /
• 2021

Facilities that supply specialty gases used in semiconductor manufacturing mainly handles with hazardous and dangerous substances with flammable, toxic, and corrosive properties, and gas cabinets are mainly used as such supply facilities. The effects of the supply facilities were analyzed for each leak through the rupture disk in the gas cabinet and a leak where the leak hole. In this case, gas leaked to the outside depending on the leak area. It is a factor that creates a risk depending on the concentration of the leaked gas. Depending on the risk of leakage, all measures such as safe operation procedures should be reviewed again.

• Safety and Health at Work
• /
• v.11 no.4
• /
• pp.509-516
• /
• 2020

Background: Meta-analyses have shown firefighters to be at an increased risk of several cancer types. Occupational carcinogen exposure may explain these increased risks. This study aims to describe Norwegian fire departments' work conditions from 1950 until today, focusing on factors relevant for potential occupational carcinogen exposure. Methods: With the help of a reference group, we developed a questionnaire on topics related to occupational exposure to carcinogens for the period 1950-2018. Selected Norwegian fire departments provided department-specific responses. Results: Sixteen departments, providing fire services for 48% of the Norwegian population as of 2019 and mainly consisting of professional firefighters, responded to our questionnaire. The introduction of synthetic firefighting foams, more regular live fire training, the introduction of chemical diving, and a higher number of diesel-driven fire service vehicles were identified as changes thought to increase exposure to occupational carcinogens. Changes thought to decrease exposure included the switch from negative to positive pressure self-contained breathing apparatuses, the use of self-contained breathing apparatuses during all phases of firefighting, the use of ventilating fans during firefighting, increased attention to flammable materials used during live fire training, increased attention to handling and cleaning of turnout gear and other equipment, and installment of exhaust removal systems in apparatus bays. Conclusion: Norwegian fire departments' work conditions have seen several changes since 1950, and this could influence firefighters' occupational carcinogen exposure. A peak of carcinogen exposure may have occurred in the 1970s and 1980s before recent changes have reduced exposure.

• Composites Research
• /
• v.35 no.6
• /
• pp.456-462
• /
• 2022

Since natural fibers are highly flammable, it is not easy to make them flame retardant. In this study, a liquid flame retardant based on phytic acid, APTES, and Thiourea, which are flame retardant candidates derived from nature, was prepared and its performance was verified through flame retardant treatment and flame retardancy evaluation of bamboo fibers. When a liquid flame retardant is used, it is possible to treat a large amount of natural fibers with flame retardant treatment. Nine types of flame-retardant treated bamboo fibers were prepared according to the Taguchi design of experiment method. Thereafter, vertical burning test and microcalorimeter test were performed for flame retardancy evaluation, and the surface of natural fibers before and after flame-retardant treatment was compared using scanning electron microscope. The results show that phytic acid has a significant effect on improving the flame retardancy of natural fibers. Through microstructure analysis, it was assumed that the phytic acid helps flame retardant to uniformly adhere to the surface of natural fibers. If such research results are utilized, it is possible to make a large amount of natural fibers high flammability in an eco-friendly way, which is expected to be advantageous for the application of prototypes.

• Journal of the Korean Institute of Gas
• /
• v.26 no.4
• /
• pp.36-40
• /
• 2022

Recently, the biggest topic in the industry is the area of industrial safety and health management. Since city gas is flammable gas and has a high risk of fire and explosion, much effort is required to prevent serious industrial and citizenry disasters. As part of city gas safety management, this study attempted to quantitatively predict the scope and degree of damage in the event of an explosion accident caused by city gas leakage through the Consequence Analysis. As a result, there was a difference in the accident result value according to various leakage conditions such as pressure and weather conditions. Through this study, a scenario of explosion due to city gas leakage will be prepared when performing city gas safety management work and used to prepare more effective accident prevention and emergency action plans.

• The Journal of the Convergence on Culture Technology
• /
• v.8 no.6
• /
• pp.775-785
• /
• 2022

By analyzing the operation status of fire safety management of small construction site workers, deriving problems, and suggesting improvement measures, this study was conducted to present practical basic data for their efficient use in the future, and the following conclusions were drawn. First, it was analyzed that small construction site workers are elderly in the age group of construction workers, have short construction skills, most of the jobs are working in the construction industry, and the employment type is non-regular workers. Second, the fire safety management improvement plan of small construction site workers is systematized, fire safety manager is deployed to manage fire risk, fire escape routes and emergency warning facilities are provided to inform all workers at the construction site. In addition, measures to reduce industrial accidents are needed through realistic evacuation training, fire VR training, and interesting educational programs.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2020.06a
• /
• pp.148-149
• /
• 2020

Currently, the most commonly used EPS insulation material has been mainly used because its ease of adhesion with concrete. However, due to poor adhesion with wallpaper, separate adhesion needs to be strengthened and there are cases of breakage or grooves in the process of dismantling the mold. The biggest problem is that when a fire breaks out, various harmful substances are present and highly flammable. Cork used in this study is a truly eco-friendly building material that is taken from between the outer and inner bark of cork trees and does not damage the wood. Also, it is a porous material that is made up of countless cells and contains an air gap between the cells. It is very light in weight between 0.06 and 0.07 and has excellent insulation with a heat conductivity of 0.04W/mK. In addition, it has high stability in the topic of conversation because it does not produce harmful gas when burned and has self-sustaining properties. However, research on cork, an eco-friendly building material with excellent performance to date, is scarce Therefore, we encourage existing scholars to raise interest in new eco-friendly building materials through this study. It also aims to manufacture insulation boards with new inorganic properties using the low weight and heat conductivity held by the cork.

• The Journal of the Convergence on Culture Technology
• /
• v.9 no.5
• /
• pp.843-847
• /
• 2023

In this paper, we propose a model for detecting efficient fire identification to prevent fires that can lead to various industrial accidents, farmland and large forest fires, with the widespread use of various chemicals and flammable substances as modern technology advances. This paper presents an algorithm that can detect fire smoke in a high-efficiency and short time using images, and an algorithm based on SVM(Support Vector Machine) and K fold cross-verification technologies. By analyzing images, fire and smoke detection algorithms have relatively superior detection performance compared to existing algorithms, and the analysis of fire and smoke characteristics detected in this paper is analyzed stably and efficiently and is expected to be used in various fields that may be exposed to fire risks in the future.