• Journal of the Korean Society of Clothing and Textiles
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• v.24 no.1
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• pp.15-23
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• 2000

Effect of fixation methods on the flame retardant(FR) and performance properties of MDPPA/HMM treated cotton fabrics were studied. Combination of three different fixation methods - premercerization, swelling agent treatment, pad dry cure fixation, and wet fixation - were applied to flame retardant finish of cotton with MDPPA/HMM. As a result, an increase in internal volume of cotton fiber by pre-mercerization and addition of swelling agent, and wet fixation increased %add-on of FR agent improving FR efficiency and wash fastness. Tensile strength of MDPPA/HMM treated cotton fabrics by wet fixation and swelling agent were slightly decreased, but that of premercerized cotton was improved. Wet fixated fabric showed lower bending rigidity and better compressional properties which improved fabric hand. Retention of swelling ability of cotton treated with MDPPA/HMM improved moisture absorption properties.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.11a
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• pp.35-36
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• 2022

In order to supplement the flame-retardant performance of oil stain, which can prevent wooden buildings from contamination, (NH4)2HPO4, a phosphorus flame-retardant, was added to oil stain and applied for each type of plywood, and an experiment was conducted. The addition rate was set to 0-60%, but white powder appeared on the surface of plywood from 40% and thus it was impossible to experiment, so the maximum addition rate was selected as 30%. As a result of the experiment, acacia plywood had the best performance. As the rate of addition of the flame retardant increased, the remaining time and carbonization length of all plywood decreased, but the carbonization length of the MDF plywood was not met with the standards.

• Fire Science and Engineering
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• v.24 no.3
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• pp.72-77
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• 2010

Honeycomb core structure with its excellent stiffness and strength is being utilized in many fields such as interior building material. Because it is inexpensive and renewable, honeycomb paper production is economically and environmentally helpful. However, the paper needs to be fireproofed because it is vulnerable to fire. In this study, we have undergone the performance evaluation process of the honeycomb paper which is widely used as interior material of a fire door and packing material. Four kinds of honeycomb (a honeycomb made of flame-resistant paper; a honeycomb attached with conventional flame-resistant film made in the laboratory; honeycomb impregnated with flame retardant; a honeycomb attached with flame-resistant film after impregnating fire retardant) were used in the study to compare the fire retardant performance. As a result, the honeycomb with impregnated flame retardant showed the highest performance. The flame-resistant film was effective in delaying the igniting time but had a negative effect on the rate of heat and smoke production.

• Fire Science and Engineering
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• v.33 no.3
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• pp.29-36
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• 2019

The combustion properties required for fire simulations of multi-layer, multi-component flame retardant cables were measured using a cone calorimeter. The CO and soot yields combustion efficiencies of the flame retardant cables were investigated. TFR-8 (flame retardant PCV and XLPE added), TFR-CVV-SB (flame retardant PCV and general PVC), and VCTF, which are excellent in the flame retardancy of cables, were considered. As the main result, the CO yield (y_CO) of the TFR-8 and TFR-CVV-SB flame retardant cables increased by 23% and 16%, respectively, with increasing incident radiation heat flux from 25 kW/㎡ to 50 kW/㎡. On the other hand, the CO yield of VCTF was not influenced significantly by the changes in radiant heat flux. Finally, the soot yield and combustion efficiency increased as the sheath material (flame retardant performance) was strengthened. Therefore, in a fire environment where various heat fluxes coexist, attention should be paid to the top of the application of the combustion property of the flame retardant cable.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.29-30
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• 2023

Wood is a construction material that has the advantages of carbon dioxide storage ability, noise reflection, and eco-friendliness. In order to use wood for a long time, you must use wood-specific paint, which is called oil stain. Oil stain improves water resistance and moisture resistance, but has the disadvantage of being weak against fire. This is because the oil contained in the oil stain causes a chemical reaction, and this chemical reaction causes the oil stain to spontaneously ignite, igniting nearby combustible materials and causing frequent fires. To improve this, in this study, different flame retardants were mixed and added to oil stain to produce functional oil stain. In addition, we would like to apply it to wood to check glow time and carbonization area. As a result of the experiment, it shows the best performance when mixed at 30(15 + 15)(%) and added to oil stain. The remaining burn time is satisfied from 10% for all samples, and the carbonized area is satisfied when it is 30%.

• Elastomers and Composites
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• v.50 no.4
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• pp.279-285
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• 2015

This study examined the mechanical properties and the flame retardant properties of CR rubber containing inorganic flame retardant with various contents of aluminium trihydroxide (ATH, $Al(OH)_3$). The content of aluminium trihydroxide was added in 0, 30, 50, 70 and 100 phr for T1~T5 samples. It was found that increasing the amount of addition over 30 phr resulted in decreasing the mechanical properties. On the other hand in oxygen index measurements T1 sample showed a value of 38.6%, indicating the improvement of flame retardant properties showed a value of 49.7~64.2%. In case of burn test, it was confirmed that CR rubber containing over ATH 50phr content showed performance corresponding to that of first grade fire-resistance.

• Fire Science and Engineering
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• v.31 no.3
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• pp.11-18
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• 2017

In this study, a non-halogen type organic-inorganic hybrid flame retardant sol, which can impart flame resistance to synthesize silicate of inorganic material and silane coupling agent of organic material by a sol-gel method, were newly manufactured. The addition of flame retardant will prevent loss of life in a fire because smoke from the flammability of interior finishing materials used as the construction materials poses a major danger. The smoke density measurement standard based on flame retardant performance standards, experiments were conducted according to the test equipment and procedures of ASTM E 662. The non-flaming mode experiment and the flaming mode experiment were conducted to confirm the performance of the manufactured flame retardant sol. As a result, the manufactured flame retardant sol improved the physical properties and heat resistance of existing flame retardants, and decreased the smoke production of the fire. Therefore, it may be possible to reduce the damage caused by smoke and expand the applications to various interior finishing materials.

• Carbon letters
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• v.28
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• pp.66-71
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• 2018

To improve the flame retardant performance of cellulose fibers, fluorine functional groups were introduced under various controlled fluorination conditions. The properties of the fluorinated cellulose fibers were analyzed by X-ray photoelectron spectroscopy and a thermogravimetric analysis. The fluorine functional group content in the fluorinated cellulose fibers increased with an increase in the fluorination temperature. However, the fluorination reaction increased the char yield and decreased the rate of degradation of the cellulose fibers by introducing donors, enabling the formation of a thick and compact char layer. Therefore, the flame retardant properties of cellulose fibers were improved following the fluorination treatment.

• Fire Science and Engineering
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• v.17 no.1
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• pp.33-39
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• 2003

The purpose of this study is to evaluate flame retardant performance, thermal stability and toxicity of combustion gases for some commercial wallpapers. ID evaluate flame retardant performance 45 degree combustion experiment method was used and thermal stability was evaluated using DSC and TGA apparatus (OSC-50/Shimadzu, TGA2050/TA Instruments Inc) . Concentrations of CO, $CO_2$, HCN and HCI were measured with (GASTEC/Japan, MSA400 Gas Monitor/Infitron Inc) and toxicity indices using NIST N-Gas Model were applied to evaluate the toxicity of combustion gases. The evaluation produced the following results : First, paper cork and PVC wallpaper treated with flame retardants were found to be suitable for flame retardant performance standards. Second, paper, cork and PVC wallpaper non-treated with flame retardants were shown to be relatively more hazardous because they had greater calorific values and a faster decomposition time than the flame retardant treated wallpapers. Third, the toxicity indices of non-treated wallpapers were found to be higher than those of treated wallpapers, and the toxicity index of PVC wallpapers was higher than those of paper and cork wallpapers.

• Journal of Fashion Business
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• v.24 no.3
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• pp.30-39
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• 2020

This study was conducted to identify problems in domestic flame-retardant performance specifications. Currently, the domestic wallcovering anti-inflammatory regulations are not prepared for damage caused by smoke, with the carbonized area as the main function. In particular, given that smoke is the main cause of human casualties and injuries in a fire, it is reasonable that the flame density and toxicity of the wallcovering should also be the main performance indicators. The scope and method of research in this study were as follows. First, a prior study related to fire on various wallcoverings was considered. Second, it raised questions about the effects of smoke in the event of a fire and domestic anti-inflammatory performance tests. Third, textile wallcovering samples were manufactured with viscose rayon for experimental verification of the problems and tested by Korean and EU standards without flame retardant processing to analyze the differences between each regulation. Fourth, the performance of flame retardant wallcovering according to Korean standards was evaluated using smoke density and harmful gas testing methods. The results of each test were as follows. Non-fire retardant wallcovering was rejected by Korea standards. However, B-s1.d0 in Europe. Smoke density testing and harmful gas by domestic combustion processing on the same sample showed that the smoke density increased about 4.3 times more than before, and the harmful gas test showed that the suspension of the post-processing sample slowed earlier than the non-processed sample.