• Korean Chemical Engineering Research
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• 제62권1호
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• pp.27-35
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• 2024

메탄, 프로판 등을 주성분으로 하는 연료가스는 폭발위험장소에서 사용될 수 있으며, 누출로 인한 공정조건의 영향으로 불균일한 혼합기를 형성할 수 있다. 균일한 혼합기를 대상으로 측정된 문헌 데이터를 이용한 화재 폭발 위험성 평가, 손상 예측은 가스 누출에 의한 실제 폭발 사고와 다른 결과를 얻을 수 있다. 본 연구에서는 가스 누출시 나타날 수 있는 농도 변화에 있어서 불균일성 혼합기의 폭발압력, 화염속도 등의 폭발특성을 조사하였다. 길이 0.82 m의 스테인리스 재질의 밀폐 배관에서 수행하였으며 컬러 초고속 카메라 및 압력 센서를 사용하여 관찰하였다. 또한 배관 내의 시간에 따른 농도차이 변화에 대해 회귀분석 모델을 사용하여 불균일 혼합물의 정량화 방법을 제안하였다. 본 연구의 농도 불균일성 조건에 있어서 메탄 폭발 시 전파화염은 불균일성 농도가 높아짐에 따라 화염 면적의 증가가 관찰되었고 이는 난류 화염의 주름진 화염 구조와 유사하였다. 메탄의 최대압력까지 걸리는 소요시간은 불균일성이 클수록 감소하였고, 폭발압력은 불균일성이 클수록 증가하였다. 농도가 불균일한 메탄의 K_G(폭연지수)의 범위는 1.30~1.58 [MPa·m/s]으로서 메탄의 농도가 균일성에서 불균일성로 변화하면서 17.7% 증가하였다.

• 한국가스학회지
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• 제17권5호
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• pp.15-21
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• 2013

본 연구는 3차원 위험성평가 시뮬레이션 툴(FLACS)을 활용하여 연료의 종류에 따른 위험성을 비교 평가하였다. 일반적인 고압가스 충전소 레이아웃을 활용하여 연료를 CNG, 수소, 30%HCNG로 하였을 경우 충전소에서 가스누출에 의한 화재 폭발 상황을 모사하여 피해영향을 비교 분석하였다. 그리고 가스별 누출제트에 의한 피해영향을 평가하였다. 동일한 조건에서 수소, CNG, HCNG가 누출되어 화재폭발이 발생할 경우 수소는 최대과압이 30kPa, HCNG는 3.5kPa 그리고 CNG는 0.4kPa의 과압이 측정되었다. HCNG의 과압이 CNG에 비해 7.75배 높게 측정되었으나, 수소에 비해서는 11.7%에 불과했다. 화염 전파에 있어서 수소는 매우 빠른 화염전파 특성을 가지는 반면 HCNG와 CNG는 수소에 비해 전파속도 및 전파거리에서 비교적 안전한 경향을 보였다. 제트화염에 의한 화염경계거리는 수소가 5.5m, CNG가 3.4m이고 HCNG는 CNG보다 약간 확장된 3.9m로 예측되었다.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 1996년도 학술발표회
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• pp.43-48
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• 1996

It is considered that automobile inner space is dangerous due to its combustion characteristics. (Automobile interior is largely made by plastic materials.) At last it is necessary to study on combustion characteristics of automobile interior. we could obtain its rapid combustion velocity and high smoke density by using ASTM D 2863 apparatus, DSC (Differential Scanning Calorimetry), Smoke density apparatus and so on. The study is summerized by following conditions and results. 1. Sample size was 150mm(length)$\times$60mmwidth). 2. Combustion velocity appeared peak point in the 2cm point. 3. PVC and foam layers are important factors in the face of smoke density. 4. Using DSC, we obtained the point that automobile interior was melted. 5. Automobile interior should be improved because of its low L.O.I value and rapid flame propagation velocity.

• 한국자동차공학회논문집
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• 제9권4호
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• pp.50-55
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• 2001

To simulate the combustion process under stratified charged conditions, like GDI engines, the new combustion model is proposed, which is based on Welter's FAE model and Peters' PDF model for considering primary reactions. In addition to these models, the new laminar burning velocity correlation and diffusion flame model are also included in the proposed model. The former can be applicable to much wider range of equivalence ratio, pressure and temperature than the others, such as Keck's and Guilder's models, and the latter has been derived from water-gas shift reaction and hydrogen oxidation, by which the secondary reactions can be considered after primary reactions. 3-D computation has been performed by using STAR-CD v3.05 in the simple cylindrical geometry under stratified charged condition. Judging from the calculated results, the present model proves to be reasonable to simulate the characteristics of flame propagation and concentrations of products in burned regions.

• Journal of Advanced Marine Engineering and Technology
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• 제34권8호
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• pp.1084-1093
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• 2010

화염 전파 특성을 나타내는 G 방정식에 기초한 Sub-grid Scale연소 모델을 이용하여 보염기 주위의 난류 예혼합 연소 해석에 관한 대 와동 모사를 수행하였다. Dynamic SGS 모델이 G방정식에 도입되었으며, 삼각형의 보염기 배면의 예혼합 연소 유동에 의해 검증되었다. 해석결과는 실험결과와의 비교를 통해 속도와 온도분포를 잘 예측하고 있음을 확인하였다.

• 한국자동차공학회논문집
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• 제23권4호
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• pp.402-409
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• 2015

In this study a quasi-dimensional model is developed to predict the combustion process and emissions of a GDI engine under ultra-lean conditions. Combustion of a GDI engine condition is modeled as two simultaneous processes to consider significant fuel stratification. The first process is premixed flame propagation described as burning in a hemispherically propagating flame. The second is diffusion-controlled combustion modeled as mixing of multiple spray zones in the burned gas region. Mixing is an important factor in ultra-lean conditions leaving stratified mixture of developing sprays behind the propagating premixed flame. Sheet breakup and Hiroyasu models are applied to predict the velocity of a hollow cone spray. Validation is performed against measured pressures and NOx and CO emissions at different load and rpm conditions in the test engine.

• 한국연소학회지
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• 제16권2호
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• pp.23-32
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• 2011

To investigate cell formation in hydrocarbon/hydrogen/carbon monoxide-air premixed flames, the outward propagation and cellular instabilities were experimentally studied in a constant pressure combustion chamber at room temperature and elevated pressures. Unstretched laminar burning velocities and Markstein lengths of the mixtures were obtained by analyzing high-speed schlieren images. In this study, hydrodynamic and diffusional- thermal instabilities were evaluated to examine their effects on flame instabilities. The experimentally-measured unstretched laminar burning velocities were compared to numerical predictions using the PREMIX code. Effective Lewis numbers of premixed flames with methane addition decreased for all of the cases; meanwhile, effective Lewis numbers with propane addition increased for lean and stoichiometric conditions and increased for rich and stoichiometric cases for hydrogen-enriched flames. With the addition of propane, the propensity for cell formation significantly was diminished, whereas cellular instabilities for hydrogen-enriched flames were promoted. However, similar behavior of cellularity was obtained with the addition of methane to the reactant mixtures.

• 한국안전학회지
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• 제19권4호
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• pp.150-154
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• 2004

실린더형의 내용적 6리터의 용기를 이용하여 수소와 액화석유 가스(LPG)의 폭발 특성을 측정하였고 270리터의 직육면체 용기를 이용하여 폭발 후 화재로의 전이 현상을 실험하였다. 폭발 특성은 strain type 압력센서를 사용하여 측정하였으며 폭발 후 화재로의 전이 현상은 고속카메라로 촬영하여 분석하였다. 실험 결과 완전 연소 농도 비보다 약간 높은 농도에서 최대 폭발압력을 나타내었다. 폭발압력 상승 속도와 화염 전파속도는 연소속도와 비례함을 알 수 있었으며 이러한 폭발 특성들은 폭발 후 화재로의 전이에 영향을 미침을 알 수 있었다. 또한 폭발 화염온도, 화염의 용기 내 체류시간 등도 폭발 후 화재로의 전이에 중요한 변수가 됨을 알 수 있었다.

• International Journal of Automotive Technology
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• 제6권4호
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• pp.323-332
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• 2005

A cylindrical constant volume combustion chamber was used to investigate the flow characteristics at the spark electrode gap and the combustion characteristics of a homogeneous charged methane-air mixture under various overall charge pressures, excess air ratios and ignition times. The flow characteristics, including the mean velocity and turbulence intensity, were analyzed with a hot wire anemometer. Combustion pressure development measured by piezoelectric pressure transducer, a flame propagation image acquired by ICCD camera and exhaust emissions measured by 2-valve gas chromatography were used to investigate effects of initial pressures, excess air ratios and ignition times on the combustion characteristics. It was found that the mean velocity and turbulence intensity had the maximum value around 200-300 ms and then decreased gradually to a near-zero value after 3000 ms and that the combustion duration was shorten and the flame speed and laminar burning velocity had the highest value under the condition of an excess air ratio of 1.1, an overall charge pressure of 0.15 MPa and an ignition time of 300 ms in the present study. The $CO_2$ concentration was proportional to the ignition time and overall charge pressure, the $CO_2$ concentration was proportional to the excess air ratio, and the UHC concentration was inversely proportional to the ignition time and overall charge pressure.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 춘계학술대회
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• pp.2139-2144
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• 2003

In steel-making processes of iron and steel industry, the purity and quality of steel can be dependent on the amount of CO contained in the molten metal. Recently, the supersonic oxygen jet is being applied to the molten metal in the electric furnace and thus reduces the CO amount through the chemical reactions between the oxygen jet and molten metal, leading to a better quality of steel. In this application, the supersonic oxygen jet is limited in the distance over which the supersonic velocity is maintained. In order to get longer supersonic jet propagation into the molten metal, a supersonic coherent jet is suggested as one of the alternatives which are applicable to the electric furnace system. It has a flame around the conventional supersonic jet and thus the entrainment effect of the surrounding gas into the supersonic jet is reduced, leading to a longer propagation of the supersonic jet. The objective of the present study is to investigate the supersonic coherent jet flow. A computational study is carried out to solve the compressible, axisymmetric Navier-Stokes equations. The computational results of the supersonic coherent jet are compared with the conventional supersonic jet.