• 제목/요약/키워드: fixed bed

검색결과 516건 처리시간 0.025초

Dechlorination of High Concentrations of Tetrachloroethylene Using a Fixed-bed Reactor

  • Chang, Young-C.;Park, Chan-Koo;Jung, Kweon;Kikuchi, Shintaro
    • 한국환경보건학회지
    • /
    • 제36권4호
    • /
    • pp.323-336
    • /
    • 2010
  • We evaluated the properties of a fixed-bed column reactor for high-concentration tetrachloroethylene (PCE) removal. The anaerobic bacterium Clostridium bifermentans DPH-1 was able to dechlorinate PCE to cis-1,2-dichloroethylene (cDCE) via trichloroethylene (TCE) at high rates in the monoculture biofilm of an upflow fixed-bed column reactor. The first-order reaction rate of C. bifermentans DPH-1 was relatively high at $0.006\;mg\;protein^{-1}{\cdot}l{\cdot}h^{-1}$, and comparable to rates obtained by others. When we gradually raised the influent PCE concentration from $30\;{\mu}M$ to $905\;{\mu}M$, the degree of PCE dechlorination rose to over 99% during the operation period of 2,000 h. In order to maintain efficiency of transformation of PCE in this reactor system, more than 6 h hydraulic retention time (HRT) is required. The maximum volumetric dechlorination rate of PCE was determined to be $1,100\;{\mu}mol{\cdot}d^{-1}l$ of reactor $volume^{-1}$, which is relatively high compared to rates reported previously. The results of this study indicate that the PCE removal performance of this fixed-bed reactor immobilized mono-culture is comparable to that of a fixed-bed reactor mixture culture system. Furthermore, our system has the major advantage of a rapid (5 days) start-up time for the reactor. The flow characteristics of this reactor are intermediate between those of the plug-flow and complete-mix systems. Biotransformation of PCE into innocuous compounds is desirable; however, unfortunately cDCE, which is itself toxic, was the main product of PCE dechlorination in this reactor system. In order to establish a system for complete detoxification of PCE, co-immobilization of C. bifermentans DPH-1 with other bacteria that degrade cDCE aerobically or anaerobically to ethene or ethane may be effective.

패각 폐기물을 이용한 $H_2S$ 제거에 관한 연구(II) -고정층 반응기를 이용한 황화반응특성 (A Study on the H??S Removal with Utilization of Seashell Waste(II) - The Characteristics of Sulfided Reaction Using Fixed Bed Reactor-)

  • 김영식
    • 한국환경보건학회지
    • /
    • 제29권3호
    • /
    • pp.86-90
    • /
    • 2003
  • In this study, lots of methods have been studing to utilize energy and decrease contaminated effluents. There has been great progress on IGCC (Integrated gasification combined cycle) to reduce thermal energy losses. The following results have been conducted from desulfurization experiments using waste shell to remove H$_2$S. Fixed bed desulfurization experiments, to obtain basic data for scale-up was indicated. Oyster was the best among the various sorbents, like the results of TGA. Especially, H$_2$S removal efficiency of uncalcined oyster was the highest. When use oyster as desulfurization sorbents, calcination process was not needed. Thus, high desulfurization efficiency would be expected. Fixed bed reactor experiments were indicated particle size of sorbents. These had influenced on desulfurization capacity. As smaller particle size was found better desulfurization capacity. Large capacity difference was found between 0.613 mm and 0.335 mm. But, differences between 0.335 mm and 0.241 mm was relatively small. As bed temperature increased, H$_2$S removal capacity increased. Therefore, both particle size and bed temperature should be considered to remove H$_2$S by sorbents.

유동층 반응기에서 하수슬러지의 건조 및 탄화 특성에 관한 연구 (A Study on the Drying and Carbonization of Sewage Sludge in Fluidized Bed Reactor)

  • 정영헌;조기철;강동효;김이광;박창웅;오광중
    • 대한환경공학회지
    • /
    • 제28권7호
    • /
    • pp.746-751
    • /
    • 2006
  • 본 연구에서는 유동층 반응기에서 하수슬러지의 반응온도, 함수율, 입자크기, 가스유속에 따른 건조 및 탄화에 의한 열중량 변화를 관찰하였고 고정층 반응기에서의 결과와 비교하였다. 그 결과, 하수슬러지의 건조시 유동층을 이용한 건조는 고정층의 경우보다 약 6배 건조효율이 증가하였고, 탄화시 유동층을 이용한 경우가 고정층보다 약 4배 빠른 것으로 나타났으며, 슬러지는 약 10분 이내에 유동층 탄화가 완료되는 것으로 판단되었다. 또한, 탄화온도가 증가할수록 탄화물의 양은 감소되나, 873K 이상에서는 탄화물의 양이 유사하였으며, 유속이 증가함에 따라 잔류고형물이 감소하므로 하수슬러지는 873K 유동층 탄화시 유동화 유속범위내에서 저속 유동을 유지하는 것이 효율적인 것으로 판단되었다.

일정 답압시 보도블럭포장재 하부 토양물리성의 변화가 조경수 생육에 미치는 영향 - 포설모레 두께 및 립경을 실험변이 인자로 설정하여 - (The Effect on the growth of landscaping trees by fixed trampling in brick paved under-surface soil physical properties -Sand bed's thickness & prticle size were setted by experimental variable factors)

  • 조재현
    • 한국조경학회지
    • /
    • 제25권2호
    • /
    • pp.94-103
    • /
    • 1997
  • The purpose of this study is to find out the effects of brick paved under-surface soil physical properties which are changed by fixed trampling. Thus, a sandy loam which is known as a profitable soil for plants is used an experimental soil to study the changes of the soil physical properties. It is related to sand bed's thickness & particle size which are settled by experimental variable factors. According to the variation of sand bed's particle size, bulk density and soil hardness at natural dryed soilcondition result in 0.075~2.00mm>2.00~5.00mm>2.00~8.00mm>5.00~8.00mm, and water content at natural dryed soil condition are observed being insensible change rate from the point that sand thickness is 30~40mm and more sand bed's thickness constructed by the variation of sand bed's thickness.

  • PDF

세라믹 담체를 이용한 안료폐수의 호기성처리 (Aerobic Treatment of Pigment Wastewater using Ceramic Support Carrier)

  • 박영식;안갑환
    • 한국환경과학회지
    • /
    • 제10권4호
    • /
    • pp.281-286
    • /
    • 2001
  • Wastewater from the pigment industry has high levels of organics and is known as hardly biodegradable. The objective of this study is to evaluate the applicability of aerobic fixed-bed boifilm reactor packed with ceramic support carrier for the pigment wastewater treatment. Orange 2(widely used azo pigment) adsorption experiment onto biofilm and activated sludge, and continuous treatment experiments were performed. In batch adsorption experiment, maximum adsorption quantity of biofilm was at least two times higher than that of activated sludge. In continuous experiment using aerobic fixed-bed biodilm reactor, the influent concentration of COD and Orange 2 were 75~500mg/${\ell}$(0.45~3.00kg COD/$m^3.day), 5~50mg/$\ell$(0.03~0.30kg Orange 2/$m^3$.day), respectively. At a COD loading rate 2.5kg COD/$m^3$.day and Orange 2 loading rate of 0.18kg Orange 2/$m^3$.day, removal efficiency of COD and Orange 2 were over 95%, 97%, respectively.

  • PDF

Slaughterhouse wastewater treatment in a bamboo ring anaerobic fixed-bed reactor

  • Tritt, Wolfgang P.;Kang, Ho
    • Environmental Engineering Research
    • /
    • 제23권1호
    • /
    • pp.70-75
    • /
    • 2018
  • A pilot scale anaerobic fixed-bed with a reactor volume of $2.8m^3$ was built to treat slaughterhouse wastewater. Bamboo rings were chosen as support media mainly because of their cheaper price in underdeveloped countries. Even with their lower porosity and specific surface, the reactor performance showed a maximum 95% COD removal efficiency at an organic loading rate (OLR) of $1kg\;COD/m^3-d$ with its corresponding hydraulic retention time (HRT) of 7.5 d. At a higher OLR of $4.0kg\;COD/m^3-d$, the COD removal efficiency of 75% was achieved with an HRT of 2 d. No big difference in COD removal efficiencies was found between the reactors operated in both upflow and downflow modes. Their operational behavior and effluent characteristics were similar. The effluent COD/TKN ratio of 6.67 at an OLR of $4.0kg\;COD/m^3-d$ was only marginal acceptable range for a subsequent biological denitrification process. Otherwise carbon supplementation is required at a lower OLR.

공기의 온도와 수증기가 목재 톱밥의 가스화에 미치는 영향 (The effect of oxidizer temperature and steam addition on gasification in wood sawdust)

  • 안성율;최경민;김덕줄
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 2007년도 제34회 KOSCO SYMPOSIUM 논문집
    • /
    • pp.63-68
    • /
    • 2007
  • An experimental study was carried out to investigate gasification process of wood sawdust in the 1-dimensional downdraft fixed bed gasifier. The preheated air which was used oxidizer and steam were used as a gasifying agent. The downdraft fixed bed gasifier obtains more amount of hydrogen and methane by increasing residence time of supplied air. The operating parameters, the supplied air temperature and steam were used. The oxidizer temperature was varied from 500K to 620K and vapor was added. The gasification process was monitored by measuring temperature at three position near the biomass using R-type thermocouples and the syngas composition was analyzed by gas chromatograph. We get the sample gas at the end of gasifier and it was eonugh time to finishing the chemical reaction. Finally, the amount of hydrogen and methane were increased widely as increasing the oxidizer temperature and adding steam.

  • PDF

E.V.A., 고무폐기물 소각에 따른 폐가스 처리의 연구 (Combustion Characteristics of E.V.A., Rubber Waste Treatment by Fixed-Bed Incinerator.)

  • 배병훈;장성호;임경택
    • 한국환경과학회지
    • /
    • 제5권2호
    • /
    • pp.221-227
    • /
    • 1996
  • The objectives of this study are to examine combustion characteristics of E.V.A. and rubber wastes by fixed-bed incinerator, The results are as follows. Combustion temperature with time rises rapidly, and mass of E.V.A. reduces at short time in E.V.A. combustion. In variation of air-fuel ratio (m), ice ideal values of m of E.V.A. and rubber are 2.5, 1.5 respectively. Mixed-waste combustion is more economic than single E.V.A. combustion, because we can get high combustion efficiency (94.0~99.0%) at 2.0 air-fuel ratio of mixed-waste combustion. Removal efficiencies of SO2 at cooling tower are about 20%. The combustion efficiencies of rubber are over 98.0% according to the experimental conditions.

  • PDF

L자형 이동상수로에서 댐 붕괴파의 수치해석 (Numerical Analysis of Dam-break Waves in an L-shaped Channel with a Movable Bed)

  • 김대근;황건
    • 한국수자원학회논문집
    • /
    • 제45권3호
    • /
    • pp.291-300
    • /
    • 2012
  • 댐 붕괴 직후에 댐 붕괴 근역에서의 댐 붕괴파 및 댐 붕괴파로 인한 하상변동을 추적하기 위하여 RANS를 지배방정식으로 하는 FLOW-3D를 이용한 3차원 수치모의를 수행하였다. 특히 이동상에서의 하상변동과 그 하상변동으로 인한 홍수파의 변동을 고정상에서의 해석결과와 비교하였다. 그 해석 결과를 정리하면 다음과 같다. 첫째, L자형 실험수로에서의 홍수파 해석 및 이동상 실험수로에서의 홍수파와 하상변동 해석 결과는 해당 수리실험을 만족스럽게 재현하고 있다. 둘째, 부유사의 농도는 홍수파의 전면에서 가장 높은 값을 보이며, 하상침식은 흐름이 급변하는 댐 직하류 지점에서 가장 크게 발생한다. 수로의 상류에서 발생하는 부유사로 인해 하류에서는 침식과 퇴적이 번갈아서 발생한다. 홍수파가 도달하는 초기에는 L자형 만곡부의 내측에서 침식이 우세하게 발생하나, 시간이 지나며 침식은 점차 만곡부의 외측으로 이동하는 양상을 보인다. 셋째, L자형 이동상에서의 홍수파는 하상의 침식 및 퇴적으로 인해 고정상에서의 홍수파에 비해 그 전파가 지체되며 홍수위가 크게 상승한다.

유동층 반응기에서 합성가스 생성에 미치는 반응온도와 반응물 유속의 영향 (Effect of Temperature and Reactants Flow Rate on the Synthesis Gas Production in a Fixed Bed Reactor)

  • 김상범;김영국;황재영;김명수;박홍수;함현식
    • 한국응용과학기술학회지
    • /
    • 제21권3호
    • /
    • pp.225-230
    • /
    • 2004
  • Synthesis gas is a high valued compound as a basic chemicals at various chemical processes. Synthesis gas is mainly produced commercially by a steam reforming process. However, the process is highly endothermic so that the process is very energy-consuming process. Thus, this study was carried out to produce synthesis gas by the partial oxidation of methane to decrease the energy cost. The effects of reaction temperature and flow rate of reactants on the methane conversion, product selectivity, product ratio, and carbon deposition were investigated with 13wt% Ni/MgO catalyst in a fluidized bed reactor. With the fluidized bed reactor, $CH_4$ conversion was 91%, and Hz and CO selectivities were both 98% at 850$^{\circ}C$ and total flow rate of 100 mL/min. These values were higher than those of fixed bed reactor. From this result, we found that with the use of the fluidized bed reactor it was possible to avoid the disadvantage of fixed bed reactor (explosion) and increase the productivity of synthesis gas.