• Journal of Environmental Science International
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• v.13 no.12
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• pp.1067-1078
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• 2004

Atmospheric particulate matters were collected by 8-stage non viable cascade impactor from October 2002 to August at Jeju City. Eight water-soluble ionic components $(Na^+,\;NH_{4}_{+},\;K^+,\;Ca{2+},\;Mg^{2+},\;CI^-,\;NO_{3}^-\;and\;SO_{4}^{2-})$ were analyzed by Ion Chromatography. The concentration of particulate matters and eight water-soluble ionic components were determined to investigate their size distributions. Particulate matters exhibited a tri-modal distribution with peak value around $0.9,\;4.0{\mu}m\;and\;9.5{\mu}m.$ In summer, the last peak value was lower than other season values likely due to particulate matter scavenged by rain water. Four ionic components $(Na^+,\;Ca^{2+},\;Mg^{2+}\;and\;CI^-)$ exhibited a bi-modal distribution in the coarse mode whereas three ionic components $(NH_{4}^+,\;K^+\;and\;SO_{4}^{2-})$ in the fine mode, with maximum peak value around $0.9{\mu}m.\;NO_{3}^-$ was found in both the coarse and the fine mode. The enrichment factor (E.F.) of each ionic components was calculated. Based upon E.F., it is considered that $Na^+,\;CI^-,\;and\;K^+$ in coarse paricle mode were delivered form oceanic source, but other components might have other source origins.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.1
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• pp.131-140
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• 2005

To investigate secondary carbonaceous species within PM$_{10}$ and PM$_{2.5}$ in Seoul urban Metropolitan Area (SMA), Korea. atmospheric particulate matters samples were collected at two sites of SMA at UOS (The University Of Seoul station) sites and IHU (InHa University of Incheon station) during the period of 4 to 14 January and 12 to 22 May, 11 to 15 August 2004, and their characteristics were qualitatively discussed. during January and May and August of 2004. Daily average mass concentration 0.095 mg/㎥ in PM$_{10}$ and 0.053 mg/㎥ in PM$_{2.5}$ for mass respectively. were observed in SMA. The concentrations of carbonaceous species contributed 18.4% and 16.4% of PM$_{2.5}$ and PM$_{10}$ during the sampling period, respectively, of which OC accounted for 68% and 52% more of the total carbon (TC). OC and EC concentrations and their mass percentages were higher in PM$_{2.5}$ than in PM$_{10}$ which could be attributed to generation process. Organic aerosols would constitute up to 38% of PM$_{2.5}$ based on the evaluation of 1.6 for the ratio of OC to organic particulate. Secondary organic carbon (SOC) were estimated to be more than 13% and up to 68% of total OC based on the minimum OC/EC ratio of 1.06/1.11 using least square method. Comparisons of OC and EC with trace elements. As results of carbonaceous species analysis, the dominant factor in view of fine particle (PM$_{10}$/PM$_{2.5}$) is primary emission source such as mobile, fossil fuel combustion etc. during winter time in SMA. But in summer periods, remarkable fine particle increasing factor was secondary organic carbon dependent to photochemical reaction. reaction.n. reaction.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.E1
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• pp.15-28
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• 2004

To study the characteristics of ammonia and the related compounds, atmospheric aerosols and gases were collected using a triple filter pack sampler, a low volume air sampler, and a three-stage Anderson air sampler in Seoul and Kangwha Island, Korea from Dec. 1996 to Oct. 1997. Ammonia concentrations showed approximately two times higher in summer than in winter at both sites. The highest $HNO_3$ levels were generally observed in summertime at two sampling sites. The average mass concentration of $PM_{2.5}$ in heavily industrialized Seoul was about three times higher than that of Kangwha. In winter, the sum of $NH_4^+$ and its counter ions (such as $Cl^-,\;NO_3^-$, and $SO_4^{2-}$) comprised $30-41\%$ of $PM_{2.5}$ mass concentration at each sampling site. Temperature dependence of particulate nitrate was examined at the urban sampling site. The formation of the nitrate in the fine mode was dependent not only on the amount of precursors but also on the variation of temperature. $(NH_4)_2SO_4$ and $NH_4HSO_4$ coexisted with $NH_4NO_3$ and $NH_4Cl$ at each site. According to the summertime backward trajectory analysis, $NO_3^-$ showed higher level with air parcels transported from northeast Asian continent. On the other hand, the concentration of $SO_4^{2-}$ showed significantly higher level when air masses originated from Pacific Ocean, southern part of Japan, and Korea.

• Korean Journal of Environmental Biology
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• v.21 no.3
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• pp.240-244
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• 2003

Conidia of molds within the Asian dust were captured in the ambient air of mid-west Korea, in springtime of 2000~2002. An eight-stage Cascade impactor and 0.22 $\mu\textrm{m}$ pore size membrane filters were used for the dust samples. Several kinds of molds grown from the samples were identified to the genus level. Those are Aspergillus, Basipetospora, Epicoccum, Fusarium, Monotospora and Penicillium. Relatively diversified mycelia of hyphomycetes were grown on the fine dust sample (1.1~2.1 $\mu\textrm{m}$) in the first year Asian dust episode (23~24 March, 2000). On the other hand, some fluffy molds and dark molds aggregations were grown on even the backup particle sample less than 0.43 $\mu\textrm{m}$ during the second year episode (24~26 April, 2001). The result of the last year episode (21~22 March, 2002) showed various mycelia grown on the sample contained from 1.1 to 2.1 $\mu\textrm{m}$ sized particles, just like the result of the first year episode (23~24 March, 2000). These variations between the episodes might be caused by the difference of the dust origins.

• Atmosphere
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• v.27 no.4
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• pp.499-509
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• 2017

Possible links among cosmic ray, cloud, and climate have scientific uncertainties. The reputed topics have been highly controversial during several decades. A link between the atmospheric ionization by galactic cosmic rays (GCR), which is modulated by solar activities, and global cloud cover was firstly proposed in 1997. Some researchers suggested that the GCR can stimulate the formation of cloud condensation nuclei (CCN) in the atmosphere, and then the higher CCN concentrations may lead to an increase of cloud cover, resulting in a cooling of the Earth's climate, and vise versa. The CLOUD (Cosmic leaving outdoor droplets) experiment was designed to study the effect of GCR on the formation of atmospheric aerosols and clouds under precisely controlled laboratory conditions. A state-of-the-art chamber experiment has greatly advanced our scientific understanding of the aerosol formation in early stage and its nucleation processes if the GCR effect is considered or not. Many studies on the climate-GCR (or space weather) connection including the CLOUD experiment have been carried out during the several decades. Although it may not be easy to clarify the physical connection, the recent scientific approaches such as the laboratory experiments or modeling studies give some implications that the research definitively contributed to reduce the scientific uncertainties of natural and anthropogenic aerosol radiative forcing as well as to better understand the formation processes of fine particulate matters as an important parameter of air quality forecast.

• Journal of Environmental Health Sciences
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• v.22 no.3
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• pp.64-71
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• 1996

Measurement of concentration and size distribution of TSP, ammonium, nitrate and sulfate were made from Mar., 1991. to June., 1992 in Seoul. The seasonal variation of concentration and size distribution of aerosols has been investiated. Aerosol were collected and size frationated by Andersen air sampler. Size classified samples were extrated with deionized water and analyzed for ammonium, nitrate and sulfate by ion chromatography. As the results of measurement, the average of concentration and MMAD(mass median aerodynamic diameter) were $118.58 \mu g/m^3$, and $2.77 \mu m$ for TSP, $1.92 \mu g/m^3$ and $1.35 \mu m$ for ammonium, $1.34 \mu g/m^3$ and $1.58 \mu m$ for nitrate, $8.52 \mu g/m^3$ and $2.15 \mu m$ for sulfate. The Seasonal variation of concentration and size distribution was observed for ammonium, nitrate and sulfate. The concentration peak of TSP was observed in coarse particles in spring and observed in fine particles in winter. The concentration's distribution of TSP, ammonium, nitrate and sulfate was observed bimodal type during all season.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.1
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• pp.57-66
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• 2016

Aerosol optical thickness (AOT) and ${\AA}ngstr{\ddot{o}}m$ exponents were monitored at the KIU site ($N35.91^{\circ}$, $E128.80^{\circ}$) during the continuous observation period of 5 November 2010~19 March 2013 using a Microtops-II handheld munti-wavelenth radiometer. Comparisons of AOT values from the Microtops-II with the Sun-sky radiometer data from the Aerosol Robotic Network (AERONET) showed very good agreements: correlation coefficients are lies between 0.98 and 0.99, slopes range from 0.98 to 1.01, and intercepts are smaller than 0.008 at five wavelengths (380 nm, 440 nm, 500 nm, 675 nm, 870 nm). During the observation period, the Microtops-II AOT and ${\AA}ngstr{\ddot{o}}m$ exponents are ${\tau}_{500}=0.560{\pm}0.351$, ${\alpha}_{500-870}=1.135{\pm}0.445$. Fine mode aerosols appear to dominate in the study region with significant contributions from small particles.

• Proceedings of the KSRS Conference
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• 2007.10a
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• pp.57-60
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• 2007

Monthly mean data of ${\AA}ngstr{\ddot{o}}m$ exponent and Aerosol optical thickness (AOT) from Sea-viewing Wide Field-of-view Sensor (SeaWiFS) measurements over the East Asian waters were analyzed. Increasing trend of the satellite-derived ${\AA}ngstr{\ddot{o}}m$ exponent from 1998 to 2004 was found while AOT mean was observed stable during the same period. The trend of ${\AA}ngstr{\ddot{o}}m$ exponent is then interpreted as increase in fraction of small aerosol particles to give quantitative estimates on the variability of aerosols. The mean increase is evaluated to be $4{\sim}5%$ over the 7-year period in terms of the contribution of small particles to the total AOT, or sub-micron fraction (SMF). Possibilities of the observed trend arising from the sensor calibration or algorithm performance are carefully checked, which confirm our belief that this observed trend is rather a real fact than an artifact due to data processing. Another time series of SMF data (2000-2005) estimated from the fine-mode fraction (FMF) of Moderate Resolution Imaging Spectroradiometer (MODIS) supports this observation yet with different calibration system and retrieval algorithms.

• Current Optics and Photonics
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• v.2 no.2
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• pp.119-124
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• 2018

The errors in retrieved aerosol backscattering coefficients due to different lidar ratios are analyzed quantitatively in this paper. The actual calculation shows that the inversion error of the aerosol backscattering coefficients using the Fernald backward-integration method increases with increasing inversion distance. The greater the error in the lidar ratio, the faster the error in the aerosol backscattering coefficient increases. For the same error in lidar ratio, the smaller actual aerosol backscattering coefficient will get the larger relative error of the retrieved aerosol backscattering coefficient. The errors in the lidar ratios for dust or the cirrus layer have great impact on the retrievals of backscattering coefficients. The interval between the retrieved height and the reference range is one of the important factors for the derived error in the aerosol backscattering coefficient, which is revealed quantitatively for the first time in this paper. The conclusions of this article can provide a basis for error estimation in retrieved backscattering coefficients of background aerosols, dust and cirrus layer. The errors in the lidar ratio of an aerosol layer influence the retrievals of backscattering coefficients for the aerosol layer below it.

• Analytical Science and Technology
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• v.23 no.4
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• pp.371-382
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• 2010

TSP and PM2.5 atmospheric aerosols have been collected at Gosan site of Jeju Island, and their compositions were analyzed to understand the pollution characteristics. The composition ratios of nss (non-sea salt)-$SO_4^{2-}$ and $NH_4^+$ were higher in Gosan site than those in other Korean background and urban sites. However the composition ratio of $NO_3^-$ was conversely lower in Gosan site. From the study of aerosol components according to particle sizes, the anthropogenic nss-$SO_4^{2-}$, $NO_3^-$ and $NH_4^+$ components were mostly existed in the fine particles. But the nss-$Ca^{2+}$, $Na^+$, $Cl^-$ and $Mg^{2+}$ originated from soil and marine sources were distributed relatively in the coarse particles. In the seasonal comparison, the concentrations of nss-$Ca^{2+}$, Al, Fe, Ca and $NO_3^-$ increased in spring season, and nss-$SO_4^{2-}$ showed higher concentration in summer and spring seasons. Based on the factor analysis, the atmospheric aerosols in Gosan site have been found to be influenced largely by anthropogenic sources, and next by marine and soil sources. The backward trajectory analyses showed that the concentrations of nss-$SO_4^{2-}$, $NO_3^-$, Pb and nss-$Ca^{2+}$ increased when the air mass moved from Chinese continent to Jeju area. On the other hand, their concentrations decreased when the air mass moved in from the North Pacific Ocean.