• Title/Summary/Keyword: fibrous form

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Effects of binary conductive additives on electrochemical performance of a sheet-type composite cathode with different weight ratios of LiNi0.6Co0.2Mn0.2O2 in all-solid-state lithium batteries

  • Ann, Jiu;Choi, Sunho;Do, Jiyae;Lim, Seungwoo;Shin, Dongwook
    • Journal of Ceramic Processing Research
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    • v.19 no.5
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    • pp.413-418
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    • 2018
  • All-solid-state lithium batteries (ASSBs) using inorganic sulfide-based solid electrolytes are considered prospective alternatives to existing liquid electrolyte-based batteries owing to benefits such as non-flammability. However, it is difficult to form a favorable solid-solid interface among electrode constituents because all the constituents are solid particles. It is important to form an effective electron conduction network in composite cathode while increasing utilization of active materials and not blocking the lithium ion path, resulting in excellent cell performance. In this study, a mixture of fibrous VGCF and spherical nano-sized Super P was used to improve rate performance by fabricating valid conduction paths in composite cathodes. Then, composite cathodes of ASSBs containing 70% and 80% active materials ($LiNi_{0.6}Co_{0.2}Mn_{0.2}O_2$) were prepared by a solution-based process to achieve uniform dispersion of the electrode components in the slurry. We investigated the influence of binary carbon additives in the cathode of all-solid-state batteries to improve rate performance by constructing an effective electron conduction network.

A Study on the typological characters and the expressive modalities of the architecture of 'the natural construction' of Frei Otto (프라이 오토의 '자연적 구조' 건축의 유형적 특성과 표현양태에 관한 연구)

  • Lee, Ran-Pyo
    • Korean Institute of Interior Design Journal
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    • v.15 no.6 s.59
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    • pp.68-76
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    • 2006
  • Founding himself on 'The Principle of Self-making' that is the instrument of 'the natural construction' and accomplishing the various interdisciplinary researches, Frei Otto could explicate the fundamental structure of life that is able to make visible the self-making processes in the nature, the technique and the architecture. It is the flexible pneumatic construction that is grounded on the fibrous organization. This was a milestone not only for him who wanted to put the idea of the new architectural form into practice, but also for the contemporary architecture that faces on the style-pluralistic disorientedness. The architectural form of the natural construction includes in itself three constitutional sub-ideas. One of them is 'the adaptable architecture', which is inclined to the architecture similar to the organization of human body, and the other 'the light architecture' that is in the pursuit of the optimal form through the minimal material. The last one is 'the ecological architecture' that aims to realize the optimal dwelling environment based on the effective energy consumption by accumulating knowledges of the always fluid and unstable nature. With these architectural ideas Frei Otto could develop a new architectural form language 'the light architecture of the natural construction'. This study is purposed to explain the various experiments that were made by his team and the basic principles of the structural dynamics of 'the architecture of the natural construction' and then to analyze the structures that were built on the ground of those principles.

Studies on the Synthesis of Aminated PP-g-GMA Fibrous ion Exchanger by E-beam Pre-irradiation and Their Properties of Selective Adsorption for $NO_{3} ^{-}$ (E-beam 전조사에 의한 $NO_{3} ^{-}$ 선택 흡착용 아민화 PP-g-GMA 섬유 이온교환체의 합성과 그 특성에 관한 연구)

  • 황택성;이선아;이면주
    • Polymer(Korea)
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    • v.26 no.2
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    • pp.153-159
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    • 2002
  • In order to remove $NO_3;^-$ ion from ground-water, fibrous ion -exchangers, APP-g-GMA, were synthesized by GMA grafting onto PP trunk polymer with E-beam accelerator for pre-irradiation. Their degrees of grafting and amination yield increased up to $60^{\circ}C$ and showed maximum values as 133%, 88%, respectively. And their swelling ratio and ion exchange capacity at the maximum values are 86%, 2.5 meq/g, respectively which was higher than commercial ion-exchangers such as IMAC HP555 and Amberlite IRA 400. Optimum adsorption condition of $NO_3;^-$ ion was measured at pH 5~6 and -Cl form of APP-g-GMA containing trimethylammonium group showed the highest adsorption capacity.

Morphological Diversity of Tremolite-actinolite Series Amphiboles with Implications to the Evaluation of Naturally Occurring Asbestos (투각섬석-양기석 계열 각섬석의 형태적 다양성과 자연 석면 평가에서의 의미)

  • Jeong, Gi-Young;Choi, Jin-Beom
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.95-104
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    • 2012
  • Electron microscopy of the tremolite-actinolite series amphiboles from the naturally occurring asbestos locality showed the morphological diversity including fibrous, acicular, and prismatic. Very thin, long, and flexible fibers of constant width form ropy bundles or mats. Acicular particles are slightly thick, long, elastic, and easily separated from the bundle of parallel rods. Acicular fragments of lower aspect ratio are formed during the crushing of the amphibole prism. Morphological features of the amphiboles are different depending on their localities and vary in a specimen. Morphological continuum between amphibole fiber and prism requires the establishment of reliable identification criterions and sample preparation protocol based on the relation between carcinogenicity and morphological features.

Development of Medical Resorbable Composite Materials Interposed in the Poly(glycolic acid) (Poly(glycolic acid)를 심선에 지닌 의료용 흡수성 복합재료의 개발)

  • Lee, Chan-Woo
    • Polymer(Korea)
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    • v.31 no.3
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    • pp.228-232
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    • 2007
  • This purpose of this study is to enhance the hydrolysis of poly (butylene succinate-co-L-lactate) (PBSL) and poly [(R) -3-hydroxybutylate] (PHB), to develop materials with advanced medical absorbability and environmental suitability. The first method involves increasing the bioabsorbability of poly (glycolic acid) (PGA) in the core of the fibrous complex, while the second method involves making a complex fiber containing PBSL and PHB in the outer layer for improving environmental degradability Improvement in the hydrolysis of PBSL and PHB due to glycolic acid occurs by hydrolytic behavior of PGA. The drawing supporting the resulting PBSL/PGA fiber was executed at $65^{\circ}C$, where the orientation is well arranged in crystal form. Obtaining a PHB/PGA complex fiber in the proper crystal orientation at $50^{\circ}C$ was not possible since the arranged crystal orientation was only identified in drawings from temperatures above $50^{\circ}C$. Also, it is necessary to execute a smooth surface to achieve an on-line drawing since unevenness occurs in the fibrous surface from an in-line drawing.

Ammonia Removal Characteristics of Biolfilm Reactor (생물막을 이용한 상수 원수에서의 암모니아 제거 특성)

  • Shin, Hang-Sik;Lim, Kycong-Ho;Lee, Sang-Min
    • Journal of Korean Society of Water and Wastewater
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    • v.10 no.1
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    • pp.78-84
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    • 1996
  • The presence of ammonia, usually in the form of ammonium ion ($NH_4{^+}$), can enhance bacterial growth m the distribution system and make the production of drinking water more costly if ammonium must be removed to ensure good disinfection. Removal of ammonia by biological oxidation could be economical which prevents excess chlorine dosage In this research, effects of hydraulic retention time (HRT) and media type on the ammonia removal efficiencies of submerged biofilm reactor were investigated. The biofilm reactors combined the characteristics of high biological solids capture efficiency and good hydraulic control. The results indicate that biofilms can remove over 77 percent of the ammonia with HRT of longer than 2 hr even at low temperature ranging from 14.6 to $16.6^{\circ}C$. The HRT has a significant effect on nitrification. The overall nitrification and efficiency of ammonia removal increase with increasing HRT. It has also been observed that when the fibrous media was used, the ammonia removal, nitrification rate and endurance to shock improved.

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Biomimetic Electrospun Fibers for Tissue Engineering Applications

  • Sin, Heung-Su
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.2.2-2.2
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    • 2011
  • The central strategy in tissue engineering involves a biomaterial scaffold as a delivery carrier of cells and a depot to deliver bioactive molecules. The ability of scaffolds to control cellular response to direct particular repair and regeneration processes is essential to obtain functional tissue engineering constructs. Therefore, many efforts have been made to understand local interactions of cells with their extracellular matrix (ECM) microenvironment and exploit these interactions for designing an ideal scaffold mimicking the chemical, physiological, and structural features of native ECM. ECM is composed of a number of biomacromolecules including proteins, glycosaminoglycans, and proteoglycans, which are assembled together to form complex 3-dimensional network. Electrospinning is a process to generate highly porous 3-dimensional fibrous structure with nano to micro scaled-diameter, which can closely mimic the structure of ECM. In this presentation, our approaches to develop biomimetic electrospun fibers for modulation of cell function will be discussed.

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Mechanical Behavior of Shape Memory Fibers Spun from Nanoclay-Tethered Polyurethanes

  • Hong, Seok-Jin;Yu, Woong-Ryeol;Youk, Ji-Ho
    • Macromolecular Research
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    • v.16 no.7
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    • pp.644-650
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    • 2008
  • This study examined the effect of nanoclays on the shape memory behavior of polyurethane (PU) in fibrous form. A cation was introduced into the PU molecules to disperse the organo-nanoclay (MMT) into poly($\varepsilon$-caprolactone) (PCL)-based PU (PCL-PU). The MMT/PCL-PU nanocomposites were then spun into fibers through melt-processing. The shape memory performance of the spun fibers was examined using a variety of thermo-mechanical tests including a new method to determine the transition temperature of shape memory polymers. The MMTs showed an improved the fixity strain rate of the MMT /PCL- PU fibers but a slight decrease in their recovery strain rate. This was explained by the limited movement of PU molecules due to the presence of nanoclays. The shape memory performance of the MMT/PCL-PU fibers was not enhanced significantly by the nanoclays. However, their recovery power was improved significantly up to a strain of approximately 50%.

Forming Mechanism of TiC Hollow Fibers during Self-Propagating High Temperature Synthesis (자전연소합성 반응중 속빈 TiC 섬유의 형성 기구)

  • 윤존도;방환철
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.332-337
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    • 2000
  • Forming mechanism of fibrous TiC during self-propagating high temperature synthetic reaction was analyzed and suggested. It was revealed that critical temperature for the stable fiber formation was not the melting point of TiC, but the eutectic reaction temperature of TiC and C. Minimum amount of TiC diluent addition required to form fibers was calculated to be 25.6%, which was consistent with the experimental result. Synthesized fibers were found hollow tube-like. The morphology was explained by the diffusion rates of C and Ti in TiC, and by the molar volume chnage of C during the reaction. Expanding shell model was suggested for the hollow fiber formation mechanism.

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A Ultrastructural Study on the Axoneme Formation in the Spermatozoa of the Edible Giant Snail, Achatina fulica (식용 왕달팽이 (Achatina fulica) 정자의 축사형성 (Axoneme formation)에 관한 미세구조)

  • Chang, Nam-Sub
    • Applied Microscopy
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    • v.28 no.4
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    • pp.513-525
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    • 1998
  • The spermatogenetic process in the edible giant snail is similar to those in the other snails, except for the axoneme formation process. In this study, the axoneme formation process in the giant snail was mainly examined by means of electron microscopy. The tail portion of a spermatozoon is about $160{\mu}m$ long, and extends straight to the rear, surrounded by two large and long mitochondria in spiral forms. A number of glycogen particles $(40\sim70nm)$ are found in the swollen matrix of the mitochodria. The axoneme which composes the tail of a spermatozoon is surrounded by $7\sim10$ lamella-form fibrous sheaths of about $0.2{\mu}m$ in thickness. Most of the mature spermatozoa are found to be clustered into a group of $5\sim7$ ea in syncytial bridges formed by cytoplasmic processes. Sertoli cells contain glycogen particles, endoplasmic reticulum, a lot of mitochondria, and lipids in their cytoplasm. They protrude their filiform pseudopodia and phagocytize abnormal spermatids or spermaozoa.

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