• Title/Summary/Keyword: evaporation characteristics

Search Result 926, Processing Time 0.035 seconds

Studies on the Optical and the Electrical Characterization of Organic Electroluminescence Devices of Europium Complex Fabricated with PVD(Physical Vopor Deposition) Technique (진공 증착법에 의하여 제작한 Europium complex 유기 박막 전기발광소자의 광학적.전기적 특성에 관한 연구.)

  • Lee, Myeong-Ho;Lee, Han-Seong;Kim, Yeong-Gwan;Kim, Jeong-Su
    • The Transactions of the Korean Institute of Electrical Engineers C
    • /
    • v.48 no.5
    • /
    • pp.285-295
    • /
    • 1999
  • Electroluminescent(EL) devices based on organic materials have been of great interest due to their possible applications for large-area flat-panel displays. They are attractive because of their capability of multi-color emission, and low operation voltage. An approach to realize such device characteristics is to use active layers of lanthanide complexes with their inherent extremely sharp emission bands in stead of commonly known organic dyes. In general, organic molecular compounds show emission due to their $\pi$-$\pi*$ transitions resulting in luminescence bandwidths of about 80 to 100nm. Spin statistic estimations lead to an internal quantum efficiency of dye-based EL devices limited to 25%. On the contrary, the fluorescence of lanthanide complexes is based on an intramolecular energy transfer from the triplet of the organic ligand to the 4f energy states of the ion. Therefore, theoretical internal quantum efficiency is principally not limited. In this study, Powders of TPD, $Eu(TTA)_3(phen) and AlQ_3$ in a boat were subsequently heated to their sublimation temperatures to obtain the growth rates of 0.2~0.3nm/s. Organic electrolumnescent devices(OELD) with a structure of $glass substrate/ITO/Eu(TTA)_3(phen)/AI, glass substrate/ITO/TPD/Eu(TTA)_3(phen)/AI and glass substrate/ITO/TPD/Eu(TTA)_3(phen)/AIQ_3AI$ structures were fabricated by vacuum evaporation method, where aromatic diamine(TPD) was used as a hole transporting material, $Eu(TTA)_3(phen)$ as an emitting material, and Tris(8-hydroxyquinoline)Aluminum$(AlQ_3)$ as an electron transporting layer. Electroluminescent(EL) and current density-voltage(J-V) characteristics of these OELDs with various thickness of $Eu(TTA)_3(phen)$ layer were investigated. The triple-layer structure devices show the red EL spectrum at the wavelength of 613nm, which is almost the same as the photoluminescent(PL) spectrum of $Eu(TTA)_3(phen)$.It was found from the J-V characteristics of these devices that the current density is not dependent on the applied field, but on the electric field.

  • PDF

Combustion Characteristics of Bio Emulsion Fuel (바이오에멀젼 연료의 연소 특성)

  • Kim, Moon-Chan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.35 no.4
    • /
    • pp.1421-1432
    • /
    • 2018
  • Water soluble oil was obtained from the pyrolysis of coconut waste as a biomass at $600^{\circ}C$. It was studied that the combustion characteristics of bio-emulsion fuel by mixing and emulsifying 15~20% of water soluble oil which obtained from pyrolysis of coconut waste as a biomass and MDO(marine diesel oil) as a marine fuel. Engine dynamometer was used for detecting emissions, temperature, and power. The temperature of combustion chamber was decreased because the moisture in bio-emulsion fuel deprived of heat of evaporation in combustion chamber. While combustion, micro-explosion took place in the combustion chamber by water in the bio-emulsion fuel, MDO fuel scattered to micro particles and it caused to smoke reduction. The temperature reduction of combustion chamber by using bio-emulsion fuel reduced the NOx emission. The increasing of bio-oil content caused increasing water content in bio-emulsion fuel so total calorific value was reduced. So the characteristics of power was decreased in proportion to using the increasing amount of bio-emulsion fuel. Heavy oil as a marine fuel exhausts a lot of smoke and NOx. We expect that we can reduce the exhaust gas of marine engine such as smoke and NOx by using of bio-emulsion fuel as a marine fuel.

Analysis of Secondary School Students' System Thinking on the Cycle of Matter in Earth System: Considering the Impact of Human Activity on the Cycle (지구 시스템 내 물질 순환에 대한 중·고등학교 학생들의 시스템 사고 분석: 인간의 활동이 순환에 미치는 영향을 고려하여)

  • Oh, Hyunseok;Lee, Kiyoung;Kim, Kwonjung
    • Journal of Science Education
    • /
    • v.45 no.3
    • /
    • pp.275-291
    • /
    • 2021
  • The purpose of this study is to analyze the level and characteristics of system thinking of middle and high school students on cycle of matter in the Earth system considering the impact of human activities on the cycle. For this purpose, we developed items for assessment and assessment rubric through the analysis of 2015 revised curriculum and applying systems thinking, respectively. Middle and high school students who participated in the Korea Earth Science Olympiad were the subjects of this study. The level of system thinking was determined using the assessment rubric for student responses collected using items for assessment. The characteristics of system thinking were identified using word analysis. Based on these, the improvement of the curriculum considering the impact of human activities was discussed. The results of the study are as follows: first, the system thinking level of most secondary school students was low in identifying or classifying system elements for matter cycle, and high levels, such as system relationship or generalization of patterns, were found to be relatively small. It was found that students had a higher level of system thinking in the carbon cycle than in the water cycle. Second, in terms of the characteristics of system thinking about water cycle, water was recognized as a major system element and mainly related with evaporation between atmosphere and other system elements. Whereas, in the carbon cycle, carbon dioxide was regarded as a major system element, and photosynthesis and respiration were represented in relation with the biosphere. Third, for education considering the impact of human activities on the matter cycle in the Earth system, it is proposed improving the curriculum considering the socio-ecological system by extending the existing earth system.

A study on changes in water cycle characteristics of university campus catchment: focusing on potential evapotranspiration improvement in Mt. Gwanak catchment (대학 캠퍼스 유역의 물순환 특성 변화에 관한 연구: 관악산 유역 잠재증발산량 개선을 중심으로)

  • Kim, Hyeonju;Kim, Young-Oh
    • Journal of Korea Water Resources Association
    • /
    • v.55 no.12
    • /
    • pp.1077-1089
    • /
    • 2022
  • With the construction of Seoul National University (SNU), the Mt. Gwanak watershed has undergone some urbanization. As with other campus catchments, data related to the water cycle is extremely limited. Therefore, this study began by collecting hydrological and meteorological data using Atmos-41, a complex meteorological observation instrument. The observation results of Atmos-41 were validated by analyzing the statistical characteristics and confidence intervals based on the monthly variability of data from the Korea Meteorological Administration. Results of the previous research were used to validate the simulated surface runoff and infiltration using the Storm Water Management Model (SWMM). The potential evapotranspiration (PET) simulated by the SWMM was rectified by comparing it to the Atmos-41 observation data. Multiple regression analysis was employed to adjust for the fluctuations in precipitation, relative humidity, and wind speed because the calculated SWMM PET tends to be underestimated during periods of low temperatures. R2 increased from 0.54 to 0.80 when compared to the Atmos-41 PET. The rate of change in the water cycle as a consequence of the SNU's construction resulted in a 15.7% increase in surface runoff, a 14.2% decrease in infiltration rate, and a 1.6% decrease in evaporation.

A Study on Heat Transfer and Pressure Drop in Flow Boiling of Binary Mixtures in a Uniformly Heated Horizontal Tube (균일하게 가열되는 수평전열관내 냉매의 유동 비등열 전달과 압력 강하 특성에 관한 연구)

  • LIM, Tae-Woo;PARK, Jong-Un;KIM, Jun-Hyo
    • Journal of Fisheries and Marine Sciences Education
    • /
    • v.14 no.2
    • /
    • pp.177-190
    • /
    • 2002
  • An experimental study was carried out to make clear heat transfer characteristics in flow boiling of binary mixtures of refrigerants R134a and R123 in a uniformly heated horizontal tube. Experiments were run at a pressure of 0.6 MPa both for pure fluids and mixtures in the ranges of heat flux $10{\sim}50{kW/m}^2$, vapor quality 0~100% and mass flux 150-600 $kg/m^2s$. Heat transfer coefficients of mixtures were reduced compared to the interpolated values between pure fluids both in the low quality region where the nucleate boiling is dominant and in the high quality region where the convective evaporation is dominant. Total pressure drop during two-phase flow boiling in a horizontal tube consists of the sum of two components, that is, the frictional pressure drop and pressure drop due to acceleration. The frictional pressure drop is the most difficult component to predict, and makes the most important contribution to the total pressure drop. On the other hand, the acceleration pressure drop resulting from the variation of the momentum flux caused by phase change is generally small as compared to the frictional pressure drop. There is no significant difference in measured pressure drop between mixtures and pure fluids. The correlation of Martinelli and Nelson predicted most of the present data both for pure and mixed refrigerants within 30%.

Analysis of Fire Suppression Efficiency for Intermittent Water Spray Pattern by Fire Dynamics Simulator (FDS를 이용한 교번식 미분무방식의 소화 성능 분석)

  • Jee, Moon-Hak;Lee, Byung-Kon
    • Fire Science and Engineering
    • /
    • v.22 no.3
    • /
    • pp.216-220
    • /
    • 2008
  • Water mist fire suppression system utilizes the fire suppression features such as cooling of fire source, dilution of ambient oxygen, and shielding of radiation heat with the evaporation of microscopic water droplets. The momentum of water mist is relatively lower than that of larger water droplet and the infiltration of water mist to the fire source is not effective. Contribution of evaporated water vapor is liable to decline to limited portion of fire source due to its light weight and sparse density. On the other hand, the cycling water mist pattern is expected to improve the penetration force of water mist as well as the air expelling capability with the stratified spray characteristics. At this paper, we present the analyzed fire suppression capability of intermittent water spray pattern by use of FDS which is computational fire dynamics fire model. We expect this analysis can support the basic concept to the development of the prototype of water mist nozzle.

Preparation and Photo Conducting Characteristics of Plasma Polymerized Organic Photorecepter (플라즈마 중합법에 의한 유기 감광체 박막의 제조와 광전도 특성)

  • 박구범
    • Journal of the Korean Institute of Telematics and Electronics T
    • /
    • v.36T no.3
    • /
    • pp.19-25
    • /
    • 1999
  • The photoreceptor films with double layer structure were prepared by the plasma polymerization and the dip-coating method. The blocking layer was coated with A1$_2$O$_3$ on the Al substrate and the charge generation layer was formed by H$_2$ phthalocyanine (H$_2$Pc). Poly 9-Vinylcarbazole was used as a charge transport layer. H$_2$Pc film prepared by the vacuum evaporation had absorption peaks on 613.6[nm] and 694.8[nm], and H$_2$Pc film prepared by the plasma polymerization had a dull peaks between 600 and 700[nm]. The surface potential of PVCz increased with increasing the applied voltage and the thickness of PVCz. The dark decay characteristic, the light decay time and the residual time increased with increasing the thickness of PVCz. The surface charge of PVCz of 15[${\mu}{\textrm}{m}$] thickness was 134[nc/$\textrm{cm}^2$] at the surface potential of -600[V] and the charge generation efficiency of H$_2$Pc was 0.034.

  • PDF

Study on characteristics of p-GaN ohmic contacts by rapid thermal annealing (열처리에 따른 p-GaN의 오믹접촉 특성에 관한 연구)

  • Kim, D.S.;Lee, S.J.;Seong, K.S.;Kang, Y.M.;Cha, J.H.;Kim, N.H.;Jung, W.;Cho, H.Y.;Kang, T.W.;Kim, D.Y.;Lee, Y.H.
    • Proceedings of the IEEK Conference
    • /
    • 2000.06b
    • /
    • pp.310-313
    • /
    • 2000
  • In this study, the Au/Ni and Au/Ni/Si/Ni layers prepared by electron beam evaporation were used to form ohmic contacts on p-type GaN. Before rapid thermal annealing, the current-voltage(I-V) characteristic of Au/Ni and Au/Ni/Si/Ni contact on p-type GaN film shows non-ohmic behavior. A Specific contact resistance as 3.4$\times$10$^{-4}$ Ω-$\textrm{cm}^2$ was obtained after 45$0^{\circ}C$-RTA. The Schottky barrier height reduction may be attributed to the presence of Ga-Ni and Ga-Au compounds, such as Ga$_4$Ni$_3$, Ga$_4$Ni$_3$, and GaAu$_2$ at the metal - semiconductor interface. The mixing behaviors of both Ni and Au have been studied by using X-ray photoelectron spectroscopy. In addition, X-ray diffraction measurements indicate that the Ni$_3$N, NiGa$_4$, Ni$_2$Si, and Ni$_3$Si$_2$ Compounds were formed at the metal-semiconductor interface.

  • PDF

SiC(3C)/Si Photodetector (SiC(3C)/Si 수광소자)

  • 박국상;남기석;김정윤
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.9 no.2
    • /
    • pp.212-216
    • /
    • 1999
  • SiC(3C) photodiodes (PDs) were fabricated on p-type Si(111) substrates using chemical vapor deposition (CVD) technique by pyrolyzing tetramethylsilane (TMS) with $H_{2}$ carrier gas. Electrical properties of SiC(3C) were investigated by Hall measurement and current-voltage (I-V) characteristics. SiC(3C) layers exhibited n-type conductivity. Ohmic contact was formed by thermal evaporation Al metal through a shadow-mask. The optical gain $(G_{op})$ of the SiC(3C)/Si PD was measured as a function of the incident wavelength. For the analysis of the photovoltaic detection of the Sic(3C) n/p PD, the spectral response (SR) has calculated by using the electrical parameters of the SiC(3C) layer and the geometric structure of the PD. The peak response calculated for properly chosen parameters was about 0.75 near 550 nm. We expect a good photoresponse in the SiC(3C) heterostructure for the wavelength range of 400~600 nm. The SiC(3C) photodiode can detect blue and near ultraviolet (UV) radiation.

  • PDF

Aroma Characteristics of Acai Berry (아사이베리의 향기성분 특성 연구)

  • Lim, Seung-Hee;Nam, Heesop;Baek, Hyung-Hee
    • Korean Journal of Food Science and Technology
    • /
    • v.48 no.2
    • /
    • pp.122-127
    • /
    • 2016
  • The objective of this study was to identify the volatile compounds and aroma-active compounds from acai berry (Euterpe oleracea). Volatiles were isolated by high vacuum distillation using solvent-assisted flavor evaporation (SAFE) and liquid-liquid continuous extraction (LLCE). To identify the characteristic aroma-active compounds of acai berry, gas chromatography-mass spectrometry-olfactometry was used. Aroma-active compounds were evaluated by aroma extract dilution analysis (AEDA). A total of 51 and 54 volatile compounds from acai berry were identified from SAFE and LLCE extracts, respectively. Alcohols were confirmed to be important volatile compounds in acai berry, as the major volatile compounds were 2-phenylethanol, (Z)-3-hexenol, and benzyl alcohol. ${\beta}-Damascenone$ (berry, rose), trans-linalool oxide (woody), (Z)-3-hexenol (grass), and 2-phenylethanol (rose, honey) were considered the aroma-active compounds in acai berry. The most intense aroma-active compound of acai berry was ${\beta}-damascenone$.