• Title/Summary/Keyword: environmental tracer

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Characteristic Distributions of Hydrogen Peroxide and Methyl Hydroperoxide and over the North Pacific Ocean

  • Lee, Meehye;Brian G. Heikes
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.E2
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    • pp.85-95
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    • 2002
  • Hydrogen peroxide and methyl hydroperoxide were measured over the northwestern Pacific Ocean during NASA's PEM (Pacific Exploratory Mission) -West. The first experiment (PEM -West A) was conducted in the fall of 1991 and PEM-West B in the early spring of 1994. Hydroperoxide data were obtained on board the NASA DC -8 aircraft through the entire depth of the troposphere. Average concentrations of both H$_2$O$_2$and CH$_3$OOH were higher during PEM -West A than B. The seasonal difference in hydroperoxide distribution was determined by the degree of photochemical activities and the strength and location of jetstream, which led to extensive and rapid continental outflow during the PEM-West B. While for H$_2$O$_2$distribution, a longitudinal gradient was more apparent than a latitudinal gradient, it was opposite for the CH$_3$OOH distribution. The longitudinal gradient indicates the proximity to the anthropogenic sources from the Asian continent, but the latitudinal gradient reflects photochemical activity. During PEM -West B, the ratio of C$_2$H$_2$/CO, a tracer for continental emission was raised and high concentrations of H$_2$O$_2$were associated with high ratios. The flux of hydroperoxide toward the North Pacific was also enhanced in the early spring. The eastward fluxes of H$_2$O$_2$ were 9% and 17% of the average photochemical production over the Pacific Basin between 140°E and 130°W during PEM-West A and B, respectively. For CH$_3$OOH, these ratios were 8% and 13%. Considering the lifetime of hydroperoxide and the rapid transport of pollutants, the export of hydroperoxide with other oxidants would have a significant influence on oxidant cycles over the North Pacific during winter/spring.

Hydrographic Analysis of Surface Water Using Radium Isotopes Signature in the East and South China Sea in Summer (여름철 동중국해 및 남중국해 표층수의 Ra 동위원소를 이용한 수계분석)

  • Yang, Han-Soeb;Lee, Tong-Sup
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.4 no.4
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    • pp.305-311
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    • 1999
  • This study aims to decipher surface water mass interaction in summer in the South China Sea and East China Sea by radium isotope distribution pattern. Salinity and activity ratio of radium ($^{228}Ra/^{226}Ra$) showed gradual changes, which were adequate to apply simple two end-member mixing between Kuroshio surface water and Changjiang Dilute Water for the East China Sea and the former and Nearshore Diluted Watermass (NDW) for the South China Sea. Two tracer methods, salinity and Ra isotope ratio, were compared for East China Sea. Results showed remarkable consistency for waters near Kuroshio, however, discrepancy were noticeable after Tsushima Warm Current branching. Mixing with subsurface waters may cause the discrepancy. When mixed with subsurface waters, salts and radium isotope ratio are expected to be biased in opposite direction, i. e. prone to underestimate the fraction of less saline water in the case of salts and vice versa for Ra isotope ratio. Taking the mean values of two different results seems more realistic to estimate fraction of end-members.

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Comparative Study on Efficiencies of Naturally-Ventilated Multi-Span Greenhouses in Korea (다연동 온실의 자연환기효율성 비교 분석)

  • Kwon, Soon-Hong;Jung, Sung-Won;Kwon, Soon-Gu;Park, Jong-Min;Choi, Won-Sik;Kim, Jong-Soon
    • Journal of the Korean Society of Industry Convergence
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    • v.20 no.1
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    • pp.8-18
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    • 2017
  • This research analyzed the ventilation effect of the multi-span greenhouse based on the types of greenhouse structure, weather conditions, and locations inside the greenhouse. To compare and analyze the ventilation effects with different types of greenhouse, the uniform environmental conditions should be selected in advance. But these factors are not controlled and require tense many precision facilities and labor forces. Thus, the CFD simulation was used for the air stream to be analyzed qualitatively and quantitatively. In addition, for the ventilation effect analysis, the TGD (Tracer Gas Decay) was used to overcome the shortcomings of the current ventilation measurement method. The calculation error of ventilation rate using TGD was low (10.5%). Thus, the TGD is very effective in calculating the ventilation efficiency. The wind direction of 90 degrees showed the best ventilation effect. The ventilation rate also decreased along the air circulation path, and the rate was the lowest around the outlet. The computed fluid method (CFD) turned out to be a power tool for simulating flow behavior in greenhouse.

A Study of Hydrogeological Properties Concerning to Groundwater Interference between Wells in the Yeongdo Island, Pusan, Korea (부산직할시 영도지역의 정호간 지하수 간섭에 관한 수리지질 특성 연구)

  • 김항묵
    • Journal of the Korean Professional Engineers Association
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    • v.27 no.6
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    • pp.72-84
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    • 1994
  • This is about an environmental study of groundwater interference by hydrodynamic dispersion between the well A and well C in Dongsam-dong, the Yeongdo Island, Pusan, Korea. The groundwater in the study wells come from the fracture zones deeply seated in welded lapilli rhyodacitic tuff of the Late Cretaceous Yucheon Group. The boring depth at the well A is 190 meters, and the optimal pumping rate of the well A is about 100 cubic meters per day therein. The fractured aquifers in impermeable welded tuff show the conjugate fracturing type and are of anisotropic. The aquifers along two fracture zones in the well A are 80 and 100 meters in depth, respectively. It is not suggested that those fractured aquifers are simply connected between the well A and C. The sea level fluctuation by ebb and high tides in a day is not effective to the groundwater table in the well A. The pumping for 15 days at the well A doesn't give rise to any changes of the groundwater levels in the neighbor well C. The radius of influence of the well A is measured as less than 200 meters. The measuring electric conductivity for the test of salt tracer doesn't testify any relationship between the well A and the well C. There is the main difference between the well A and the well C on the basis of the water analysis of those wells. the well A is located in the high content zone of salt much over the standard value for drinking, whereas the other wells B. C. D are in the low content area of salt below the standard value. It is elucidated for the high content zone of salt in Yeongdo around the well A to have been uplifted over 20 meters.

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A Study on the Kinetics of a Pasked Bed Aerobic Biofilm Rrocess (충전상(充塡床) 호기성(好氣性) 생물막공법(生物膜工法)의 반응속도론(反應速度論)에 관한 연구(研究))

  • Cho, Kwang Myeung;Jeong, Jae Kee;Son, Jong Sik
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.45-53
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    • 1987
  • The purpose of this research was to study the kinetics of a packed bed aerobic biofilm process. Experiments were carried out by feeding an aerated packed bed reactor with a synthetic wastewater. The reactor packed with glass beads as media had a nominal hydraulic detention time of 5 hours. The flow pattern in the reactor was determined by a tracer test using a NaCl solution to be a completely-mixed type. The results of the research showed that the F/M ratio in the reactor was almost constant since the the biomass increased due to the growth of biofilm as the volumetric organic loading increased. It was also proved theoretically and experimentally that packed bed aerobic biofilm process could be analyzed by the kinetics of completely-mixed activated sludge process with sludge recycle.

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Analysis of Correlation Between Wonhyo Tunnel(section of KTX line) Works and Swamp (경부고속철도 천성산구간 원효터널공사와 늪지와의 상관성 분석)

  • Ham, Dong-Sun;Kim, Byeong-Ho;Jeon, Byeong-Gyoo;Kim, In-Soo
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.1838-1844
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    • 2007
  • The Wonhyo Tunnel on KTX railroad line is a section of latest concerns from domestic environmental NGOs, which focus on potential destruction of ecosystem or the like due to ever-depleted swamp water at about 300m upward from the tunnel under construction. As a result of study, out of all swamps in the vicinity of the tunnel, it was found that Mujechi 1st and 2nd swamps have been getting smaller in their area little by little since 50 years ago primarily under the influence of eroded streams around lower swamp and even ever-increasing annual mean temperature. As the result of monitoring about swamp before work, it was found that swamp water depends absolutely on amount of rainfall. Besides, the results of monitoring during work also didn't show any leakage generated in the tunnel during and after excavation works with regard to a wheat field swamp in the most vicinity of the tunnel (80m away). On the other hand, it was found that the range affected by ground water sink in tunnel section without grouting process amounted to about 100m around the tunnel, which indicates that such ground water sink has no significant impact upon most of swamps near the tunnel. As the result of testing by two well tracer test around swamps, it was noted that swamp water didn't run out from the bottom of swamp even with adjacent ground water level sunk in factitious ways. And the results of physical survey showed that swamp kept saturated even in dry season when ground water level becomes lower than the bottom of swamp. Therefore, even supposing that ground water level becomes sunk due to tunnel works, it is estimated that the water level of swamps would be still kept owing to impervious layer(peat beds).

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On-offshore Distribution of Longshore Current in the Surf Zone (쇄파후(碎波後) 발생(發生)하는 연안류(沿岸流)의 유속분포(流速分布)에 관한 연구(研究))

  • Kim, Kyoung Ho;Koo, Bong Kuen
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.6 no.4
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    • pp.11-19
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    • 1986
  • This study aims at the elucidation of the distribution of longshore currents after wave breaking. Longshore currents have relations to the beach process and dispersion of contaminants in the nearshore region, thus the understanding of its. mechanism is very important. In the present study, using the electromagnetic current meter, the water particle velocity is measured in the 3-dimensional wave field and Eulerian mean velocity is obtained. At the same time, from the dispersion of tracer, the Lagrangian mean velocity is also obtained. It is observed that the longshore currents were confined within the surf zone and the maximum value of them exists in the surf zone. The longshore currents were considered to be constant toward the depth and we obtained the similar distribution of longshore currents between the measured value and the theoretical ones by Longuet-Higgins model.

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Control of Cyanobacteria (Microcystis aeruginosa) Blooms by Filter-feeder Bivalves (Unio douglasiae, Anodonata woodiana) : an In Situ Mesocosm Experiment using Stable Isotope Tracers (안정동위원소 추적자 실험을 통한 이매패류의 남조류 (Microcystis aeruginosa) 저감효과 평가)

  • Seo, Yeon-Ji;Kim, Min-Seob
    • Korean Journal of Ecology and Environment
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    • v.51 no.3
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    • pp.245-252
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    • 2018
  • Stable isotope tracers were first applied to evaluate the Microcystis cell assimilation efficiency of bivalves, since the past identification method has been limited to tracking the changes of each chl-a, clearity, and nutrient. The filter-feeders (Sinanodonta woodiana and Unio douglasiae) were assessed under the condition of cyanobacteria (Microcystis aeruginosa) blooms through an in mesocosm experiment using $^{13}C$ and $^{15}N$ dual isotope tracers. chl-a concentration in the treatment mesocosm was dramatically decreased after the beginning of the second day, ranging from 116 to $66{\mu}g\;L^{-1}$. In addition, the incorporated $^{13}C$ and $^{15}N$ atom % in the S. woodiana bivalve showed higher values than U. douglasiae bivalves. The results demonstrate that U. douglasiae has less capacity to assimilate toxic cyanobacteria derived from diet. Our results therefore also indicate that S. woodiana can eliminate the toxin more rapidly than U. douglasiae, having a larger detoxification capacity.

Evaluation of Ground-Water Sampling Techniques for Analysis of Chlorofluorocarbons (지하수의 CFCs(Chlorofluorocarbons) 조사를 위한 시료 채취 방법의 평가)

  • 고동찬;이대하
    • Journal of Soil and Groundwater Environment
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    • v.8 no.2
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    • pp.1-8
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    • 2003
  • Two types of ground-water sampling techniques for CFCs (chlorofluorocarbons) analysis, the cold-welded copper tube method and flame-sealed borosilicate glass ampule method, were compared and evaluated. CFCs concentrations by the copper tube method showed a poor reproducibility among triplicates whereas those by the glass ampule method showed a good agreement and relative standard deviations of triplicates were less than 5%. The poor reproducibility of the copper tube method appears to be attributed to the incomplete sealing in connection between faucets of wellhead and the sampling apparatus. The copper tube method also showed higher CFCs concentrations than the glass ampule method, which is more pronounced for CFC-11 than for CFC-12. The plastic tubings and rubber gasket of faucets in case of the copper tube method possibly contaminated the samples with CFC-11 and CFC-12. The potential of CFCs contamination for the glass ampule method was eliminated by using stainless steel and Nylon only and by connecting the sampling equipment directly to the main discharge pipe of wellhead. The validity of the glass ampule method were also verified by detecting very low level of CFCs for the ground-water sample which is old enough to have negligible CFCs.

Variation of Rare Earth Element Patterns during Rock Weathering and Ceramic Processes: A Preliminary Study for Application in Soil Chemistry and Archaeology (암석의 풍화과정 및 도자기 제조과정에 따른 희토류원소 분포도의 변화: 토양화학 및 고고학적 응용을 위한 기초연구)

  • Lee, Seung-Gu;Kim, Kun-Han;Kim, Jin-Kwan
    • The Journal of the Petrological Society of Korea
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    • v.17 no.3
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    • pp.133-143
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    • 2008
  • On the basis of chemical composition of granite, gneiss and their weathering products, in this paper, rare earth elements (REEs) was estimated as tracer for clarifying a geochemical variance of earth surface material during weathering process. The chemical composition of clay, clay ware and pottery also were measured for testifying usefulness of REE geochemistry in clarifying the source material of pottery. It was observed that there was no systematic variation of chemical composition among source rock, weathered rock and soil during weathering process. The chemical composition of clay, clay ware and pottery also did not show systematic variation by baking pottery. However, PAAS (Post Archean Australian Shale)-normalized REE patterns of rock-weathered rock-soil and clay-clay ware-pottery are similar regardless of weathering process or ceramic art. Our results confirm that REE geochemistry is powerful tool for clarifying the source materials of surface sediment or archaeological ceramic products.