• Environmental Engineering Research
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• v.9 no.3
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• pp.113-118
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• 2004

• Korean Journal of Environmental Agriculture
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• v.28 no.2
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• pp.146-157
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• 2009

The influence of Pb-citrate complex formation on Pb uptake and the effect of Pb on organic acid exudation were investigated using four plant species, viz., sunflower (Helianthus annuus L), Indian mustard (Brassica juncea), canola (Brassica napus) and vetiver grass (Vetiveria zizanioides) under hydroponic conditions. Seedlings were exposed to different levels of Pb and Pb-citrate for 24 hrs and subsequently Pb distributions in plant shoot, root and hydroponic solution were measured. The dissolved organic carbon (DOC) concentration generally decreased as the concentration of Pb in the hydroponic solution increased. In contrast to DOC, the total organic acid concentrations exuded from Indian mustard roots significantly increased (424 to 6656 mg $kg^{-1}$) with increased Pb treatment, implying that exuding organic acids were involved in Pb accumulation in Indian mustard. The complexation of Pb with citrate enhanced Pb accumulation in the above ground portions. Lead concentration in Indian mustard increased from 2.05 mg $kg^{-1}$ to 6.42 mg $kg^{-1}$ when the concentration of citrate in solution increased from 0 to 50 mg $L^{-1}$. This result showed enhanced translocation of Pb from root to shoot with observation of transfer coefficient ($K_t$) increase from 2.03E-3 to 5.72E-3.

• Journal of Soil and Groundwater Environment
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• v.18 no.1
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• pp.129-136
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• 2013

This research was conducted to investigate effects of acid buffering capacity and soil component in treatment of phenanthrene using electrokinetic-Fenton process. In Hadong clay of high acid buffering and low iron oxide content, it was difficult to oxidize phenanthrene due to shortage of iron catalyst and scavenger effect of carbonate minerals. The desorbed phenanthrene conductive to Fenton oxidation was transported toward cathode by electroosmotic flow. However, in Youngdong illitic clay, oxidation of phenanthrene near anode readily occurred compared to Hadong clay due to high iron content and low acid buffering capacity.

• Journal of Environmental Impact Assessment
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• v.4 no.1
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• pp.17-23
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• 1995

To assess preliminarily the contamination potential of water resources including groundwater owing to the hydrogeological characteristics of landfill site and the potential impact to humans and animals through contamination of water resources by leachate, "Landfill Site Preliminary Assessment Model(LASPAS)" was contrived. LASPAS could help them proritization of remediation of landfil sites by the convenient and relatively simple evaluation method of landfill site features. LASPAS was designd to aliot numerical ratings to landfill site related factors undermentioned; 1) hydrogeological factors such as hydraulic conductivity of aquifer, thickness of confining layer over aquifer, topographical slope, net recharge, and subsurface containment 2) water resources contamination factors of impacts on receptors such as proximity to drinking water supply, substitutability of drinking water supply, type of use of water resources, known impact on drinking water supply, and flood potential.

• Journal of Environmental Science International
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• v.16 no.12
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• pp.1325-1335
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• 2007

The utility of soil-gas surveys is directly proportional to their accuracy in reflecting and representing changes in the subsurface concentrations of source compounds. Passive soil-gas vapor-phase is merely a fractional trace of the source, so, as a matter of convenience, the units used in reporting detection values from EMFLUX surveys are smaller than those employed for source-compound concentrations. According to the Leaking Underground Storage Tank(LUST) Program Annual Report, approximately 16 U.S. million dollars were spent for environmental site investigations at over 1,600 Underground Storage Tank(UST) sites and approximately over 1,000 acres of land was characterized and remediated in the State of Illinois in the year of 2003 alone. The main purpose of this study is to propose an idea to significantly reduce the site investigation cost by utilizing a passive soil-gas survey and conventional intrusive drilling method and to fully define the three dimensional characteristics of subsurface contamination from two industrial drycleaning facilities.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.375-378
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• 2005

The objective of this study was to clarify the possibility of adsorption trichloroethylene (TCE) of pretreated granular activated carbon (GAC). The chemical solution used for the acidic treatment was phosphoric acid. In addition, the effect of ultrasound on GAC assessed in this experiments. It was observed that the adsorption of TCE were different based on pH value of pretreated GAC. However, natural water such as groundwater has various factors like ionic strength and hardness etc. Therefore, more laboratory work is needed to study about pretreated GAC.

• Proceedings of the KSEEG Conference
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• 2003.04a
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• pp.66-68
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• 2003

Polycyclic Aromatic Hydrocarbons (PAHs) are hydrophobic and most are practically insoluble in water contributing to their persistence in the environment. In addition, most exist in strongly adsorbed forms when they are introduced into the soils. Their removal efficiency can be limited in low mass transfer phases, such as PAHs-contaminated soils, because most chemical and biological remediation technologies require transfer from NAPs (Non-Aqueous Phase Liquids) into the mobile phase. (omitted)

• Journal of Environmental Science International
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• v.27 no.1
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• pp.1-10
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• 2018

A continuous process of persulfate oxidation and citric acid washing was investigated for ex-situ remediation of complex contaminated soil containing total recoverable petroleum hydrocarbons (TRPHs) and heavy metals (Cu, Pb, and Zn). The batch experiment results showed that TRPHs could be degraded by $Fe^{2+}$ activated persulfate oxidation and that heavy metals could be removed by washing with citric acid. For efficient remediation of the complex contaminated soil, two-stage and three-stage processes were evaluated. Removal efficiency of the two-stage process (persulfate oxidation - citric acid washing) was 83% for TRPHs and 49%, 53%, 24% for Cu, Zn, and Pb, respectively. To improve the removal efficiency, a three-stage process was also tested; case A) water washing - persulfate oxidation - citirc acid washing and case B) persulfate oxidation - citric acid washing (1) - citric acid washing (2). In case A, 63% of TRPHs, 73% of Cu, 60% of Zn, and 55% of Pb were removed, while the removal efficiencies of TRPHs, Cu, Pb, and Zn were 24%, 68%, 62%, and 59% in case B, respectively. The results indicated that case A was better than case B. The three-stage process was more effective than the two-stage process for the remediation of complex-contaminated soil in therms of overall removal efficiency.

• Environmental Engineering Research
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• v.25 no.2
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• pp.197-204
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• 2020

A number of different nanoscale zero-valent iron (nZVI) materials have been prepared and compared depending on the desired properties for the particular application, but different physicochemical properties of this prepared nZVI make it difficult to universally compare and standardize them to the same scale. In this study, we aimed to demonstrate a simple microplate-based colorimetric assay using 4-chlorophenol as an indicator with respect to the remediation of real treatment targets, such as trichloroethylene (TCE), 1,1,1-trichloroethane (TCA), and atrazine. Effect of nickel contents on 4-chlorophenol reduction was successfully investigated by the miniaturized colorimetric assay. In the same manner, the effect of nickel contents on dehalogenation of TCE, TCA, and atrazine was investigated and the pseudo-first-order kinetic constants were compared with the results for 4-chlorophenol. The similar pattern could be observed between 4-chlorophenol reduction obtained by colorimetric assay and TCE, TCA, atrazine reduction obtained by a traditional chromatographic method. The reaction kinetics does not match perfectly, but the degree of reaction can be estimated. Therefore, the colorimetric assay can be a useful and simple screening tool to determine nZVI reactivity toward halogenated organics before it is applied to a particular remediation site.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.10a
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• pp.105-106
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• 2005