• 제목/요약/키워드: environmental diffusion

검색결과 922건 처리시간 0.021초

Effect of Nonuniform Vertical Grid on the Accuracy of Two-Dimensional Transport Model

  • Lee, Chung-Hui;Cheong, Hyeong-Bin;Kim, Hyun-Ju;Kang, Hyun-Gyu
    • 한국지구과학회지
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    • 제39권4호
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    • pp.317-326
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    • 2018
  • Effect of the nonuniform grid on the two-dimensional transport equation was investigated in terms of theoretical analysis and finite difference method (FDM). The nonuniform grid having a typical structure of the numerical weather forecast model was incorporated in the vertical direction, while the uniform grid was used in the zonal direction. The staggered and non-staggered grid were placed in the vertical and zonal direction, respectively. Time stepping was performed with the third-order Runge Kutta scheme. An error analysis of the spatial discretization on the nonuniform grid was carried out, which indicated that the combined effect of the nonuniform grid and advection velocity produced either numerical diffusion or numerical adverse-diffusion. An analytic function is used for the quantitative evaluation of the errors associated with the discretized transport equation. Numerical experiments with the non-uniformity of vertical grid were found to support the analysis.

Isomeric Effects on Volatilization of 1,3-Dichloropropene Fumigant in Soil

  • Kim, Jung-Ho;Mallavarapu, Megharaj
    • 한국환경과학회지
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    • 제18권12호
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    • pp.1325-1330
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    • 2009
  • The fumigant 1,3-dichloropropene (1,3-D) was recently proposed as a direct replacement for methyl bromide ($CH_3Br$) in soil fumigation. This study was conducted to better understand behavior phase partitioning, diffusion and volatilization of 1,3-D as affected by isomer. The Henry's law constant(KH) of cis-1,3-D and trans-1,3-D was 0.058 and 0.037 at $20^{\circ}C$, respectively. $K_H$ of cis form of 1,3-D was higher than that of trans form of 1,3-D. To compare with volatilization of 1,3-D isomer, soil column [70 cm (length)${\times}$12 cm (i.d.)] included a shank injection at 30 cm with 300 kg $ha^{-1}$. Maximum cis-1,3-D and trans-1,3-D concentration reached 57 mg $L^{-1}$ and 39 mg $L^{-1}$ at 30 cm depth at 1h after application. Cumulatively, after 10 days, 51.8% and 43.57% of applied cis-1,3-D and trans-1,3-D was emitted via volatilization, respectively. The total losses of cis-1,3-D were significantly greater than that of trans-1,3-D. Finally, cis-1,3-D and trans-1,3-D, such as isomer are dominant of 1,3-D fates in soil.

염소이온 노출개시시기를 고려한 기존 확산계수 모델 수정제안 (Chloride Diffusion Coefficient Model Considering the Initiation Time of Exposure to Chloride Environment)

  • 김기현;차수원
    • 콘크리트학회논문집
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    • 제21권3호
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    • pp.377-386
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    • 2009
  • ACI life-365 기준확산계수 모델은 NT build 443 방법에 의한 시험 결과들로부터 만들어졌다. 이 방법은 침지기간 동안의 시간평균 확산계수를 구하는 방법이므로 ACI에서는 침지기간 동안의 시간평균 확산계수를 기준확산계수로 정의한 것이다. ACI 모델에서는 재령에 따른 감소효과를 지수함수 형태로 표현하고 있으므로 이를 고려한 ACI 기준확산계수 모델의 수정이 필요하다. 이를 위해 본 연구에서는 염소이온 노출개시기를 고려한 확산방정식의 해석해를 유도하고, 이를 사용하여 NT build 443 방법의 시간평균 확산계수를 기준재령의 확산계수로 변환하였다. 연구결과 life-365 기준확산계수 모델은 기존 값 보다 10% 정도 증가되고 수정되어야 함을 밝혔으며, 이에 따라 NT build 443 방법과 NT build 492 방법의 기존관계를 수정하여 내구수명 평가에 이용할 수 있도록 하였다. JCI 확산계수모델과 ACI 확산계수모델의 직접적인 비교를 위하여 JCI 확산계수모델에 대응하는 기준확산계수를 유도하였으며, 이를 통해 JCI 모델보다 ACI 모델이 더 보수적인 결과를 나타내는 것을 확인하였다.

확산 포집기로 공기중 혼합유기용제 포집시 온도와 상대습도가 포집효율에 미치는 영향 (Effects of temperature and relative humidity on the sampling efficiencies of mixed organic vapors measured by diffusion monitors)

  • 한진구;노영만;김현욱
    • 한국산업보건학회지
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    • 제5권2호
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    • pp.200-211
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    • 1995
  • This study was designed to evaluate the effects of temperature and humidity on the sampling efficiency of mixed organic vapors of l,2-DCE, benzene, and MIBK by 3 different types of diffusion monitors. Independent variables used for the study were temperatures ($25^{\circ}C$, $35^{\circ}C$), humidities (30%, 80%), and vapor concentrations (low, medium, and high). In addition, vapor concentrations measured by the traditional charcoal tube method were used as reference values and were compared with those of by diffusion monitors. The results were as follows: 1. The desorption efficiencies(DE) of 1,2-DCE and benzene from charcoal tubes and from diffusion monitors ranged from 98% to 105%. In contrast, the DEs of MIBK from charcoal tubes and diffusion monitors except DM1 ranged from 71% to 85%. The DE of MIBK from DM1 was 98%. 2. No statistically significant differences of 1,2-DCE concentrations and the sampling efficiencies regardless of temperatures and humidities studied between charcoal tube and 3 diffusion monitors were found. 3. At 80% humidity, increasing frequencies of 1,2-DCE breakthrough at higher temperature and higher vapor concentration measured by charcoal tubes were observed. 4. No statistically significant difference of benzene concentrations were found between charcoal tube and diffusion monitors except DM3. The sampling efficiencies of DM3 were statistically significantly lower at all experimental conditions except the $35^{\circ}C$ and 30% humidity condition. 5. No statistically significant difference of MIBK concentrations were found between charcoal tube and diffusion monitors except DM3. The sampling efficiencies of DM3 were statistically significantly higher at higher humidity conditions regardless of temperature. Although statistically not significant, sampling efficiency of MIBK showed positive correlation with humidity while negative correlation with concentration was observed. 6. For sampling 1,2-DCE and benzene, no significant variations of concentrations among three diffusion monitors regardless of temperature and humidity conditions were found. For MIBK sampling, however, wide variations with increasing humidity among diffusion monitors were obtained. In conclusion, this study suggests that diffusion monitors will be a reasonables substitute for the traditional charcoal tubes for sampling non-polar organic vapors at temperature and humidity conditions studied. For polar organic vapors, use of an alternative desorption solution other than CS2 is recommended because of its low desorption efficiency. In addition, since variable among diffusion monitors for polar organic vapors particularly at higher humidity conditions were observed, further study is recommended of the effects of humidity on the performance of diffusion monitors.

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국지풍모델을 이용한 연안지역 거대 점오염원의 이류확산 수치모의 (Numerical Simulation of Dispersion of a Vast Point Source in Coastal Area using the Local Wind Model)

  • 전병일
    • 한국환경과학회지
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    • 제7권4호
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    • pp.511-522
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    • 1998
  • The two-stage numerical model was used to study the relation between three-dimensional local wind seal area for Korean peninsula. The first stave is three dimensional time-dependent local wind model which elves the wind field and vertical diffusion coefncient. The second stage is advection/duusion model which uses the results of the first stage as input data. First, wand fields on Korean peninsula for none synoptic scale wand showed typical land and sea breeze circulation, and the emitted particles were transported by sea breeze for daytime, emissions return to sea by land breeze for nighttime.

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미기상 특성에 따른 대기오염 농도분포에 관한 연구 (A Study on the Distribution of Air Pollutant Concentration According to Micrometeorological Characteristics)

  • 김유근;홍정혜;전병일
    • 한국환경과학회지
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    • 제3권1호
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    • pp.31-38
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    • 1994
  • The diffusion of the pollutants released into atmosphere is dependent on its chemical reaction, topography and micrometeorological characteristics. The purpose of the study is to investigate how much micrometeorological characteristics such as stability, wind speed and mixing height affect the diffusion of the air pollutants. For this purpose, this paper let 1) the basic theory be K-theory, 2) eddy diffusivity and wind speed be dependent on mixing height and stability, and 3) Grout method be used for numeric calculation. The result was 1) the more unstable condition, the higher mixing height and the higher wind speed we, the lower pollutants concentration appears, 2) the most intensive effect on the distribution of the pollutant concentration is the atmospheric stability.

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지표면 특성을 고려한 부산지역의 건성침적속도 예측 (The Numerical Simulation of Dry Deposition Velocity Of O3 using Land-Use Information in the Busan Metropolitan City)

  • 문난경;이화운
    • 한국환경과학회지
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    • 제11권9호
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    • pp.925-931
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    • 2002
  • Land-use types should be included in air pollutant diffusion model because a complex mixture of various land-use patterns with computational grid can make errors in calculation of several parameters. However, the air pollutant diffusion model has generally been treated with a uniform component with land-use type in each mesh because of the complexity of the simulation. This study presents a numerical simulation of the horizontal distribution of $O_3$dry deposition velocity during summertime in Busan metropolitan city. The calculation of the meteorological field was conducted using the land cover data. Simulation has been performed by the following two scenarios : (1) one with current land cover data, and (2) the other with only land and sea for the surface characteristics. The results from each scenario reveals considerable differences on the meteorological fields and these differences can cause changes in the calculation values of $O_3$deposition velocity.

2-Dimensional Model Development for Water Quality Prediction

  • Paik, Do-Hyeon
    • 한국환경보건학회지
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    • 제31권6호
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    • pp.489-497
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    • 2005
  • A numerical method for the mathematical water modeling in 2-dimensional flow has been developed. The model based on a split operator technique, in which, the advection term is calculated using the upwind scheme. The diffusion term is one- dimensionalized and calculated using Crank-Nicholson's implicit finite difference scheme to reduce the numerical errors from large time steps and variable spacings. It also provides a relatively simple and economic method for more accurate simulation of pollutant dispersion. Water depths and flow velocities in the Boreyong reservoir during the normal water periods were predicted by numerical experiments with a 2-dimensional flow model so as to provide current field data for the study of advection and diffusion of pollutants. Developed 2-dimensional water quality model is applied to Boreyong reservoir to simulate a spatial and periodical changes of water quality.

Penetration Efficiency of Charged Particles in a Cylindrical Tube Connection with Electrical Voltage Difference

  • Song, Dong-Keun;Kim, Tae-Oh
    • Journal of Korean Society for Atmospheric Environment
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    • 제23권E1호
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    • pp.29-38
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    • 2007
  • A cylindrical tube connection that has a voltage difference and is separated electrically by an insulator was modelled. The penetration efficiencies of charged particles passing through the connector tube were investigated. Typically, as the particle size decreases and the applied voltage difference increases, the penetration efficiency decreases. To assess the effect of the electrode geometry, various lengths of electric insulator and aerosol flow rate with a fixed tube length and tube diameter were used when calculating penetration efficiencies. The comparison of penetration efficiencies for various electrode geometry setups suggests that the penetration efficiency can be described as a function of the product of applied voltage and electrical mobility of charged particles. The diffusion loss from this and previous studies are compared. Further, an explicit form for penetration efficiency is provided as a function of a new non-dimensional parameter, $Es(=Z_pV/U_{avg}W);\;P_{es}=0.2{\cdot}{\exp}(-Es/0.6342)+0.8{\cdot}{\exp}(-Es/4.7914)$.

${\gamma}-Alumina$에 담지된 산화구리에 의한 $SO_x$가스의 제거 특성 (Removal Characterics of $SO_x$ by CuO Impregnated ${\gamma}-Alumina$)

  • 이창선;윤용수
    • 환경위생공학
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    • 제11권3호
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    • pp.29-35
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    • 1996
  • Numerical solutions were obtained to the model equations for various parameters characterizing the pore structure, effective internal diffusion and the chemical reaction constant. The conversion was decreased with the cause of pore closure at the surface of reacting particles, reduction of porosity, surface area of reaction and effective diffusion coefficient in the solid with the progress of reaction. Total conversion was strongly depend on the local conversion at surface. According to the decreasing of impregnated concentration of the copper oxide and the increase of the flue gases concentration, total conversion was increased. And the conversion were affected by gas flow rate and pore size distribution of the reacting solid.

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