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Environmental Auditing-Analysis of Enterprises (환경감사 - 기업분석)

  • Wotte, Joris
    • Journal of Environmental Impact Assessment
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    • v.4 no.3
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    • pp.9-13
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    • 1995
  • In July 1993 a new prescription of the EC was finished, concerning the voluntary participation of enterprises in a common auditing system. By this in the EC-member countries there must be founded centers of environmental auditing where experienced experts of environmental auditing should be accredited. These accredited experts are controllers for evaluating and certification of carried out environmental-auditings. An environmental-auditing practically represents an environmental assessment for an already existing enterprise with establishing corresponding programmes and strategies for the internal management to improve the environmental relations. Much experiences, which could be collected in the field of EIA during the last years may be transfered to this new task immediately. Only an essential difference there should not be overseen because of national legislation EIA in the defined cases must be carried out. By the EC-prescription carrying out an environmental-auditing for an enterprise is optional, it is recommended only. It was not introduced as a must. In spite of this fact because of the hard competition on the market there will be developed a pressure for the enterprises, to carry out such environmental-auditings. At present already a number of first projects in this direction can be seen, in the first line above all enterprises with the necessary economic power want to use this possibility, to gain better positions on the market. We have already gathered the first experiences in this field. We arranged corresponding contacts to several enterprises within the surroundings of Dresden. Within an opening discussion, where the project is explained and discussed with the management of the enterprise very detailed, the understanding, the readiness and the cooperation for the project are generated necessary prerequesits for the success of the whole work. By means of careful detail-work in collaboration with all departments and on all levels of the enterprise the total mass and energy-balances of the factory established and analysed. There are included also such ranges like material delivery, personal policy, public relations and sale as well as waste management. It is important that all people working in the factory have the feeling to be our partners, and not to have the impression to be checked or controled by an outside organization. This one of the most important factors of environmental auditing, in order to wake up and to develop a common interest on all sides. At the end of the environmental auditing there will be according to the prescription of the EC a catalogue of measures to do immediately, short time, mean time and long time for improvement of the environmental situation of the enterprise. All proposals are made in connection with a corresponding economic evaluation. These measures and programmes are declared as the environmental manual and are the basis for the work of the environmental management of the enterprise for the next three years. According to the EC-prescription, the enterprise with this environmental manual can get a corresponding certificate, which may be used for public relation purposes.

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Recycling and Characteristics of Plasma Melting Slag Materials Produced by Different Cooling Methods (플라즈마 용융방식으로 배출된 슬래그의 냉각방식에 따른 재료적 특성 및 재활용)

  • Chung, Juyoung;Bae, Wookeun;Kim, Moonil;Park, Seyong
    • Journal of the Korean GEO-environmental Society
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    • v.11 no.7
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    • pp.25-31
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    • 2010
  • In this study, it was intended to suggest new cooling method that enables to improve the applicability and added value higher than existing slag by applying new cooling method(powder cooling slag) at the time discharging slag, which is produced from the ash melting system that the plasma torch is used for the first time in Korea. It is suggested the applicative direction in the development of future recycling process by discovering its nature of material and applicative possibility as earthwork material. The ashes produced after the sewage sludge discharged from Y city was incinerated by the fluidized bed method and was used as test materials. As result of XRF(X-Ray Flourescence Spectrometry) analysis, main ingredient of sewage sludge ashes was $SiO_2$(32%) besides CaO, $Al_2O_3$, $Fe_2O_3$, and so on. In addition, as result of XRD analysis, traditional diffuse pattern of glass could be found from granulated air-cooled slags, while a minor crystal phase could be observed from powder cooling slag, because the powder on the surface exists in the state not melted. From EDX(Energy Dispersive X-ray Spectroscopy) analysis, it is deemed that powder ingredient has no change before and after it is used as cooling medium, and accordingly it is thought that the powder can be produced as the material where the function is added if used in different shape.

Geochemical Characteristics of Groundwater during the Constant and Step-drawdown Pumping Tests at the River Bank Filtration Site (장기 및 단계 양수시험 시 강변여과 지하수의 수질변화 특성)

  • Kim, Gyoobum;Shin, Seonho;Kim, Byungwoo;Park, Joonhyung
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.8
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    • pp.11-21
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    • 2013
  • In-situ test to find the change of $Fe^{2+}$ and $Mn^{2+}$ concentrations and ion contents in groundwater was conducted during two pumping tests at the riverbank filtration site, where is the riverine area of the Nakdong River in Changnyeong-Gun. Groundwater was sampled at one pumping well and 10 monitoring wells during a 5 steps drawdown pumping test with the rates from $500m^3/day$ to $900m^3/day$ and a constant pumping test with $800m^3/day$. The change in ion concentration of groundwater was more remarkable during a step drawdown pumping test than a constant pumping test. Especially, the decrease in $Fe^{2+}$ and $Mn^{2+}$ concentrations was distinct in a step drawdown pumping test and it happens predominantly along the direction that the radius of pumping influence was small due to a good aquifer connectivity to a pumping position. The precipitation and the oxidation of iron and manganese were caused by an air inflow and a disturbance in groundwater flow due to an abrupt change in pumping rate. The pumping rate and spatial distribution of an aquifer around a pumping well need to be considered as an important factor for the development of in-situ iron and manganese treatment technology.

Investigation on a Haze Episode of Fine Particulate Matter using Semi-continuous Chemical Composition Data (준 실시간 화학적 조성자료를 이용한 미세입자 연무 에피소드 규명)

  • Park, Seung-Shik;Kim, Sun-Jung;Gong, Bu-Joo;Lee, Kwon-Ho;Cho, Seog-Yeon;Kim, Jong-Choon;Lee, Suk-Jo
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.5
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    • pp.642-655
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    • 2013
  • In this study, semi-continuous measurements of $PM_{2.5}$ mass, organic and elemental carbon (OC and EC), black carbon (BC), and ionic species concentrations were made for the period of April 03~13, 2012, at a South Area Supersite at Gwangju. Possible sources causing the high concentrations of major chemical species in $PM_{2.5}$ observed during a haze episode were investigated. The measurement results, along with meteorological parameters, gaseous pollutants data, air mass back trajectory analyses and PSCF (potential source contribution function) results, were used to study the haze episode. Substantial enhancements of OC, EC, BC, $K^+$, $SO{_4}^{2-}$, $NO{_3}{^-}$, $NH{_4}{^+}$, and CO concentrations were closely associated with air masses coming from regions of forest fires in southeastern China, suggesting likely an impact of the forest fires. Also the PSCF maps for EC, OC, $SO{_4}^{2-}$, and $K^+$ demonstrate further that the long-range transport of smoke plumes of forest fires detected over the southeastern China could be a possible source of haze phenomena observed at the site. Another possible source leading to haze formation was likely from photochemistry of precursor gases such as volatile organic compounds, $SO_2$, and $NO_2$, resulting in accumulation of secondary organic aerosol, $SO{_4}^{2-}$ and $NO{_3}{^-}$. Throughout the episode, local wind directions were between 200 and $230^{\circ}C$, where two industrial areas are situated, with moderate wind speeds of 3~5 m/s, resulting in highly elevated concentration of $SO_2$ with a maximum of 15 ppb. The $SO{_4}^{2-}$ peak occurring in the afternoon hours coincided with maximum ambient temperature ($24^{\circ}C$) and ozone concentration (~100 ppb), and were driven by photochemistry of $SO_2$. As a result, the pattern of $SO{_4}^{2-}$ variations in relation to wind direction, $SO_2$ and $O_3$ concentrations, and the strong correlation between $SO_2$ and $SO{_4}^{2-}$ ($R^2=0.76$) suggests that in addition to the impact of smoke plumes from forest fires in the southeastern China, local $SO_2$ emissions were likely an important source of $SO{_4}^{2-}$ leading to haze formation at the site.

Growth and Optical Properties of SnSe/BaF2 Single-Crystal Epilayers (SnSe/BaF2 단결정 박막의 성장과 광학적 특성)

  • Lee, II Hoon;Doo, Ha Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.7 no.2
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    • pp.209-215
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    • 2002
  • This study investigated the crystal growth, crystalline structure and the basic optical properties of $SnSe/BaF_2$ epilayers. The SnSe epilayer was grown on $BaF_2$(111) insulating substrates using a hot wall epitaxy(HWE) technique. It was found from the analysis of X-ray diffraction patterns that $SnSe/BaF_2$ epilayer was growing to single crystal with orthorhombic structure oriented [111] along the growth direction. Using Rutherford back scattering(RBS), the atomic ratios of the SnSe was found to be stoichiometric, almost 50 : 50. The best values for the full width at half maximum (FWHM) of the DCXRD was 163 arcsec for SnSe epilarer. The epilayer-thickness dependence of the FWHM of the DCXRD shows that the quality of the $SnSe/BaF_2$ is as expected. The dielectric function ${\varepsilon}$(E) of a semiconductor is closely related to its electronic energy band structure and such relation can be drawn from features around the critical points in the optical spectra. The real and imaginary parts(${\varepsilon}_1$ and ${\varepsilon}_2$) of the dielectric function ${\varepsilon}$ of SnSe were measured. These data are analyzed using a theoretical model known as the model dielectric function(MDF). The optical constants related to dielectric function such as the complex refractive index(n*-n+ik), absorption coefficient (${\alpha}$) and normal- incidence reflectivity (R) are also presented for $SnSe/BaF_2$.

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Characterization of Layered Double Hydroxides(Mg-Al-$CO_3$ systems) and Rehydration Reaction of Their Calcined Products in Aqueous Chromate Solution (층상이중수산화물(Mg-Al-$CO_3$ 체계)의 물리 · 화학적 특성규명 및 소성된 시료의 크롬산이온 수용액에서 재수화반응)

  • Rhee, Seog Woo;Kang, Mun-Ja;Moon, Hichung
    • Journal of the Korean Chemical Society
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    • v.39 no.8
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    • pp.627-634
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    • 1995
  • Layered double hydroxides ($Mg-Al-CO_3$ systems, LDH), which are hydrotalcite-like anionic clay minerals, having different $Mg^{2+}\;to\;Al^{3+}$ ratio were synthesized by coprecipitation method. The subsequent products were characterized by the following methods; elemental analysis, X-ray powder diffraction, thermal analysis (DSC and TGA), FT-IR and $^{27}$Al-MAS NMR. X-ray powder patterns showed that the products formed were layered structure materials. Two heat absorption peaks were observed around 20 ∼280$^{\circ}C$ (surface water and interlayer water) and 280∼500$^{\circ}C$ (water from lattice hydroxide and carbon dioxide from interlayer carbonate) in DSC diagrams, and they were quantitatively analyzed by TGA diagrams (in case LDH4 16.2% and 28.6% respectively). FT-IR spectra indicate that the interlayer carbonate ions occupied symmetrical sites between two adjacent layers in a parallel direction. $^{27}$Al-MAS NMR spectra show only single resonance (8.6 ppm) of the octahedrally coordinated aluminum similar magnesium. When LDH4 was calcined at 560$^{\circ}C$ for 3 hours in air, its layered structure was destroyed giving a mixed metal oxide. However it readily became rehydrated in aqueous chromate solution to its original structure.

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A Relief Method to Obtain the Solution of Optimal Problems (최적화문제를 해결하기 위한 완화(Relief)법)

  • Song, Jeong-Young;Lee, Kyu-Beom;Jang, Jigeul
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.20 no.1
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    • pp.155-161
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    • 2020
  • In general, optimization problems are difficult to solve simply. The reason is that the given problem is solved as soon as it is simple, but the more complex it is, the very large number of cases. This study is about the optimization of AI neural network. What we are dealing with here is the relief method for constructing AI network. The main topics deal with non-deterministic issues such as the stability and unstability of the overall network state, cost down and energy down. For this one, we discuss associative memory models, that is, a method in which local minimum memory information does not select fake information. The simulated annealing, this is a method of estimating the direction with the lowest possible value and combining it with the previous one to modify it to a lower value. And nonlinear planning problems, it is a method of checking and correcting the input / output by applying the appropriate gradient descent method to minimize the very large number of objective functions. This research suggests a useful approach to relief method as a theoretical approach to solving optimization problems. Therefore, this research will be a good proposal to apply efficiently when constructing a new AI neural network.

An Analytical Solution of Flow and Progressive Wave-Induced Residual Pore Water Pressure in Seabed (흐름과 진행파에 의한 해저지반 내 잔류간극수압의 해석해)

  • Lee, Kwang-Ho;Kim, Dong-Wook;Kang, Gi-Chun;Kim, Do-Sam;Kim, Tae-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.31 no.7
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    • pp.13-28
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    • 2015
  • This study extended the Lee et al.'s (2015a) solution which improved the existing analytical solution for prediction of the residual pore water pressure into progressive wave and flow coexisting field. At this time, the variation of incident wave period and wave length should be incorporated to Lee et al.'s (2015a) analytical solution, which does not consider flow. For the case of infinite thickness, the new analytical solution using Fourier series was compared to the analytical solution using Laplace transformation proposed by Jeng and Seymour (2007). It was verified that the new solution was identical to the Jeng and Seymour's solution. After verification of the new analytical solution, the residual pore water pressure head was examined closely under various given values of flow velocity's magnitude, direction, incident wave's period and seabed thickness. In each proposed analytical solution, asymptotic approach to shallow depth with the changes in the soil thickness within finite soil thickness was found possible, but not to infinite depth. It is also identified that there exists a discrepancy case between the results obtained from the finite and the infinite seabed thicknesses even on the same soil depth.

Removal of Phenanthrene by Electrokinetic-Fenton Process in a 2-dimensional Soil System (동전기-펜턴 공정을 이용한 2차원 토양 정화장치에서의 phenanthrene 제거)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.10 no.5
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    • pp.11-17
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    • 2005
  • Characteristics of phenanthrene removal in the Electrokinetic (EK)-Fenton process were investigated in a 2-dimensional test cell in a viewpoint of the effect of gravity and electrosmotic flow (EOF). When the constant voltage of 100 V was applied to this system, the current decreased from 1,000 to 290 mA after 28 days, because soil resistance increased due to the exhaustion of ions in soil by electroosmosis and electromigration. Accumulated EOF in two cathode reservoirs was 10.3 L and the EOF rate was kept constant for 28 days. At the end of operation, the concentration of phenanthrene was observed to be very low near the anode and increased in the cathode region because hydrogen peroxide was supplied from anode to cathode region following the direction of EOP. Additionally, the concentration of phenanthrene decreased at the bottom of the test cell because the electrolyte solution containing hydrogen peroxide was largely transported toward the bottom due to a low capillary action in the soil with high porosity. Average removal efficiency of phenanthrene by EK-Fenton process was 81.4% for 28 days. In-situ EK-Fenton process would overcome the limitations of conventional remediation technologies and effectively remediate the contaminated sites.

Computational Method for Rate of Overtopping Using Time Dependent Mild-Slope Equation (시간의존 완경사방정식을 이용한 월파량 산정 방법)

  • Kwak, Moon-Su;Lee, Hong-Gyu;Park, Sung-Yoon;Pyun, Chong-Kun
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.18 no.4
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    • pp.372-382
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    • 2006
  • Most of the conventional breakwaters impermeable breakwaters which block seawater exchange between the outside and inside of the harbors. The blocking of seawater exchange may cause pollution of water in harbors. To solve the water pollution problem, various kinds of seawater exchange breakwaters have been proposed. Their types can be classified into the current type which uses tidal current, and the overtopping type which uses the wave energy. The overtopping type breakwaters require a discharge coefficient to calculate the rate of overtopping into the harbor. The present study is to compute the rate of overtopping with introduction of a correct discharge coefficient and to evaluate the effect of the overtopping type breakwater on the water qualify inside a harbor. The rate of overtopping was computed by using Forchheimer formula with time dependent mild-slope equation for various wave conditions. The formula has been generally used to calculate the overflow discharge in steady state river flows. The discharge coefficient, which is the key parameter of the calculation, was determined by a series of hydraulic model tests. The present scheme was applied to the seawater exchange section of the western breakwater of Jeju New Harbor's and the efficiency of that section was examined. The calculated results showed that the rate of overtopping into the harbor reached about $27.5m^3/s$ in the wave condition (wave height 3.7 m, wave period 8.5s, and wave direction NNW).