• 한국신재생에너지학회:학술대회논문집
• /
• 2006.06a
• /
• pp.145-148
• /
• 2006

The protocrystalline silicon (pc-Si:H) multilayer solar cell is very promising owing to its fast stabilization with low degradation against light irradiation. However, the pc-Si:H multi layers have not extensively been investigated in detail on its material characteristics yet. We present the material characteristics of pc-Si:H multilayer using a transmission electron microscopy(TEM), and Raman spectroscopy. In addition, we present the superior light-soaking behavior of the pc-Si:H mutt i layer solar cell. A TEM micrograph shows that a pc-Si:H multilayer has a repeatedly layered structure and crystalline-like objects in a-Si:H matrix. A Raman spectra introduces improved short-range-order and medium-range-order in pc-Si:H multilayer. As a result the excellent metastability of the pc-Si:H multilayer solar cell is primarily due to the repeatedly layered structure that improves a structural order in absorber layer.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.06a
• /
• pp.210-213
• /
• 2006

나노입자를 이용하여 치밀한 $Cu(In,\;Ga)Se_2$ 태양전지용 광흡수층을 제조하기 위해 먼저, 콜로이달 방법으로 합성된 20nm이하의 CIGS 나노입자를 저가의 스프레이 법을 이용하여 CIGS 막을 제조하였다. 제조된 CIGS막을 two-zone RTP (rapid temperature Process) 방법으로 Se 분위기 안에서 열처리를 행하였다. 입자의 치밀화를 위해 기판의 온도, Se 증발온도와 수송가스의 유량을 조절하여 CIGS 입자성장을 행하였다. 그러나, Se의 증발온도가 높을수록 CIGS와 MO 박막 사이에서 $MoSe_2$ 층이 형성되었다. 형성된 $MoSe_2$층의 부피 팽창으로 인해 하부의 유리기판과 Mo층 사이에서 peeling off 현상이 발생했다. 이러한 Peeling off현상을 억제하면서 CIGS 나노입자 성장을 하기 위해, Se 공급을 빨리 할 수 있도록 Se의 증기압을 높였으며, 최적조건에서 급속 열처리 공정을 통해 CIGS 나노입자 성장과 치밀화를 위한 소결거동을 관찰하였다.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.06a
• /
• pp.222-224
• /
• 2006

A non-vacuum process for $Cu(In,Ga)Se_2$ (CIGS) thin film solar cells from nanoparticle precursors was described in this work CIGS nanoparticle precursors was prepared by a low temperature colloidal route by reacting the starting materials $(CuI,\;InI_3,\;GaI_3\;and\;Na_2Se)$ in organic solvents, by which fine CIGS nanoparticles of about 20nm in diameter were obtained. The nanoparticle precursors were mixed with organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of CIGS with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents ud to burn the organic binder material. Subsequently, the resultant (porous) CIGS/Mo/glass simple was selenized in a two-zone Rapid Thermal Process (RTP) furnace in order to get a solar ceil applicable dense CIGS absorber layer. Complete solar cell structure was obtained by depositing. The other layers including CdS buffer layer, ZnO window layer and Al electrodes by conventional methods. The resultant solar cell showed a conversion efficiency of 0.5%.

• Journal of Powder Materials
• /
• v.25 no.6
• /
• pp.514-522
• /
• 2018

Layered-double hydroxide (LDH)-based nanostructures offer the two-fold advantage of being active catalysts with incredibly large specific surface areas. As such, they have been studied extensively over the last decade and applied in roles as diverse as light source, catalyst, energy storage mechanism, absorber, and anion exchanger. They exhibit a unique lamellar structure consisting of a wide variety of combinations of metal cations and various anions, which determine their physical and chemical performances, and make them a popular research topic. Many reviewed papers deal with these unique properties, synthetic methods, and applications. Most of them, however, are focused on the form-factor of nanopowder, as well as on the control of morphologies via one-step synthetic methods. LDH nanostructures need to be easy to control and fabricate on rigid substrates such as metals, semiconductors, oxides, and insulators, to facilitate more viable applications of these nanostructures to various solid-state devices. In this review, we explore ways to grow and control the various LDH nanostructures on rigid substrates.

• Nuclear Engineering and Technology
• /
• v.54 no.1
• /
• pp.11-18
• /
• 2022

In this research, curium oxide (CmO₂) is studied as fuel for VVER-1200 reactor to get an attention to its energy value and possibilities. For this purpose, CmO₂ is used in fuel rods or integrated burnable absorber (IBA) rods with and without UO₂ and then compared with the conventional fuel assembly of VVER-1200 reactor. It is burned to 60 GWd/t by using SRAC-2006 code and JENDL-4.0 data library. From these studies, it is found that CmO₂ is competent like UO₂ as a fuel due to higher fission cross-section of ²⁴³Cm and ²⁴⁵Cm isotopes and neutron capture cross-section of ²⁴⁴Cm and ²⁴⁶Cm isotopes. As a result, when some or all of the UO₂ of fuel rods or IBA rods are replaced by CmO₂, we get a similar k-inf like the reference even with lower enrichment UO₂ fuels. These studies show that the use of CmO₂ as IBA rods is more effective than the fuel rods considering the initially loaded amount, power peaking factor (PPF), fuel temperature and void coefficient, and the quality of spent fuel. From a detailed study, 3% CmO₂ with inert material ZrO₂ in IBA rods are recommended for the VVER-1200 reactor assembly from the once through concept.

• Structural Engineering and Mechanics
• /
• v.88 no.6
• /
• pp.521-533
• /
• 2023

In the present study, the finite volume method is applied for the thermal performance prediction of the natural ventilation system using vertical solar chimney whereas, design parameters are optimized through the response surface methodology (RSM). The computational simulations are performed for various parameters of the solar chimney such as absorber temperature (40≤T_abs≤70℃), inlet temperature (20≤T₀≤30℃), inlet height of (0.1≤h≤0.2 m) and chimney width (0.1≤d≤0.2 m). Analysis of variance (ANOVA) was carried out to identify the design parameters that influence the average Nusselt number (Nu) and mass flow rate (ṁ). Then, quadratic polynomial regression models were developed to predict of all the response parameters. Consequently, numerical and graphical optimizations were performed to achieve multi-objective optimization for the desired criteria. According to the desirability function approach, it can be seen that the optimum objective functions are Nu=25.67 and ṁ=24.68 kg/h·m, corresponding to design parameters h=0.18 m, d=0.2 m, T_abs=46.81℃ and T₀=20℃. The optimal ventilation flow rate is enhanced by about 96.65% compared to the minimum ventilation rate, while solar energy consumption is reduced by 49.54% compared to the maximum ventilation rate.

• Applied Chemistry for Engineering
• /
• v.24 no.3
• /
• pp.227-230
• /
• 2013

The phase change of $(U_{1-x}Nd_x)_3O_8$ powder produced by oxidation of Nd-doped $UO_2$ pellet at $500^{\circ}C$ was investigated by high temperature oxidation heat treatment at $900{\sim}1500^{\circ}C$ under an air atmosphere. The XRD analysis results showed that the formation of $(U_{1-y}Nd_y)O_{2+z}$ phase and $U_3O_8$ phase from metastable $(U,Nd)_3O_8$ phase initiated at a temperature of $1000^{\circ}C$. The relative integrated intensity of $(U_{1-y}Nd_y)O_{2+z}$ phase to $U_3O_8$ phase increased with increasing of the oxidation temperature from 1100 to $1500^{\circ}C$. And also, it was found from the SEM observation that the particle size of $(U_{1-y}Nd_y)O_{2+z}$ phase increased with increasing of the oxidation temperature. However, electrone probe X-ray microanalyzer (EPMA) analysis results showed that Nd contents in $(U_{1-y}Nd_y)O_{2+z}$ phase decreased with increasing of the oxidation temperature. This behavior on the ground of XRD, SEM, and EPMA analysis data could be interpreted in terms of the transportation of U ions from $U_3O_8$ phase into $(U_{1-y}Nd_y)O_{2+z}$ phase through the interface of two phases during high temperature oxidation.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.39 no.9
• /
• pp.885-892
• /
• 2015

In this study, we simulate the railway crash accident that occurred at the Sangwangsimni station on the Seoul Metro Line #2, and we propose a solution to minimize the damage. We use LS-DYNA, which is the commercial software employed for collision analysis to perform 1-D and 3-D simulations for the recurrence of accidents. By performing 1-D simulations, we analyze the load, displacement, absorbed energy of the couplers, and acceleration of vehicles, and we evaluate the safety in accidental collisions. By performing 3-D simulations, we analyze the deformation of the car and over-ridding. We propose methods to improve the safety in collisions involving railway vehicles, and we perform collision accident simulations to determine improvements when applying a high-performance energy absorber to the front car.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.68.2-68.2
• /
• 2010

Dye-sensitized solar cells (DSSC) show great promise as an inexpensive alternative to conventional p-n junction solar cells. Investigations into the various factors influencing the photovoltaic efficiency have recently been intensified. The conventional absorber electrode in DSSC is composed of compacted or sintered $TiO_2$ nanopowder that carries an anchored organic dye. The absorbance of incident light in the DSC is realized by specifically engineered dye molecules placed on the semiconductor electrode surface ($TiO_2$). The dye absorbs light at wavelengths up to about 920nm, the energy of the exited state of the molecule should be about 1.35eV above the electronic ground state corresponding to the ideal band gap of a single band gap solar cell. The dye molecules ar adhered onto the nanostrutured $TiO_2$ electrode by immersing the sintered electrode into a dye solution, typically 3mM in alcohol, for a long enough period to fully impregnate the electrode. However, the concentrations of the dye is slightly changed due to the evaporation of the alcohol. The dye is more expensive than other materials in DSSC and related to the efficiency of DSSC. Therefore, the concentrations of the dye should be carefully measured. In this study, we investigated to the dye loading on fired $TiO_2$ powder as a function of temperature by the TG-DTA and the dye solution by UV-visible spectroscopy after the impregnation process. The dye loading is related to the porosity of the nanostructured $TiO_2$ electrode.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2002.11a
• /
• pp.71-79
• /
• 2002

Nuclear design characteristics of duplex burnable poison rod were evaluated based on 24 month cycle fuel for Korean Standard Nuclear Plant. A fuel assembly with duplex burnable poison rod was designed for an equivalent assembly to 16 gadolinia BPs. Duplex BP is composed of inner region of natural U-12wt%Gd$_2$O$_3$ and outer shell of 4.95wt%UO$_2$-2wt%Er$_2$O$_3$. In order to compare this duplex option, assemblies with 140 erbia pins were designed as an alternative option. The variation of k-infinitive, rod worth, pin peaking and MTC were compared. Duplex BP had the better neutronic performance than gadolinia BP in all parameters. However, Duplex BP was worse than erbia BP in the aspect of safety.