• Title/Summary/Keyword: emission stability

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Poly(fluorene)s for LED Applications

  • Lee, Jeong-Ik;Zyung, Tae-Hyoung;Klaerner, Gerrit;Miller, Robert D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2000.01a
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    • pp.129-130
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    • 2000
  • The emission color stability of poly(fluorene) derivatives upon thermal annealing or passage of current in an electroluminescent device is affected by the structure of the main chain polymer unit and particularly by the polymer chain end substituents. Proper attention to these features leads to colorfast blue emission in both photo- and electoluminescence. Furthermore, the spectral emission characteristics can be tuned by the incorporation of various comonomers. Preliminary single layer device studies validate the potential utility of poly(fluorene) homo and copolymers for OLED applications.

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A Study on the Characteristics of Combustion for Substituting $CO_2\;for\;N_2$ in Combustion Air (연소용 공기중 $N_2$$CO_2$대체에 대한 연소특성 해석)

  • Kim, Han-Seok;Ahn, Kook-Young;Kim, Ho-Keun;Lee, Yun-Won;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.7 no.4
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    • pp.29-35
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    • 2002
  • [$CO_2$] is a well-known greenhouse gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. The central method of low $CO_2$ emission is Oxygen/CxHy combustion. Theoretically Oxygen/CxHy combustion only produces $CO_2\;and\;H_2O$ and allows convenient recovery of $CO_2$. The combustion characteristics, flame stability, composition in the flame zone and temperature profile were studied experimentally for various compositions of oxidant by substituting $CO_2\;for\;N_2$ with the constant $O_2$ concentration. Results showed that flame became unstable due to the high heat capacity, low transport rate and strong radiation effect of $CO_2$ in comparison with those of $N_2$. The reaction zone was quenched and broadened, as the ratio of $CO_2\;to\;N_2$ was increased. The emission of NOx in flue gas decreased due to the decreased temperature of the reaction zone. As the conversion ratio of $CO_2\;to\;N_2$ was increased, the emission of CO and the higher temperature zone increased due to decrease of reaction rate by the a quenching effect.

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Investigation of Photoluminescence and Annealing Effect of PS Layers

  • Han, Chang-Suk;Park, Kyoung-Woo;Kim, Sang-Wook
    • Korean Journal of Materials Research
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    • v.28 no.2
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    • pp.124-128
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    • 2018
  • N-type porous silicon (PS) layers and thermally oxidized PS layers have been characterized by various measuring techniques such as photoluminescence (PL), Raman spectroscopy, IR, HRSEM and transmittance measurements. The top surface of PS layer shows a stronger photoluminescence peak than its bottom part, and this is ascribed to the difference in number of fine silicon particles of 2~3 nm in diameter. Observed characteristics of PL spectra are explained in terms of microstructures in the n-type PS layers. Common features for both p-type and n-type PS layers are as follows: the parts which can emit visible photoluminescence are not amorphous, but crystalline, and such parts are composed of nanocrystallites of several nm's whose orientations are slightly different from Si substrate, and such fine silicon particles absorb much hydrogen atoms near the surfaces. Light emission is strongly dependent on such fine silicon particles. Photoluminescence is due to charge carrier confinement in such three dimensional structure (sponge-like structure). Characteristics of visible light emission from n-type PS can be explained in terms of modification of band structure accompanied by bandgap widening and localized levels in bandstructure. It is also shown that hydrogen and oxygen atoms existing on residual silicon parts play an important role on emission stability.

A Study of Characteristics of NOx Emission in Lobed Burner (로브형 버너에서의 NOx 배출 특성에 관한 연구)

  • Cho, H.C.;Cho, K.W.;Lee, Y.K.
    • Journal of the Korean Society of Combustion
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    • v.6 no.1
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    • pp.1-6
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    • 2001
  • To evaluate the effect of lobed structure on pollutant emission, an experimental study examines NOx and CO emissions associated with four burner geometries, such as a conventional circular burner and three lobed ones. Rapid mixing allowed by the lobed burner to produce lean premixed flames, with narrower flame stability diagram than for the conventional circular one. Conventional circular burner of wide and uniform burner rim has an advantage of flame stabilization. Correlation on fuel discharge velocity for flame blowout should be included a variable related to the wall effect of the burner. NOx emission reduces by about 5% at the burner with lobed structure in fuel discharge side compared to conventional circular one. This is due to lower flame temperatures through flame elongation and increased radiative heat losses, caused by partially luminous flame in flame front. Meanwhile, at the burner with lobed structure in air discharge side and both fuel and air discharge sides, NOx emission somewhat increases with reduced radiative heat losses in spite of flame elongation. Therefore, the rapid mixing by lobed structure does not always have an advantage on NOx reduction.

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Fabrication of triode type Ti-silicided field emission tip array (3극 티타늄 실리사이드 전계방출 팁 어레이의 제작)

  • Ohm, Woo-Yong
    • 전자공학회논문지 IE
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    • v.44 no.3
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    • pp.1-5
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    • 2007
  • A new field emission tip array was realized by Ti silicidation of Ti coated Si tip, which has long term durability, chemical stability, and high emission current density. The fabricated Ti silicided FE tip array under high vacuum condition of about $10^{-8}Torr$ shows that the turn-on voltage is about 40V and the emission current is about $69{\mu}A$ when the bias of 150V is applied between anode and cathode of $100{\mu}m$ distance.

Enhanced field emission properties of double-walled carbon nanotubes coated with lead selenide nanoparticles (셀렌화납 코팅을 통한 이중벽 탄소나노튜브의 전계방출특성 향상)

  • Shin, Dong-Hoon;Lee, Cheol-Jin;Choi, Young-Min;Kim, Jong-Ung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.3
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    • pp.594-598
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    • 2010
  • We studied on the field emission properties of double-walled carbon nanotubes (DWCNTs) coated with lead selenide (PbSe) nanoparticles. PbSe nanoparticles were uniformly attached on the surface of the DWCNTs by a simple chemical process. The PbSe-coated DWCNTs showed highly increased emission current density and enhanced emission stability over 20 h, compared with raw DWCNTs. We consider that the enhanced field emission properties of PbSe-coated DWCNTs were attributed to the increased field enhancement factor and lowered work function of the emitters.

Spindt Cathode Tip Processing to Enhance Emission Stability and High-Current Performance

  • Spindt, C.A.;Schwoebel, P.R.;Holland, C.E.
    • Journal of Information Display
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    • v.2 no.3
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    • pp.44-47
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    • 2001
  • The extracted field emission current can be used to controllably heat microfabricated cold field emission cathode tips. The heating can be sufficient to smooth and recrystallize the tip surface by surface self-diffusion, and at least partially clean the surface of contaminants by thermal desorption. Self-heating not only allows for the achievement and maintenance of stable emission characteristics, but can be used to make the current-voltage characteristics of microfabricated field emitter tips nearly identical to one another. The resulting improvement in emission uniformity will allow for more reliable array operation at increased electron emission current densities.

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Unambiguous Identification of Fugitive Pollutants and Determination of Annual Emission Flux as Diurnal Monitoring Mode

  • Chang, Shih-Yi;Tso, Tai-Ly;Lo, Jiunn-Gung;Huang, Jer-Luen;Lin, Cheng Ming
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.731-738
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    • 1995
  • Toxic air pollutants are investigated in a petrochemical industrial park in Taiwan by using a movable open path FTIR. The results show the qualitative and quantitative analysis of emission gases from plants, and also provide the emission rate of different compounds. More than twenty compounds under usual operation are found from this industrial park. The concentration variation with time can be correlated exactly with wind direction. It means that by changing the measuring points, the source of emission can be unambiguously identified. An EPA proved PAL model is applied to estimate the emission rate of either a point or an area source. Local atmospheric stability is determined by releasing the $SF_6$ tracer. The origins of errors come mainly from the uncertainty of source's configuration and the variation of meteorological condition. Through the continuous measurement (half an hour base in this study) of OP-FTIR sensor, the maximum value of emission rate and the annual amount of emission can be derived. The emission rate of the measured toxic gases are derived by the model technique and the results show that the emission amount are in the order of ten to hundred tons per year.

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Fabrication of New Co-Silicided Si Field Emitter Array with Long Term Stability (Co-실리사이드를 이용한 새로운 고내구성 실리콘 전계방출소자의 제작)

  • Chang, Gee-Keun;Kim, Min-Young;Jeong, Jin-Cheol
    • Korean Journal of Materials Research
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    • v.10 no.4
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    • pp.301-304
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    • 2000
  • A new triode type Co-silicided Si FEA(field emitter array) was realized by Co-silicidation of Co coated Si FEA and its field emission properties were investigated. The field emission properties of the fabricated device through the unit pixel with $45{\times}45$ tip array in the area of $250{\mu\textrm{m}}{\times}250{\mu\textrm{m}}$ under high vacuum condition of $10^{-8}Torr$ were as follows : the turn-on voltage was about 35V and the anode current was about $1.2\mu\textrm{A}(0.6㎁/tip)$ at the bias of $V_A=500V\;and\; V_G=55V$. The fabricated device showed the stable electrical characteristics without degradation of field emission current for the long term operation except for the initial transient state. The low turn-on voltage and the high current stability of the Co-silicided Si FEA were due to the thermal and chemical stability and the low work function of silicide layer formed at the surface of Si tip.

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Field-emission Properties and Long-term Stability of Tip-type Carbon Nanotubes Coated with Gallium-incorporated Zinc Oxide Films (갈륨이 첨가된 산화아연막의 코팅에 따른 미세팁 구조 탄소나노튜브의 전계방출 특성 및 장시간 안정성)

  • Kim, Jong-Pil;Noh, Young-Rok;Jo, Kyoung-Chul;Lee, Sang-Yeol;Park, Jin-Seok
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.4
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    • pp.65-69
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    • 2009
  • Carbon nanotubes (CNTs) were coated with undoped zinc oxide (ZnO) or 5 wt% gallium-incorporated ZnO (GZO) using various deposition conditions. The CNTs were directly grown on conical-type tungsten substrates at $700^{\circ}C$ using inductively coupled plasma-chemical vapor deposition. The pulsed laser deposition technique was used to deposit the ZnO and GZO thin films with very low stress. Field-emission scanning electron microscopy and high-resolution transmission electron microscopy were used to monitor the variations in the morphology and microstructure of CNTs prior to and after ZnO or GZO coating. The formation of ZnO and GZO films on CNTs was confirmed using energy-dispersive x-ray spectroscopy. In comparison to the as-grown (uncoated) CNT emitter, the CNT emitter that was coated with a thin (10 nm) GZO film showed remarkably improved field emission characteristics, such as the emission current of $325\;{\mu}A$ at 1 kV and the threshold field of $1.96\;V/{\mu}m$ at $0.1\;{\mu}A$, and it also exhibited the highly stable operation of emission current up to 40 h.

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