• 환경영향평가
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• 제29권3호
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• pp.219-229
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• 2020

본 연구에서는 해안매립지역내 벙커C유로 오염된 토양을 대상으로 토양세정 효과를 증진시키기 위한 전기저항가열의 운전인자 별 최적 조건을 도출하여 융복합 적용가능성을 평가하였다. 회분식 실험결과 Tween-80 세정제 보다 VG-2020 세정제에서 약 1.5배 이상의 높은 세정효율 보였으며, 상온 시 대비 60℃에서 약 1.4배의 세정효율 증가를 가져왔다. 전기저항가열 박스 실험결과, 함수율 20~40%의 토양에서 약 40~80분 내에 100℃까지 상승하였으며, 포화 토양층 내 STS 316재질의 파이프형 전극봉을 3각 배열 시 열전달효율이 우수한 것으로 나타났다. 또한 상기 최적조건으로 토양온도를 60℃ 이상을 유지하기 위한 전극봉의 간격은 1.5 m인 것으로 확인되었고, 전기저항가열과 동반된 토양세정 박스실험에서는 5 PV(Pore Volume)에서 약 55%의 급격한 TPH 저감효율을 보였으며 10 PV(Pore Volume)에서 토양오염 우려기준(TPH 2,000 mg/kg 미만)을 만족하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.480-480
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• 2008

Vacuum circuit breaker(VCB) is now emerging as an alternative of gas circuit breaker(GCB) which uses SF6 gas as insulating material whose dielectric strength is outstanding. But we have to reduce SF6 gas because SF6 gas is one of greenhouse gas and efforts to reduce greenhouse gas are now trend of the world. Therefore, we can say VCB is the optimal alternative of GCB because vacuum is environmentally friendly. The vacuum interrupter is the core part of VCB to interrupt arcing current. There are mainly two methods to extinguish arc. One is radial magnetic field (RMF) method and the other is axial magnetic field (AMF) method. We deals with RMF method in this paper. Compared with AMP, RMF arc quenching method has different principle to extinguish arc. In case of RMF method, pinch effect is much larger than AMF method. Because of pinch effect RMF type contact electrodes have the single large spot which is severly damaged and melted while AMF type contact electrodes have small and multiple spots which are slightly damaged and melted. To prevent contact electrode being damaged and melted from high temperature-arc, RMF method uses Lorentz force to move arc. In this paper we calculated and compared the arc driving force of two cases and we analyzed the force acting on each part of arc by means of commercial finite element method software Maxwell 3D. They have 3petals and we considered two cases. One is the case when fixed(upper) and movable(lower) contacts are in mirror arrangement (Case 1). The other is the case when one of two contacts (movable contact) is revolved at maximum angle as possible as it can be (Case 2). And at each case above, we analyzed arc driving force at two positions, position 1 is the closest to the center of contact and position 2 is near the edge of petal on fixed contact. As a result we could find that Case 2 generated stronger arc driving force than Case 1 at position 1. But at position 2 Case 1 generated stronger arc driving force than Case 2. This simulation method can contribute to optimizing spiral-type electrode designs in a view of arc driving force.

• 한국수소및신에너지학회논문집
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• 제7권1호
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• pp.29-37
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• 1996

Alkaline water electrolysis has been commercialized as the only large-scale method for a long time to produce hydrogen and the technology is superior to other methods such as photochemical, thermochemical water splitting, and thermal decomposition method in view of efficiency and related technical problem. However, such conventional electrolyzer do not have high electric efficiency and productivity to apply to large scale hydrogen production for energy or chemical feedstocks. Solid polymer electrolyte water electrolysis using a perfluorocation exchange membrane as an $H^+$ ion conductor is considered to be a promising method, because of capability for operating at high current densities and low cell voltages. So, this is a good technology for the storage of electricity generated by photovoltaic power plants, wind generators and other energy conversion systems. One of the most important R&D topics in electrolyser is how to minimize cell voltage and maximize current density in order to increase the productivity of the electrolyzer. A commercialized technology is the hot press method which the film type electrocatalyst is hot-pressed to soild polymer membrane in order to eliminate the contact resistance. Various technologies, electrocatalyst formed over Nafion membrane surface by means of nonelectrolytic plating process, porous sintered metal(titanium powder) or titanium mesh coated with electrocatalyst, have been studied for preparation of membrane-electrocatalyst composites. In this study some experiments have been conducted at a solid polymer electrolyte water electrolyzer, which consisted of single cell stack with an electrode area of $25cm^2$ in a unipolar arrangement using titanium mesh coated with electrocatalyst.

• 대한의용생체공학회:의공학회지
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• 제13권2호
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• pp.133-140
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• 1992

Bioelectrical Impedance method for measuring human body composition is based upon the principle that the electrical conductivity of the fat-free mass (FFM) is far greater than that of the (at. Deter- mination o( impedance was nlade in 30 healthy and obese men aged $40.9{\pm}14.7$yr (mean${\pm}$SD) and 25 healthy and obese women aged $44.0{\pm}10.2$ yr. A commercial impedance body fat analyzer was used with a four electrode arrangement that introduced a painless constant current(ImA at 50 kHz) into the body. Linear relationships were found between impudence values and FFM(r=-0.786) and between weight and FFM(r=0.837). Signigicant increases in the correlation coefficients were ob served when the predicator Hta/z was regressed against FFM(r=0.912) where Ht Is height and Z Is impedance. A linear regression equation, FFM=0.586(Htf/z) +0.317(Weight) -1.674(r=0.977), was found. The correlation coefficient of % body fat between the impedance and infrared methods was 0.898. These data Indicate that the bioelectrical impedance technique is a reliable and valld approach for the estimation of human body composition. This method Is safe, noninvasivr, prouides rapld measure menu, requires little operator skill and subject cooperation, and Os portable. Finally measurement of percent body fat was made possible using both the regression equation and a developed impedance measuring device which measures impedance between wrist and ankle.

• 한국환경과학회:학술대회논문집
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• 한국환경과학회 2019년도 정기학술대회 발표논문집
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• pp.83-83
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• 2019

Increasing the CO₂ concentration in the atmosphere induce high temperature and rising sea levels. So the technology that capture and reuse of the CO₂ have been recently become popular. Among other methods, CRR(CO2₂ reduction reaction) is typical method of CO₂ reusing. Electrocatalyst can show more higher efficiencies in CRR than photocatalyst because it doesn't use nature source. Nowadays, finding high efficient electrocatalyst by controlling electronic (affected by stoichiometry) and geometric (affected by atomic arrangement) factors are very important issues. Mono-atomic electro-catalyst has limitations on controlling binding energy because each intermediate has own binding energy range. So the Multi-metallic electro-catalyst is important to stabilize intermediate at the same time. Carbon monoxide(CO) which is our target product and important feedstock of useful products. Au is known for the most high CO production metal. With copper, Not only gold/copper has advantages which is they have FCC packing for easily forming solid solution regardless of stoichiometry but also presence of adsorbed CO on Cu promotes the desorption of CO on Au because of strong repulsion. And gold/copper bi-metal catalyst can show high catalytic activity(mass activity) although it has low selectivity relatively Gold. Actually, multi-metallic catalyst structure control method is limited in the solution method which is takes a lot of time. In here, we introduce CTS(carbo thermal shock) method which is using heat to make MMNP in a few seconds for making gold-copper system. This method is very simple and efficient in terms of time(very short reaction time and using carbon substrate as a direct working electrode) and increasing reaction sites(highly dispersed and mixing alloy structures). Last one is easy to control degree of mixing and it can induce 5 or more metals in one alloy system. Gold/copper by CTS can show higher catalytic activity depending on metal ratio which is altered easily by changing simple variables. The ultimate goals are making CO₂ test system by CTS which can check the selectivity depending on metal types in a very short time.

• 한국토양비료학회지
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• 제45권3호
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• pp.353-359
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• 2012

The identification of effective root zone would clarify dynamics of plant available water and soil water balance. Using the relationship between soil properties and electrical resistivity (ER) the purpose of this research is to identify soil zone affected by a plant root activity using electrical resistivity tomography (ERT) technique. Four plastic containers were prepared for two different soil textures (clay and sandy loam) and one container for each texture was selected for planting four corn seedlings (Zea mays L.) and the others were prepared for the blank. For ERT monitoring, we prepared 0.8 m plastic sticks with 17 electrodes installed with 5 cm space. The Ministing (AGI Inc., Texas) instrument for electrical resistivity measurement and semi-auto converter of electrode arrangement were set up for dipole-dipole array. During 2 months of the corns growing, ERT monitoring was made 3 to 4 days after the irrigation practice. Despite of the same amount water supplied into soils, two textures showed very different apparent resistivity values due to different clay content. The apparent electrical resistivity is consistently lower in clay loam comparing to sandy loam soil implying that plant root does not significantly alter the overall trend of resistivity. When plant root system, however, is active both soils with plants showed 2-7 times higher electrical resistivity and higher coefficient variation than soils without plant, implying the effect of root system on the resistivity, in which may caused by. This result suggests plant root activities regulating the soil water dynamics mainly control the variation of electrical resistivity over soil textural difference. Therefore the identification of water uptake zone would highly be correlated to plant root activities, thus ERT will be feasible approach to identify spatial characteristics of a plant root activity.

• 조명전기설비학회논문지
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• 제22권12호
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• pp.122-129
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• 2008

본 논문은 실내에 잔존하는 직경 1[${\mu}m$] 이하의 미세먼지들을 집진하기 위하여 전기집진기를 설계하였으며, 이때 집진 효율의 극대화를 위하여 전계와 동시에 자계를 수직 및 수평으로 배치함에 따른 실험실 공기중에 포함된 미세먼지의 집진특성에 대하여 논하였다. 전계에 수평으로 자계를 인가한 경우는 자계의 유무 및 자석의 수량에 관계없이 집진효율이 거의 일정하게 나타났으며, 자석을 수평으로 배치하여 전계에 수직으로 인가한 경우는 비자화 페라이트 막대를 부착한 경우보다 약 5[%] 이상 집진효율이 향상되었다. 또한, 자계를 전계에 수직으로 인가하는 방법에 있어서, 자석을 접지전극의 가운데 정렬한 경우는 인가전압 5[kV]에서의 집진효율이 $17{\sim}32[%]$로서 자석을 앞쪽에 설치한 경우와 유사하였으며, 지그재그 및 안쪽 끝에 정렬시킨 경우는 집진효율이 $17{\sim}38[%]$로서 향상되었으며, 특히 0.7 및 1[${\mu}m$]의 굵은 입자들에 대한 집진특성이 양호하였다. 따라서, 전기집진기의 집진특성을 향상시키기 위해서는 자계를 전계에 수직으로 접지전극의 중간 또는 지그재그 식으로 배치하는 것이 가장 적절한 것으로 판단된다.

• Journal of Electrochemical Science and Technology
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• 제9권4호
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• pp.282-291
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• 2018

The pristine fluorine-doped $SnO_2$ (abbreviated as FTO) inverse opal (IO) was developed using a 410 nm polystyrene bead template. The nanolayered copper tungsten oxide ($CuWO_4$) was decorated on the FTO IO film using a facile electrochemical deposition, subsequently followed by annealing at $500^{\circ}C$ for 90 min. The morphologies, crystalline structure, optical properties and photoelectrochemical characteristics of the FTO and $CuWO_4$-decorated FTO (briefly denoted as $FTO/CuWO_4$) IO film were investigated by field emission scanning electron microscopy, X-ray diffraction, UV-vis spectroscopy and electrochemical impedance spectroscopy, showing FTO IO in the hexagonally closed-pack arrangement with a pore diameter and wall thickness of about 300 nm and 20 nm, respectively. Above this film, the $CuWO_4$ was electrodeposited by controlling the cycling number in cyclic voltammetry, suggesting that the $CuWO_4$ formed during 4 cycles (abbreviated as $CuWO_4$(4 cycles)) on FTO IO film exhibited partial distribution of $CuWO_4$ nanoparticles. Additional distribution of $CuWO_4$ nanoparticles was observed in the case of $FTO/CuWO_4$(8 cycles) IO film. The $CuWO_4$ layer exhibits triclinic structure with an indirect band gap of approximately 2.5 eV and shows the enhanced visible light absorption. The photoelectrochemical (PEC) behavior was evaluated in the 0.5 M $Na_2SO_4$ solution under solar illumination, suggesting that the $FTO/CuWO_4$(4 cycles) IO films exhibit a photocurrent density ($J_{sc}$) of $0.42mA/cm^2$ at 1.23 V vs. reversible hydrogen electrode (RHE, denoted as $V_{RHE}$), while the FTO IO and $FTO/CuWO_4$(8 cycles) IO films exhibited a $J_{sc}$ of 0.14 and $0.24mA/cm^2$ at $1.23V_{RHE}$, respectively. This difference can be explained by the increased visible light absorption by the $CuWO_4$ layer and the favorable charge separation/transfer event in the cascading band alignment between FTO and $CuWO_4$ layer, enhancing the overall PEC performance.